765 results about "M-Phenylenediamine" patented technology

The invention discloses a preparation method of an aromatic polyamide film modified by a ZIF-8 type metal-organic framework material. A ZIF-8 filling polyamide composite film is prepared on an ultrafiltration bottom film by an interfacial polymerization method, wherein nano-grade ZIF-8 particles are added into an m-phenylenediamine aqueous solution and/or a trimesoyl hexane solution; a polyamide ultrathin skin layer, to which ZIF-8 is added, is formed through interfacial polymerization. The preparation method has the advantages that by the use of a ZIF-8 nano-grade aperture and a three-dimensional multi-hole structure, the selectivity or the permeability of the aromatic polyamide film is improved; the prepared ZIF-8 filling polyamide composite film can serve as a nanofiltration or reverse osmosis film for removing organic matters from the aqueous solution; when the adding ratio of an organic phase or water phase solution, to which ZIF-8 is added, is 0.05-0.15% (w/v), the performance of the film is the highest, and the permeation flux and the retention rate can be increased at the same time; furthermore, the nanofiltration or reverse osmosis performance of the two-phase adding film is higher than that of a single-phase adding film.

The invention discloses a composite nanofiltration membrane based on a hydrophilic modified polyolefin microporous substrate and a preparation method thereof. The composite nanofiltration membrane comprises a substrate and a selective cortex formed on the substrate through an interfacial polymerization reaction, and the substrate is a polyolefin microporous membrane subjected to hydrophilic modification through sedimentation; the selective cortex is formed by the interfacial polymerization reaction of an aqueous phase monomer and an oil phase monomer on the surface of the substrate; the aqueous phase monomer is at least one of piperazine, m-phenylenediamine and o-phenylenediamine; and the oil phase monomer is trimesoyl chloride. The substrate of the composite nanofiltration membrane is the polyolefin microporous membrane subjected to the hydrophilic modification through the sedimentation, a formed hydrophilic layer is thin and uniform, the surface topography of the substrate is unchanged, and the selective cortex formed on the hydrophilic layer through the interfacial polymerization is dense, uniform and defect-free, so that water flux of the composite nanofiltration membrane is large; the polyolefin microporous substrate has good tolerance for organic solvents, so that the use range of the composite nanofiltration membrane is improved.

The invention relates to a method for spinning aramid fiber 1313 with low salt content by wet spinning. The method comprises the following steps of: prepolymerizing m-phenylenediamine (MPD) and part m-phthaloyl chloride (IPC); adding the preformed polymer and the rest m-phthaloyl chloride into a double-screw extruder to extrude the aramid fiber 1313 containing chlorine hydride; extruding spinning dope into a aqueous coagulation bath after neutralizing the chlorine hydride with calcium hydroxide; crimping and cutting coagulated tows into the required fiber length via hot water drawing, water rinsing, drying, dry-heat drawing and heat setting after being taken out of the coagulation bath to receive a finished fiber. The method is convenient and simple, can improve the molecular weight of products and the evenness of polycondensate, and reduce the salt content of the final spinning solution.

The invention discloses a method for preparing graphene aerogel and application thereof, and relates to the technical field of graphene materials. The method includes steps of uniformly mixing graphene oxide dispersion liquid and amine curing agents with one another to obtain graphene oxide mixed liquid; hermetically heating the obtained graphene oxide mixed liquid to obtain the graphene aerogel. The amine curing agents are one type of or a plurality of types of diaminodiphenyl-methane, diamino diphenyl sulfone, diethylenetriamine, triethylenetetramine, diethylaminopropylamine and m-phenylenediamine. The graphene aerogel prepared by the aid of the method can be applied to epoxy resin, so that graphene aerogel/epoxy resin composite materials with high conductivity and excellent mechanical properties can be obtained. The method and the application have the advantages that the graphene aerogel prepared by the aid of the method is internally of a uniform macroporous structure and is high in porosity; the amine curing agents are adopted in preparation procedures, accordingly, the epoxy resin interface bonding can be improved, and the conductivity and the mechanical properties of the epoxy resin can be enhanced.

