A device for reducing radionuclide emission in extreme accidents of nuclear power plants comprises an adsorption tank, three water tanks, three electromagnetic valves, three float valves and a remote controller. The adsorption tank is filled with a high-temperature-resistant inorganic adsorption material is preset in a containment sump, the three water tanks filled with different solutions are preset in a containment, and the remote controller is mounted outside the containment of the nuclear power plant. The solution in the first water tank comprises, by weight, 0.5%-5% of strontium ions, 0.1%-2% of iodide ions, 0.1%-2% of tellurous acid radicals and the balance water or comprises, by weight, 0.5%-5% of strontium ions, 0.1%-2% of iodide ions, 0.1%-2% of tellurous acid radicals, 1%-4% of boric acid and the balance water. The solution in the second water tank comprises, by weight, 0.1%-4% of silver ions and the balance water or comprises, by weight, 0.1%-4% of silver ions, 1%-4% of boric acid and the balance water. The solution in the third water tank comprises, by weight, 0.5%-5% of sulfate radicals and the balance water or comprises, by weight, 0.5%-5% of sulfate radicals, 1%-4% of boric acid and the balance water.