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17 results about "Imidogen" patented technology

Imidogen is an inorganic compound with the chemical formula NH. Like other simple radicals, it is highly reactive and consequently short-lived except as a dilute gas. Its behavior depends on its spin multiplicity, i.e. the triplet versus singlet ground state.

Post-modified imine-COF adsorbent as well as preparation method and application thereof

The invention relates to the technical field of adsorption materials, and discloses a post-modified imine-COF adsorbent and a preparation method and application thereof, the adsorbent comprises the following structural units: a COF skeleton, which is a two-dimensional or three-dimensional porous skeleton formed by an aromatic aldehyde monomer and an amino monomer through a Schiff base reaction; the imine group is formed in a COF skeleton through a post-modification reaction, and the imine group is-C = NR, r is selected from one or more of a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted heterocyclic group and a hydrogen atom. The adsorbent retains excellent structural characteristics of the COF material, realizes high density and uniform distribution of functional groups, and avoids interference of functional monomers on crystal nucleation and growth, so that the adsorption performance of the adsorbent is improved, and the adsorbent can efficiently capture rare earth when being applied to a rare earth-containing solution.
Owner:NANCHANG UNIV

Hybrid organic-inorganic two-dimensional metal carbide mxenes

Hybrid organic-inorganic MXenes (h-MXenes) having amido, imido, alkoxy, or aryloxy surface terminating groups and methods for synthesizing the hybrid organic-inorganic MXenes are provided. The synthesis of h-MXenes having a broad scope of erminal organic functional groups is carried out via the displacement of halide atoms from halide-terminated MXenes by deprotonated primary organic amines or deprotonated alcohols.
Owner:UNIVERSITY OF CHICAGO

Interface modification layer material and synthesis method and application thereof

The application relates to the technical field of photoelectric functional materials, in particular to an interface modification layer material and a synthesis method and application thereof. The interface modification layer material provided by the application increases the steric hindrance of the molecule by introducing a functional group at the para-position of the benzene ring in the BPhen molecular structure, and reduces the aggregation and crystallization of the molecule; the molecular weight of the synthesized phenanthroline derivative is large, the glass transition temperature is higher than that of BPhen, and the thermal stability of the material is better; the synthesized phenanthroline derivative exists in the form of ionized quaternary ammonium salt, the reactivity of the imine group in the molecular structure is weaker than that of BPhen or BCP, and the stability of the device is improved; and the synthesis method of the interface modification layer material provided by the application is simple, the yield is high, the purification is easy, the price is low, and the interface modification layer material can be prepared on a large scale. The interface modification layer material can be applied in a semiconductor photoelectric device, and is used as an electrode modification layer to reduce the electrode work function.
Owner:JIAXING UNIV

Imine-based conjugated microporous polymers with high specific surface area and high conjugation degree and preparation method and application thereof

The application relates to an imine-based conjugated microporous polymer with high specific surface area and high conjugation degree and a preparation method and application thereof, three monomers of aryl bromide, arylamine and boric acid are selected, and the imine-based conjugated microporous polymer with high specific surface area and high conjugation degree is synthesized based on a one-pot two-reaction of Buchwald-Hartwig carbon-nitrogen coupling reaction and Suzuki-Miyaura carbon-carbon coupling reaction. In the alkaline condition, the ratio of the aryl bromide and arylamine monomers is kept unchanged, the boric acid monomer is introduced to carry out the Suzuki-Miyaura C-C coupling reaction, the specific surface area, active sites and conjugation degree can be effectively increased. The method is simple in operation, the conjugated microporous polymer with high specific surface area, high conjugation and high redox property has great application potential in energy storage electrode materials, supercapacitors and the like.
Owner:DONGHUA UNIV

Imino methylphosphine reagent and application thereof in preparation of cyclopropylamine compounds

The invention provides an imino methyl phosphine reagent and application thereof in preparation of cyclopropylamine compounds, and belongs to the technical field of organic chemistry. A method for preparing a cyclopropylamine compound from the imino methyl phosphine reagent comprises the following steps: dissolving the phosphine reagent in an organic solvent, cooling to a certain temperature, adding alkali, stirring, adding an epoxy compound, heating to a certain temperature, reacting, carrying out acidolysis to obtain cyclopropylamine salt, and carrying out alkali neutralization to obtain free cyclopropylamine. According to the imino methylphosphine reagent and the application thereof in preparation of cyclopropylamine compounds, a target product is synthesized in one step from epoxy compounds, the defects that a traditional method is tedious in step, toxic reagents are used, the yield is low and the like are overcome, the synthesis efficiency and the yield are improved, the use of harmful reagents and organic solvents is reduced, and the cost is reduced. And primary free cyclopropylamine is easy to obtain and is convenient to subsequently convert into medicines and bioactive molecules.
Owner:CHONGQING MEDICAL UNIVERSITY

IVB metal complex containing imidazoline (alkyl)-2-imino group, catalyst system and method for preparing polymer by using IVB metal complex

