The invention discloses a
lithium nickel cobalt aluminum
oxide and
lithium manganese oxide composite material used for a
lithium ion battery and a preparation method of the lithium
nickel cobalt aluminum
oxide and
lithium manganese oxide composite material. According to the method, suspension liquid is prepared through mixing lithium
nickel cobalt aluminum oxide with water, doped type
lithium manganese oxide precursors are prepared by the utilization of a co-
precipitation method, so that the prepared precursors are evenly precipitated on the surface of lithium nickel cobalt aluminum oxide, and through
calcination, crushing and screening, the
composite material which is doped with
lithium manganese oxide and coated with the lithium nickel cobalt aluminum oxide is obtained. According to the material, the lithium nickel cobalt aluminum oxide (the
structural formula is LiNi0.8Co0.15Al0.05O2) serves as a core, and the doped lithium
manganese oxide < the
structural formula is LiMn2-xMxO4 (0.1<=x<=0.5), and M is one or two of Mg, Co, Al, Cr, Zn and Ti> serves as a shell. The doped lithium
manganese oxide serves as a
coating layer, through a combination of a control
crystallization method and a liquid-phase ball milling method, the doped type lithium
manganese oxide precursors are prepared, the defects that a traditional lithium
manganese oxide material is low in
energy density, and
cycling performance of the lithium nickel cobalt aluminum oxide is poor are overcome, the capacity of the material is high, and the
cycling performance is excellent. The preparation method is simple, and industrial production is easy.