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57results about How to "Small fluctuations in concentration" patented technology

Method for extracting tungsten from scheelite

The invention discloses a method for extracting tungsten from scheelite, comprising the following steps of: mixing the scheelite with a mixed solution of phosphoric acid and sulfuric acid for reaction, adding dihydrate gypsum as seed crystals, and controlling the concentration of SO4<2->, the content of P2O5 and the reaction temperature to obtain the dihydrate gypsum with good filtering and washing properties. The invention has the advantages that one-step efficient normal pressure leaching of the scheelite is achieved, thus resources and energy consumption are saved, and the resolution ratio of the scheelite is up to above 98%; the problems of Cl<-> corrosion and serious HCl volatilization are overcome; the cyclic utilization of phosphoric acid is basically achieved, and the leaching cost and waste water discharge are greatly reduced; leaching equipment is simple, is convenient for operation and is easy to realize industrialization; the single and stable dihydrate gypsum is obtained, the filter efficiency of the dihydrate gypsum is high, the washing property of the dihydrate gypsum is good, and the P2O5 content in the washed dihydrate gypsum is reduced to be below 2%, thereby reducing the loss of phosphoric acid; and the passivation phenomenon of calcium sulfate solid film when the tungsten ore is leached is avoided.
Owner:CENT SOUTH UNIV

Method and equipment for continuous smelting of lead sulphide concentrate

A lead sulfide ore concentrate continuous smelting method and equipment thereof are provided. The invention relates to a pyrometallurgical process of lead sulfide ore concentrate and the equipment adopted for realizing the process. In the device, a partition wall is arranged in the space above the liquid slag layer of the molten pool of the furnace body, which separates the device into three regions of an oxidation region, a reduction region and a fuming region that are not communicated. The top of every region is equipped with a flue gas outlet and is respectively equipped with a spray gun. A material smelting inlet is arranged on the top part of the oxidation region. A siphon discharging outlet is arranged on a crude lead layer on the bottom of the furnace body. A slag discharging outlet is arranged on the liquid slag layer of the fuming region. The smelting materials are continuously fed in the furnace from the top of the oxidation region. The liquid metal lead is continuously discharged out of the furnace from the siphon discharging outlet. SO2 obtained in the oxidation area is used for preparing sulfate acid. Valuable metal smoke dust such as high zinc that is obtained in the fuming region is reused. The invention has the advantages of short process line, fully utilization of slag heat, obvious energy saving effect, less investment in the metallurgical furnace equipment, low activity-based cost, small concentration fluctuation of SO2, cheap reducing agent and wide resources.
Owner:YUNNAN TIN GROUP HLDG

Production method for producing cement and sulfuric acid from phosphogypsum

InactiveCN112694067AImprove product qualityEliminate the environmental problems of stackingSulfur compoundsCeramic production plantsReductive decompositionDust control
The invention discloses a production method for producing cement and sulfuric acid by using phosphogypsum. The method comprises the following steps: carrying out pretreatment purification on phosphogypsum to reduce insoluble phosphorus, water-soluble phosphorus impurities and most free water in the phosphogypsum, kneading with a reducing agent, granulating, and directly feeding the material into a reductive decomposition integrated rotary kiln with fluidization preheating function; controlling a gas phase atmosphere to perform step-by-step heating, drying, dehydration and reductive decomposition under the combustion of the pulverized coal; sulfur dioxide gas generated after reductive decomposition is used for producing sulfuric acid after being subjected to dust removal and purification; and the reduced and decomposed material enters an oxidation calcining kiln for cement clinker sintering, and the gas-phase atmosphere is controlled under the combustion of pulverized coal for heating, mineralizing and sintering to obtain the cement clinker. Compared with the prior art, the production method for producing cement and co-producing sulfuric acid by using phosphogypsum has the advantages that the coal consumption for reduction and firing is reduced, the production efficiency and the product quality are improved, the device investment is saved, the economic benefit of producers is increased, and the environmental protection problem of phosphogypsum stacking treatment is eliminated.
Owner:CHENGDU QIANLIJIN TECHCAL INNOVATION CO LTD

Method for recovery and reusing of etching liquid containing copper ions and nitrate