The invention belongs to the technical field of high-performance polyolefin catalysis, and discloses an IVB metal complex containing imidazoline (alkyl)-2-imino, a catalyst system and a method for preparing a polymer from the IVB metal complex, the structural formula of the metal complex is shown in the specification, and in the formula, R1-R6 are the same or different substituent groups; the application comprises the following steps: preparing a catalyst system from the metal complex and the cocatalyst, and then carrying out polymerization reaction on ethylene and a large-volume olefin monomer in an inert solvent under the action of gas protection and the catalyst system, the ethylene / large-volume olefin monomer copolymer (or ethylene is subjected to a polymerization reaction in an inert solvent to obtain an ethylene homopolymer, or cycloolefin is subjected to a polymerization reaction in an inert solvent to obtain a cycloolefin homopolymer). The metal complex disclosed by the invention is excellent in temperature resistance, and shows excellent polymerization activity and relatively high insertion rate of a large-volume olefin monomer in a copolymerization reaction system.
Owner:DONGHUA UNIV

Chiral imide-based covalent organic framework material and method for preparing the same

PendingCN122145798APolymer sciencePtru catalyst
The present application relates to a kind of chiral imide group covalent organic framework material and its preparation method, belong to covalent organic framework material technical field.The chiral imide group covalent organic framework material of the present application is with imide bond as connecting unit, with higher thermal stability and chemical stability, and the precise construction of framework chirality is realized by chiral induction strategy, to give material clear chiral characteristics, with important application potential in chiral recognition, chiral separation and asymmetric catalysis etc.;Its preparation is with R / S-tetrahydrofuran-2-methyl acid as chiral inducer, isoquinoline as catalyst, imidazole as reaction medium, and imide bond connecting type covalent organic framework material with crystallinity and significant chiral signal can be prepared by solvothermal reaction.
Owner:SUZHOU UNIV

Three-dimensional network imino covalent organic framework material as well as preparation method and application thereof

The invention discloses a three-dimensional network imino covalent organic framework material as well as a preparation method and application thereof, and belongs to the field of materials. A specific number of multi-aldehyde benzene series and multi-amino benzene series are subjected to a Schiff base reaction, in the preparation process, a mode of combining ultrasonic dispersion and mechanical oscillation is adopted to ensure that reactants are uniformly mixed, and efficient polymerization can be realized at room temperature in cooperation with the synergistic catalysis of acetic acid or cesium carbonate and aniline or benzaldehyde; reaction conditions are mild and easy to control, damage of high temperature and high pressure to a material structure is avoided, meanwhile, directional assembly of a covalent organic framework is promoted through a solvent in a specific proportion and solvent types, formed imine bonds are stably combined, functional groups in a molecular structure endow the material with good chemical activity, and the covalent organic framework material is prepared. The accurate reaction of the multi-aldehyde benzene series and the multi-amino benzene series successfully constructs a three-dimensional network spherical structure.
Owner:SHANDONG POLICE ACAD

Imidousilane coupling agents and methods for their preparation and modified glass fibers and composites prepared therefrom

This invention provides an imide-based silane coupling agent, its preparation method, and modified glass fibers and composite materials prepared therefrom. The method for preparing the imide-based silane coupling agent involves using a mercapto-containing silane coupling agent and maleimide in a molar ratio of 1:0.5-1:1.5 as raw materials to obtain the imide-based silane coupling agent. This invention also provides the imide-based silane coupling agent prepared by the above method, a method for modifying glass fibers using this imide-based silane coupling agent, and the modified glass fibers and composite materials prepared therefrom. The mercapto-olefin click chemistry reaction used in this invention to prepare the imide-based silane coupling agent has mild conditions, is simple to operate, and has a high conversion rate, which can broaden the types and applications of silane coupling agents.
Owner:CHINA PETROLEUM & CHEMICAL CORP +2

A method for preparing an imide lithium salt

The application discloses a preparation method of an imidolide lithium salt, comprising the following steps: (1) dissolving a lithium salt precursor in an organic solvent; adding Li3N and stirring the reaction at a certain temperature; wherein the lithium salt precursor contains a sulfonyl group; (2) removing the solvent in the reaction solution and drying to obtain the imidolide lithium salt. The method for directly preparing the imidolide lithium salt by using lithium nitride has the highest atomic economic efficiency, a simplified production process and lower cost, and can promote better commercial development of the imidolide lithium salt.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI

Preparation method of imine pyridine COF fluorescent probe and application of imine pyridine COF fluorescent probe in detection of Cu 2+ ​

The present invention discloses a preparation method of an iminopyridine COF fluorescent probe and its 2+ The detection application comprises the following steps: dispersing amino monomer (TA) and aldehyde monomer (PD) in an organic solvent, ultrasonically treating, using glacial acetic acid as a catalyst, repeatedly freezing and thawing, and then passing N2 for degassing, heating the container in a vacuum seal for reaction, cooling to room temperature after the reaction is complete, washing, and drying the product to obtain an iminopyridine COF (COF-TAPD) fluorescent probe. The COF-TAPD fluorescent probe of the present invention realizes the detection of Cu in water. 2+ The probe has excellent stability, anti-interference ability and low detection limit, with a LOD of 7.63nM. After five cycles of use, it still maintains more than 85% of the fluorescence response ability, and is effective in detecting heavy metal Cu in water. 2+ It has good practical application potential.
Owner:XIANGTAN UNIV

