The invention discloses a flexible bamboo
lignin-based
polymer material as well as a preparation method and application thereof.
Arginine modified
polyphenol bamboo
lignin and
lipoic acid are used as raw materials, and the flexible bamboo
lignin-based
polymer material with excellent performance is prepared through
lipoic acid ring opening polymerization and sulfydryl free radical-
polyphenol Michael
addition reaction. The preparation method specifically comprises the following steps: carrying out
demethylation phenolation modification on bamboo lignin by using a one-pot method,
grafting arginine, improving the reaction activity of the bamboo lignin, quantitatively introducing
lipoic acid, blocking by using allylurea, and synthesizing the bamboo lignin-based
polymer material containing the allylurea, wherein the polymer material contains a dynamic disulfide reversible ring-opening structure. The method breaks through the limitation that the existing lignin is low in reaction activity and lignin-based macromolecules are difficult to recycle, expands the application scene and range of the lignin, and realizes a green mode of oriented preparation, cyclic
processing and efficient utilization of the lignin-based macromolecules; and a theoretical basis and guiding significance are provided for high-quality development and high-valued frontier application of the
forest resource lignin.