The invention discloses a method for recovery and reusing of etching liquid containing copper ions and nitrate, and belongs to the technical field of etching liquid recovery. The method comprises thefollowing steps that a high-concentration copper-containing solution and a low-concentration copper-containing solution are obtained from the etching liquid through an electrodialysis device, the high-concentration copper-containing solution enters a copper extraction tank to be subjected to circulating electrolysis, thus the copper ions are reduced to generate copper elementary substances, the copper elementary substances are deposited on a copper electrode serving as a cathode, the cathode serves as an anode in a refining tank, thus the anode in the refining tank is dissolved out on the cathode, and a copper plate is obtained; electrolyte, with the low copper ion concentration, obtained in the copper extraction tank and the low-concentration copper-containing solution generated in the electrodialysis device are subjected to swirling flow electrolysis, and thus a copper pipe and/or copper powder are/is obtained; and concentrated nitric acid is added into clear liquid, and thus the etching liquid is recycled. If the etching liquid contains nickel ions, after electrolysis is completed, lye is added to adjust pH, and thus the nickel ions are precipitated. Copper recycled through themethod is high in economic value, a chemical agent is not put, and secondary pollution is avoided; and the etching liquid is regenerated and recycled, and resources are maximally utilized.
Owner:湖北永绍科技股份有限公司 +1

SNCR denitration control method and device for circulating fluidized bed unit and storage medium

The invention discloses an SNCR denitration control method and device for a circulating fluidized bed unit and a storage medium. The method comprises the following steps: S1, oxygen amount control: designing an oxygen amount control model prediction controller by taking the total air amount of secondary air as a control variable, the total coal amount as an interference variable and the oxygen content in flue gas as a controlled variable, and controlling the opening degree of a baffle door of a secondary air fan according to an output result of the oxygen amount control model prediction controller; and S2, denitration control: designing a denitration control model prediction controller by taking the total ammonia spraying amount as a control variable, taking the NOx concentration of the clean flue gas as a controlled variable and taking the oxygen content in the flue gas as an interference variable, and controlling the opening degree of an ammonia spraying valve according to an outputresult of the denitration control model prediction controller. The fluctuation range of the NOx generation amount under the variable load working condition can be reduced through oxygen amount controloptimization, oxygen amount measuring points serve as feedforward control through denitration control optimization, the delay time of a control system can be shortened, and the ammonia spraying amount can be saved through combination of the oxygen amount control optimization and the denitration control optimization.
Owner:YANTAI LONGYUAN POWER TECH

Continuous aluminum oxide feeding equipment

ActiveCN105671594AReduce temperature and alumina concentration fluctuationsImprove current efficiencyComposite materialOxide
The invention discloses continuous aluminum oxide feeding equipment which comprises a material box, a feeding air cylinder, a fixed container, a crust breaking head, a material passing frame, an oblique plate, a buffer and a feeding pipe. The feeding pipe is led to the bottom of the crust breaking head. The continuous aluminum oxide feeding equipment further comprises an air pipe which is arranged at a buffer outlet and used for blowing air to the buffer outlet. Compared with the prior art, the continuous aluminum oxide feeding equipment has the beneficial effects that (1) aluminum oxide is made to enter an electrolyte slowly, and the temperature fluctuation of an electrolytic cell and the concentration fluctuation of the aluminum oxide are reduced, so that the current efficiency is improved, and energy consumption is reduced; (2) the aluminum oxide is made to have enough time to be melted into the electrolyte, so that sediment at the furnace bottom is reduced, the pressure drop at the furnace bottom is reduced, and energy consumption is reduced; (3) the aluminum oxide is made to enter the electrolyte slowly through a pipeline, and the crust breaking head is prevented from being impacted so that the aluminum oxide can be prevented from being dispersed, the actual amount of materials entering the electrolytic cell is increased, and the effect coefficient is decreased; and (4) large particles in the aluminum oxide are blown away through the gas reverse blowing principle, so that blockage is eliminated, and the hole blockage phenomenon can be effectively prevented.
Owner:SNTO TECH GRP

High-precision control method for mine filling slurry concentration

The invention relates to a high-precision control method for mine filling slurry concentration. The method comprises the following steps of: describing a slurry production process by adopting a third-order lag system, and decomposing the system into two small systems, namely an aggregate conveying process and an aggregate and cement stirring process; and establishing a control-oriented augmented error system without time lag in form by introducing errors and new variables. On the basis, a control law of the stirring process and a control law of the conveying process are designed by applying anoptimal control theory respectively. According to the method, the characteristics of the system and future information of an output target signal are fully utilized, so that the fluctuation of the slurry concentration can be effectively reduced, a guarantee is provided for high-quality filling, and the technical problem of control in the current mine filling slurry production process is solved. The method aims at engineering practical problems, and the achievement provides a theoretical reference for mine filling slurry production and has important application value for reducing the slurry concentration fluctuation and improving the filling quality.
Owner:宁夏烽火台数据信息技术有限责任公司