The invention discloses a preparation method of a reverse osmosis membrane, and more particularly relates to a high-desalting-rate and high-flux reverse osmosis membrane with extreme convenience in rinsing treatment and a preparation method of the high-desalting-rate and high-flux reverse osmosis membrane. According to the invention, a porous polysulfone support layer is provided with a functional compact composite layer which is a m-phenylenediamine aqueous solution formed by organic acid or an aquo-complex thereof, which contains one or more than one hydroxyl, and organic alkali in a buffer salt system, and the porous polysulfone support layer is subjected to polycondensation together with an organic solvent solution of trimesoyl chloride containing a certain amount of additives on the surface of the porous polysulfone support layer. The preparation method of the reverse osmosis membrane has the advantages that the required rinsing treatment technology is mild, simple and efficient; the total residual amount of the unreacted amine in the membrane after rinsing is low, and industrial continuous rapid preparation can be realized easily.

The invention relates to a cross-linked sulfonated polysulfone/polyether sulfone-sulfonated polysulfone composite membrane and a manufacturing method of the cross-linked sulfonated polysulfone/polyether sulfone-sulfonated polysulfone composite membrane. Polyhydroxyl or multi-amino or hyperbranched substances are selected, a polyether sulfone/sulfonated polysulfone blended ultra-filtration base membrane is coated with a cross-linked sulfonated polysulfone solution to manufacture the composite membrane, a composite membrane separation layer of which the thickness is 1 micrometer-10 micrometers is formed on the surface of the base membrane, the water contact angle of the surface of the composite membrane separation layer ranges from 40 degrees to 90 degrees, and the composite membrane separation layer has good osmosis and separation properties. The manufacturing method includes the steps that sulfonated polysulfone of different concentrations and sulfonation degrees, m-phenylenediamine, polyethylene glycol, dopamine, H30 and other cross-linking agents are dissolved in solvent to manufacture the coating solution, with the polyether sulfone/sulfonated polysulfone blended ultra-filtration being the base membrane, the composite membrane separation layer is manufactured under vacuum conditions, and finally the cross-linked sulfonated polysulfone/polyether sulfone-sulfonated polysulfone composite membrane which is hydrophilic is obtained. The manufactured composite membrane has the good osmosis and separation properties, and can be used for nanofiltration and forward osmosis processes and membrane separation processes including seawater desalting, waste water treatment, domestic water treatment and bio-separation.

The invention relates to a device and a method for continuously preparing a polyisophthaloyl metaphenylene diamine spinning solution and belongs to the field of high polymer materials. The method is characterized in that a polar solvent, m-phenylenediamine melt and m-phthaloyl chloride melt are continuously and simultaneously added into two twin-screw reactors which are connected in series in a specific proportion so as to continuously prepare the polyisophthaloyl metaphenylene diamine spinning solution. By the method, the mixing requirements at different polymerization stages can be met, and the problem of difficulty in heat radiation can be solved; the polyisophthaloyl metaphenylene diamine polymer which is prepared by a continuous production mode is narrow in molecular weight distribution and stable in intrinsic viscosity; and when the intrinsic viscosity is more than 2.0dl/g, the continuous and stable spinning requirements of polyisophthaloyl metaphenylene diamine fibers can be met.

The invention discloses a production method of a meta-position aramid paper fibrid. The production method comprises the following steps of: polymerizing m-phenylenediamine and isophthaloyl chloride in DMAC (M, N-dimethylacetamide) to form PMIA (polyisophthaloyl metaphenylene diamine) resin); producing hydrogen chloride gas by a neutralization reaction; diluting the resin, dispersing in a mother liquor and precipitating to obtain a fibrid suspending liquid in accordance with the manufacturing conditions of the meta-position aramid paper; pumping the fibrid suspending liquid and deionized water into a washing and filtering machine, and removing the solvent, additive and moisture containing in the fibrid to obtain the fibrid in accordance with the manufacturing conditions of the meta-position aramid paper. The method has advantages of low cost, high efficiency, stable process, simple used equipment and suitability for sustainable industrial production.