Application of imidogen covalent organic framework in adsorption separation of 5-hydroxymethylfurfural

The invention discloses application of an imidogen covalent organic framework in adsorption separation of 5-hydroxymethylfurfural, and belongs to the technical field of adsorption separation. The structural formula of the imidogen covalent organic framework is shown as a formula I or a formula II. The imidogen covalent organic framework is used as an adsorbent for adsorbing and separating 5-hydroxymethylfurfural, adsorption sites are provided for the 5-hydroxymethylfurfural through uniform pore channels, rich imidogen groups and high specific surface area of the imidogen covalent organic framework, and the imidogen covalent organic framework has extremely high selectivity on the 5-hydroxymethylfurfural; according to the present invention, the low-concentration 5-hydroxymethylfurfural can be efficiently separated from the mixed solution containing 5-hydroxymethylfurfural, levulinic acid, formic acid and glucose, and the high selectivity and the high stability can be maintained in the pH value range of 1-11;
Owner:GUANGDONG UNIV OF TECH

Compound N-(isopropylimido) guanidine monofluorophosphate monohydrate and N-(isopropylimido) guanidine monofluorophosphate monohydrate birefringent crystal as well as preparation method and application of N-(isopropylimido) guanidine monofluorophosphate monohydrate birefringent crystal

The invention provides a compound monohydrate N-(isopropylimido) guanidine monofluorophosphate and monohydrate N-(isopropylimido) guanidine monofluorophosphate birefringent crystal as well as a preparation method and application thereof, the chemical formula of the compound is (C4N4H11) 2PO3F. H2O, the molecular weight is 346.32, and the compound is prepared by adopting a room temperature solution method; the chemical formula of the crystal is (C4N4H11) 2PO3F. H2O, the molecular weight is 346.32, the crystal belongs to a triclinic system, the space group is shown in the specification, the cell parameters are as follows: a = 7.3372 (6), b = 9.0541 (8), c = 12.6489 (10), alpha = 96.383 (3) degrees, beta = 96.496 (3) degrees, gamma = 97.670 (3) degrees, the unit cell volume is 820.59 (12) 3, and the birefringence is 0.165 at 546 nm. The crystal is grown by adopting a hydrothermal method or a room-temperature solution method, has good chemical stability, can be used for manufacturing polarizing prisms, phase delay devices and electro-optical modulators with various purposes, such as Glan prisms, polarization beam splitters, compensators, opto-isolator circulators, optical modulators and the like, and plays an important role in the fields of optics and communication.
Owner:XINJIANG TECH INST OF PHYSICS & CHEM CHINESE ACAD OF SCI

A d-a type imine group conjugated microporous polymer catalyst for activating persulfate and a preparation method and application thereof

The present application relates to a kind of D-A type imine group conjugated microporous polymer catalyst activated with persulfate and its preparation method and application, the catalyst is prepared by Buchwald-Hartwig coupling reaction of benzothiadiazole monomer and aromatic amine monomer.The catalyst prepared in the present application has high efficient degradation performance to various organic pollutants, wide applicable pH range and confined enhanced mass transfer etc.Characteristics;The catalytic membrane with mass transfer enhancement can be further prepared by the present application.
Owner:DONGHUA UNIV

Preparation method and application of 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound

The invention relates to a preparation method and an application of a 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound. The invention belongs to the technical field of fine chemical synthesis. The invention aims to solve the technical problems that the existing method for preparing the 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound is harsh in reaction condition, high in cost, limited in product derivatization route and the like. The method comprises the following steps: by taking N-acyl diazene as a substrate, reacting the N-acyl diazene with trimethylsilyl cyanide under the action of alkali or a phosphine reagent to prepare the 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound. According to the method disclosed by the invention, the 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound is prepared in one step under the condition of room temperature. According to the preparation method of the 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound, the reaction process is greatly accelerated through selection of alkali and phosphine reagents and synergistic reasonable control of the ratio of various substances, efficient preparation of the 2-imido-3, 5-disubstituted-1, 3, 4-oxadiazole compound is achieved, the substrate is good in applicability, the ring is provided with an imine structure, and the application prospect is wider; the method can be widely applied to synthesis in the fields of medicines in academic circles and the like.
Owner:HARBIN UNIV OF SCI & TECH

Metathesis compositions comprising air stable imidoalkylene complexes

The present invention relates to a composition, each comprising a Srok-alkylene complex bearing a neutral ligand selected from the group consisting of 1, 10-phenanthroline and 2, 2 '-dipyridyl, and one or more compounds comprising an olefinic double bond. When the complex is not dissociated, the complex can be thermally activated to initiate a metathesis reaction in the composition. The invention also relates to a composition comprising a Srok-alkylene complex bearing a neutral 2, 2 '-bipyridine ligand, and one or more compounds comprising an olefinic double bond, in which the complexes are self-activating.
Owner:VERBIO AG