The invention provides a clean production method of high-purity
copper phthalocyanine. The method comprises following steps: (1), synthesis: alkylbenzene is added to a condensation tank,
phthalic anhydride is continuously added after the temperature is increased,
urea,
cuprous chloride and
ammonium molybdate are added after
phthalic anhydride is dissolved, the components are subjected to a reaction, and a crude
copper phthalocyanine product is prepared; (2), refining:
copper phthalocyanine slurry is prepared from the crude
copper phthalocyanine product and added to a
mixed solution N preparedfrom dilute
sulfuric acid and a cosolvent, heating and stirring are performed until the crude
copper phthalocyanine product is completely dissolved, then water is dropwise added until
copper phthalocyanine crystals are not separated out, filtering is performed, a
filter cake is subjected to
ethanol washing,
water washing, filtering and
vacuum drying, and the high-purity copper phthalocyanine product is obtained; (2), waste liquor
recovery: a large amount of filter liquor produced in a reaction process is adsorbed by
ion exchange resin, neutralized, concentrated, evaporated and centrifuged, andan
ammonium sulfate product is prepared.
Copper phthalocyanine prepared with the method is high in purity and has
single crystal form, good coloring effect and excellent color stability, meanwhile,
tail gas and
wastewater in the production are effectively treated, and
economic benefits of
energy conservation and emission reduction are obtained.