The invention relates to epoxy-phenolic-titanium-structure amine nanometer compound temperature resistant heavy anti-corrosive paint and a preparation method thereof. The paint has the following formulation: 30-40 parts of epoxy phenolic resin, 5-10 parts of nanometer compound mother solution, 6-8 parts of intensified carbon fiber, 20-23 of titanium pigment, 9-12 parts of ceramic powder, 15-25 parts of mixed solvent which are well mixed according to the proportion, dispersed and ground till grain diameter is under 40mum to prepare the component A; compound firming agent comprising 4, 4'-diamino sulfobenzide, lentine and phenol-aldehyde amine and mixed solvent are prepared to form the component B; and then the component A and the component B are blended, heated and solidified for 1-3 hours to form the heavy anti-corrosive nanometer compound paint. The coating with the 0.1-1.0 mm thickness can resist the corrosion destruction of strong corrosive medium containing sulfureted hydrogen, sulfur dioxide, carbon dioxide, chloride and the like in the temperature of 80-150 DEG C and in the 1-40 high atmospheric pressure, solves the problems of high temperature acidity deep-etching in industries such as petrifaction, metallurgy, electrical powder and coal and the like, and effectively protect metal materials.

The invention discloses a core shell catalyst by taking hydrotalcite as a shell and a molecular sieve as a core as well as a preparation and an application thereof. According to the invention, divalent metal source and aluminum species in a core-shell molecular sieve are used for forming a hydrotalcite compound on the surface of the molecular sieve, and the core-shell structure molecular sieve by taking the molecular sieve as the core and the petal hydrotalcite as the shell is formed; after the molecular sieve is reduced, the nano-grade metal-modified molecular sieve catalyst having uniform size, high dispersibility, excellent heat stability and high universality is obtained, and can be used for a catalytic reaction for hydrogenation synthesis of m-dinitrobenzene to obtain m-phenylenediamine. compared with the prior art, the preparation process is simple, the metal atom utilization rate is high, applied metal source is almost completely reacted, no loss is generated, cost is reduced, and pollution on environment is reduced, industrial production is easy, and a series of different metal-modified molecular sieve catalysts can be prepared according to the modifiable character of the composition elements of the hydrotalcite and diversity of a topological structure of the molecular sieve.

The invention discloses a preparation method of a phase change energy storage paraffin microcapsule with multiple layers of capsule shells. The method comprises the following steps: 1, mixing a trimesoyl chloride active monomer with phase change paraffin, heating to form an oil phase liquid, adding the oil phase liquid to an aqueous emulsifier solution having a same temperature with the oil phase liquid, and adding an aqueous solution of an m-phenylenediamine cross-linking agent while stirring to prepare an oil-in-water emulsion; 2, continuously stirring the above paraffin microcapsule emulsion in a heat insulation state, adjusting the pH value of the paraffin microcapsule emulsion to be greater than 8.0 in the stirring process, centrifuging after the stirring ends, and washing with water; and 3, adding the above paraffin microcapsule with the inner layer capsule shell of polyamide to a trihydroxymethyl aminomethane-HCl buffer solution containing 4-(2-aminoethyl)-1,2-resorcinol, dipping while continuously stirring at room temperature, separating, washing with water, and drying. The energy storage paraffin microcapsule can prevent leakage of capsule core paraffin in the phase change process, has good endophilicity with water, and is in favor of transferring heat.

A high-flux composite reverse osmosis polyamide member features that on a supporting polysulfone membrane, there is a functional aromatic polyamide layer which is prepared from aromatic polyamine (the mixture of lentine and 5-sulfonyl lentine) and aromatic polyacyl chloride chosen from sym-phenyltrimethyl acyl chloride, 5-isocyanate-isophthalic chloride, meta-phenyldimethyl acyl chlorid, and their mixture.

