The invention discloses a preparation method of cross-linked
cellulose fibers, and belongs to the technical field of
cellulose preparation. The method comprises the following steps that a cross-linking agent solution and a catalyst solution are added to
Lyocell fibers, preliminary curing is conducted under the first set temperature condition, the preliminarily cured
Lyocell fibers are obtained, in the cross-linking agent solution, the
mass percentage content of a cross-linking agent solute ranges from 0.1% to 10%, and the
mass percentage content is defined as a; in the catalyst solution, the value range of the
mass percentage content of a catalyst solute is (0-5%) * a; under the condition of a second set temperature, washing the cured
Lyocell fiber, changing the
electron cloud
density distribution of the cured Lyocell
fiber, and completing deep curing to obtain the deeply cured Lyocell
fiber; and carrying out post-treatment on the deeply cured Lyocell fiber, so as to obtain the cross-linked
cellulose fiber. The cross-linking limiting device can improve the uniformity of cross-linking limiting and the product quality.