Heat sink of electrolytic tank

The invention specifically relates to a heat sink of an electrolytic tank, belonging to the technical field of electrolysis of sodium hypochlorite. The heat sink comprises the electrolytic tank, an electrode assembly, a cooling mechanism and a temperature controlling mechanism. The cooling mechanism comprises a cooling pipe immersed in brine; one end of the cooling pipe is connected with a coolingwater inlet, and the other end of the cooling pipe is connected with a cooling water outlet; the temperature controlling mechanism is connected with the cooling pipe in series and comprises a body which has a flow channel running through the body; two ends of the flow channel communicate with the cooling pipe; the body is further provided with a slideway which perpendicularly intersects with andcommunicates with the flow channel, a slide block is arranged in and slidably connected with a slideway; a flow hole cooperating with the flow channel is formed in the slide block; one end of the slideway is provided with a compression spring that abuts against the slide block; and the other end of the slideway is provided with a stop block. The heat sink of the invention carries out real-time adjustment of the temperature of the electrolytic tank, so the temperature of the electrolytic tank is always maintained in a stable range; and thus, an electrolysis rate is stable, and the concentrationfluctuation of a produced sodium hypochlorite solution is small.
Owner:贵州成黔科技开发有限公司

Production equipment for preparing semiconductor film on tubular base

The invention discloses production equipment for preparing a semiconductor film on a tubular base. The production equipment adopts a single-slot multi-tube manner, heated liquid flows into the inner wall of the tubular base so as to heat the tubular base from inner side to heat a reaction solution through the tubular base, the reaction solution can exist in a normal temperature status and does not affect the growth of the semiconductor film, and the reaction can be carried out preferably on the outer wall of the tubular base so as to save the solution; high temperature heating liquid provided by an independent constant high-temperature heating box is taken as a heat source, so that the temperature of semiconductor film deposition is stable, and high repeatability of the semiconductor film deposition is realized; a manner of combination of an overflow structure and interior heating of the tubular base is also adopted; and the solution is updated at real time by adopting a reaction solution overflow circulatory system, the effect of concentration reduction on a reaction process at a later period is reduced, the waste liquor emission load is lowered, and the solution injection volume is reduced. The production equipment is applicable to industrial mass production of semiconductor films deposited on various tubular bases.
Owner:PEKING UNIV

Flue gas desulfurization and denitrification optimization control method based on hysteresis model

The invention relates to a hysteresis model-based flue gas desulfurization and denitrification optimization control method, which comprises the following steps of: establishing a power plant desulfurization and denitrification system simulation model through dynamic simulation software according to modular modeling and a control strategy; establishing a first delay time prediction model for the time delay existing in the determination of the pH value of an absorption tower in the desulfurization system, and establishing a second delay time prediction model for the time delay existing in the determination of the concentration of flue gas nitrogen oxide at the inlet of the denitration system through a flue gas online monitoring device CEMS; predicting the concentration of sulfur dioxide at a desulfurization outlet and the concentration of nitrogen oxide at a denitration inlet by adopting a support vector machine model; controlling the slurry spraying amount according to the predicted value of the sulfur dioxide concentration in combination with a first lag time prediction model, and controlling the ammonia spraying amount according to the predicted value of the nitrogen oxide concentration in combination with a second lag time prediction model; and the control parameters are issued to the desulfurization and denitrification system simulation model for intelligent diagnosis.
Owner:STATE GRID HEBEI ENERGY TECH SERVICE CO LTD +2

Multi-model adaptive control method for denitration control system

The invention relates to a multi-model adaptive control method for a denitration control system. The method comprises steps that 1, sub models of a controlled object under different loads are established; 2, PID controllers are respectively designed according to the m sub models; output of the controlled object and output of each sub model are acquired through measurement; 4, deviation of output of the controlled object and output of each sub model is acquired; 5, a weight wi of each controller is solved; 6, control quantities u1(k) to um(k) of the controllers are weighted to output to acquire a global control quantity up(k); 7, the global control quantity is sent to the controlled object and the sub models for control; and 8, the process returns to the step 3. The method is advantaged in that a global controller can be made to output the optimal control quantity in real time under the changeable load condition, the purpose of adaptive load change is realized, change of an export NOx concentration can be timely tracked according to change of ammonia injection amount, export NOx concentration fluctuation of the denitration system can be effectively reduced, so the NOx concentration is stabilized to be in an index required by the environmental protection department, control thinking is simple, and the method is easy for realization in a power plant DCS.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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