A method for detecting 10 types of aromatic amines compounds (including aniline, ortho toluidine, m-toluidine, p-aminotoluene, m-phenylenediamine, m-methoxyaniline, 1- naphthylamine, 2- naphthylamine, 3- aminobphenyl and 4- aminobphenyl) in cigarette mainstream smoke by liquid chromatography-tandem mass spectrometry is characterized in that a Cambridge filter and an absorbing bottle containing 5%of HC1 solution respectively gather the aromatic amines compounds in a particle phase matter and a gas phase matter of mainstream smoke, after the 5%HCI solution is used for extracting the aromatic amines compounds on the filter, the aromatic amines compounds are purified by an HLB (hydrophile-lipophile balance) solid-phase extraction column, and a liquid chromatography-tandem mass spectrometry instrument is used for determining the 10 types of aromatic amines in the mainstream smoke in cigarettes. Compared with an existing GC-MS (gas chromatography-mass spectrometer) analysis method for detecting aromatic amines in mainstream smoke of cigarettes, the method does not need derivatization reaction or liquid-liquid extraction operation, greatly simplifies pretreatment steps of samples, improves analysis efficiency, and can more comprehensively detect harmful aromatic amines compounds in mainstream smoke of cigarettes.

This invention discloses a method for preparing flame-retardant epoxy resin nanocomposite. The method comprises: (1) mixing Na-montmorillonite, organic solvent aqueous solution and silane coupling agent into a reactor, heating to 40-100 deg.C, and reacting for 2-22 h to obtain organic montmorillonite; (2) utilizing 1-oxy-4-hydroxymethyl-2,6,7-trioxy-1-phosphabicyclo[2.2.2]octane, POCl3 and melamine as the raw materials to prepare (1-oxo-4-methylene-2,6,7-trioxy-1-phosphabicyclo[2.2.2]octane)phosphate dimelamine salt flame retardant; (3) adding organic montmorillonite and flame retardant into a mixture of epoxy resin and curing agent m-phenylenediamine, and curing at 80-160 deg.C for 6-12 h to obtain flame-retardant epoxy resin/organic montmorillonite nanocomposite. In the flame-retardant epoxy resin/organic montmorillonite nanocomposite, the flame retardant and organic montmorillonite have good synergistic effect. The flame-retardant epoxy resin nanocomposite has such advantages as low addition amount, good thermal and mechanical properties, and high flame retardancy.

The invention discloses a preparation method of a composite reverse osmosis membrane, and particularly relates to a preparation method of an organic acylating chlorination nanometer titania modified aramid composite reverse osmosis membrane. The preparation method comprises the following steps of: preparing organic phase solution of trimesoyl chloride; then adding acylating chlorination modified nanometer titania into the organic phase solution to prepare uniform suspension liquid; soaking backup polysulfone supporting membrane in m-phenylenediamine (MPD) aqueous solution with the mass concentration of 0.5% to 3%, wherein the aqueous solution contains sodium dodecyl sulfate (SDS); then rolling through a rubber roller to remove excessive solution; after drying the solution, contacting the dried solution with the organic phase solution that is subjected to ultrasonic dispersion just now for 10 to 120 seconds; and finally, drying the solution in vacuum to obtain the product. The preparation method of the composite reverse osmosis membrane disclosed by the invention has the advantages that a stable structure is formed in the reaction, therefore, the mechanical strength of the reverse osmosis membrane can be improved, and meanwhile, the flux of pure water of the membrane can be improved by virtue of nano particles while an original high salt removing rate is maintained. The preparation method is simple and is easy to implement.

A reverse-osmosis polyamide member is prepared through providing the aqueous solution of lentine and piperazine, immersing the porous carrier in it to have a liquid layer on it, and single-surface contacting with the organic solution of symphenyl triformyl chloride for interface polymerizing reaction. Said reverse osmosis membrane can be used to treat the saline for removing either impurity (SO4 ions) or NaCl in different condition, having high selectivity.

The invention relates to a preparation method of a low-voltage positive charge hollow fiber nanofiltration membrane and belongs to the technical field of membrane preparation. The preparation method comprises the following steps: firstly pretreating by immersing a hollow fiber ultrafilter membrane into distilled water; then successively adding carbon nanotube, m-phenylenediamine, a surfactant, an acid binding agent and a pH regulator into deionized water to prepare a water-phase solution with pH of 8-12; adding trimesoyl chloride into an organic solvent, mixing and dissolving to obtain an oil-phase solution; and finally carrying out a reaction by letting the hollow fiber membrane be contacted with the water-phase A solution, carrying out a reaction by letting the hollow fiber membrane be contacted with the oil-phase solution, drying and preserving so as to obtain the low-voltage positive charge hollow fiber nanofiltration membrane. The prepared nanofiltration membrane has advantages of high water flux, high separation efficiency of divalent saline ions and above, strong anti-pollution ability, long service life and the like.

The invention belongs to a method for producing phenylene diamine, in particular to the method for producing the phenylene diamine by performing hydrogenation reduction on mixed dinitrobenzene with palladium catalyst. The prior art which produces the phenylene diamine by performing the hydrogenation reduction by adopting a Raney nickel or carrier nickel catalyst has the disadvantages of high energy consumption, low raw material conversion rate, and poor product quality. The method comprises the following steps of: adding 100 weight parts of dinitrobenzene, 100 to 200 weight parts of alcohols solvents and 0.5 to 1 weight part of the palladium catalyst into a reaction kettle, wherein the temperature in the reaction kettle is between 40 and 60 DEG C and the pressure is between 0.25 and 0.60 MPa; performing hydrogenation for 30 to 120 minutes; conveying a reaction product to a filter; dealcoholizing in a dealcoholization tower for recovering to obtain phenylene diamine solution; and obtaining m-phenylenediamine, o-phenylenediamine and p-phenylenediamine products by dewatering, rectifying and separating. The method has the advantages of improving product quality, reducing raw material consumption and reducing production cost.

The invention relates to polyimide resin containing a furan ring and a preparation method of the polyimide resin. The polyimide resin containing the furan ring is obtained by reaction of 2,5-furan bis(formamide p-phenylenediamine) or 2,5-furan bis(formamide m-phenylenediamine) and dicarboxylic anhydride monomer, wherein the structural formula of the 2,5-furan bis(formamide m-phenylenediamine) is as shown in the description, and the structural formula of the 2,5-furan bis(formamide p-phenylenediamine) is as shown in the description; and the structural formula of the obtained polyimide resin containing the furan ring is as shown in the description, wherein X is a residue of the dicarboxylic anhydride monomer, and n is an integer greater than 0. The glass transition temperature of the obtained polyimide resin containing the furan ring is 250-400 DEG C, and the temperature is 420-500 DEG C under the condition of 5% of thermal degradation mass loss in a nitrogen gas environment; and the obtained polyimide resin containing the furan ring has higher usage temperature and thermal stability, has excellent mechanical properties and can be applied to many high and new technical fields of aerospace, space, micro-electronics, precision machinery and the like.

The invention relates to a micro-reaction system and a micro-reaction method for preparing para/meta-aramid. The micro-reaction system is composed of a micro-reactor and a stirring kettle, wherein the micro-reactor is internally provided with a microstructure distribution plate or a micro-channel; and sieve pores or through grooves are formed in the microstructure distribution plate. The method comprises the steps of dissolving p/m-phenylenediamine into a calcium chloride solution, and adding pyridine to obtain a reaction solution A; dissolving isophthaloyl dichloride/paraphthaloyl chloride into the calcium chloride solution to obtain a reaction solution B; mixing the reaction solutions A and B in the micro-reactor, and triggering condensation polymerization reaction to obtain a reaction solution C; enabling the reaction solution C to enter the stirring kettle, and reacting under stirring to produce a product D; and washing the product D to obtain para/meta-aramid. The material mixing effect is enhanced through the micro-reactor, so that reaction heat can be rapidly removed, and the process stability is improved; and due to the further reaction in the stirring kettle, the polymerization degree is further increased, the pressure drop in the reaction process is reduced, and the safety is improved.