71results about How to "Grain intact" patented technology

The invention discloses a low-temperature sintered high-permeability NiCuZn ferrite material for a wire wound chip inductor and a preparation method of the ferrite material. The ferrite material comprises the following main components based on oxide content: 40.5 to 49.6 moles percent of Fe2O3, 30 to 47 moles percent of ZnO, 5 to 20 moles percent of CuO and the balance of NiO. The preparation method comprises the following steps of: (1) mixing raw materials, (2) performing primary sanding, (3) performing primary spray drying and granulation, (4) pre-sintering, (5) adding trace elements, (6) performing secondary sanding, (7) performing secondary spray drying and granulation, (8) molding and (9) sintering. By adding auxiliary components such as NaCO3, B2O3, Ta2O5 and the like, the sintering temperature is greatly reduced, the sintering temperature is below 900 DEG C, the high-frequency electromagnetic performance of the material is greatly improved, the sintering density of the material is improved, the mechanical strength of the material is improved, and the manufacturing process requirement of the wire wound chip inductor is met; and on the other hand, energy is saved, and the producing and manufacturing costs are greatly reduced. The initial permeability of the material is 2,850; the specific loss coefficient of the material is less than 5.5*10<-6> under the test conditions of 100 kHz and 0.25mT; and the specific loss coefficient of the material is less than 25.6*10<-6> under the test conditions of 500 kHz and 0.25mT.

The invention discloses a LaFeSi-based magnetic refrigeration material as well as a preparation method and application thereof. The chemical formula of the refrigeration material is La1+aFe13-b-cCobSicHd and the refrigeration material comprises a NaZn13 structural phase, wherein a is greater than 0 but less than or equal to 1, b is greater than or equal to 0 but less than or equal to 1.2, c is greater than or equal to 1.0 but less than or equal to 1.8 and d is greater than or equal to 0 but less than or equal to 3. The preparation method comprises the following steps: preparing raw materials according to the chemical formula and smelting in the presence of high-purity inert gas to obtain an alloy ingot with uniform components; annealing the alloy ingot in the presence of high-purity inert gas and then quickly quenching to obtain the La(Fe, Co, Si)13-based block magnetic refrigeration material containing the NaZn13 structural phase; and furthermore, introducing hydrogen into the block magnetic refrigeration material. According to the block magnetic refrigeration material, the forming period of a magnetic thermal phase is obviously shortened. The material before hydrogenation needs not to be mechanically crushed to small particles, and the block can be fully hydrogenated to be saturated. The material has a huge magnetocaloric effect and low hysteresis, so that the material is an ideal near room-temperature magnetic refrigeration working material.

A low-temp sintered AIN-base composition is prepared from AIN (50-80 wt%), lead borosilicate glass (15-50), and LiF (rest) through hot pressing and sinter, including heating and pressurizing by threestages, and holding temp at 950 or 1000 deg.C under 18-25 MPa for 2-8 hr. Its advantages include low sinter temp and density, high heat conductivity (11 W/m.k) and low cost.

The invention discloses a diamond micro-channel Cu-based CVD diamond heat sink sheet and a preparation method thereof. The diamond micro-channel Cu-based CVD diamond heat sink sheet sequentially comprises a Cu substrate, a micro-through-hole template and a CVD diamond film from bottom to top, wherein the Cu substrate and the micro-through-hole template are provided with nano-diamond particles therebetween, the Cu substrate is embedded with a diamond micro-channel array, the diameter of each diamond micro-channel ranges from 0.3mm to 0.5mm, and the distance between every two micro-channels ranges from 2mm to 3mm. The heat dissipation effect of the heat sink sheet is superior to that of traditional heat sink sheets such as Ag, Cu and Al; the heat dissipation performance of the micro-channelCu-based diamond heat sink sheet is better; the nucleation density and the growth rate of diamond in the micro-through-hole are greatly improved; and the CVD selective growth of the diamond film is realized in the micro-through holes.

The invention discloses a method for producing roll collars by recycling tungsten carbide from waste hard alloy roll collars. The method includes the steps: recycling coarse-grain tungsten carbide serving as a raw material from the waste hard alloy roll collars, mixing the coarse-grain tungsten carbide with other raw materials according to a formula of the roll collars, placing the mixture into a rotary mill, adding industrial alcohol which has alcohol content more than 95.5% and account for 13.8%-15.7% of the weight of the raw materials into the mixture, milling the mixture for 22 to 24 hours, screening, drying, blending rubber, pressing, removing rubber, pressurizing 6MPa at the temperature ranging from 1410 DEG C to 1460 DEG C in a vacuum pressurizing sintering furnace for longer than 70min, and uncovering the furnace with the temperature not higher than 100 DEG C to obtain the hard alloy roll collars. The method is physical, pollution-free and low in cost, and the recycled tungsten carbide is complete in shape and unchanged in alloy property.

The invention relates to a method for repairing a waste lithium iron phosphate material. The method comprises the following steps: 1) measuring the contents of Li, Fe and P elements in the waste lithium iron phosphate material; 2) preparing a mixed solution containing lithium salt, ferric salt and phosphoric acid, adding the waste lithium iron phosphate material into the mixed solution according to a final stoichiometric ratio of Li:Fe:P of 0.75-1.25:1:1, stirring and mixing the components, and controlling the pH value of the mixed solution to be 5.5-8.5 by using ammonia water in the stirringprocess to obtain a mixture; 3) carrying out hydrothermal reaction on the mixture at 100-200 DEG C to obtain a lithium iron phosphate precursor, and 4) carrying out carbon coating reaction on the lithium iron phosphate precursor at 650-800 DEG C to obtain the repaired lithium iron phosphate battery material. The method realizes direct repair of the waste lithium iron phosphate battery positive electrode material.

The invention discloses a micro-through-hole Cu-based CVD diamond heat sink sheet and a preparation method thereof. The micro-through-hole Cu-based CVD diamond heat sink comprises a Cu substrate, a metal transition layer and a CVD diamond film which are arranged in order from bottom to top, and micro-through-holes with the diameter ranging from 0.3 mm to 0.5 mm and the spacing ranging from 2 mm to3 mm are distributed in the Cu substrate in an array mode; and diamond nanoparticles are electrostatically assembled on the surface of the metal transition layer. The heat dissipation effect of the heat sink sheet is better than that of traditional heat sink sheets such as Ag, Cu and Al, and the adhesion between a diamond film and a Cu metal substrate and the nucleation density of diamond are improved; and the heat dissipation performance of the micro-channel Cu-based diamond heat sink sheet is better.

The invention discloses a boron-doped diamond electrode with an ultrahigh specific surface area as well as a preparation method and application of the boron-doped diamond electrode. The boron-doped diamond electrode comprises a substrate and an electrode working layer, wherein the electrode working layer is wrapped on the surface of the substrate, and the substrate is polycrystalline silicon or monocrystalline silicon with a high specific surface area; the electrode working layer is a boron-doped diamond layer; the polycrystalline silicon with the high specific surface area is obtained by performing anisotropic etching or/and isotropic etching on the surface of the polycrystalline silicon; and the monocrystalline silicon with the high specific surface area is obtained by performing anisotropic etching on the surface of the monocrystalline silicon. The boron-doped diamond electrode is characterized in that the boron-doped diamond layer comprises a boron-doped diamond high-conductivity layer, a boron-doped diamond corrosion-resistant layer and a boron-doped diamond strong electrocatalytic activity layer which are different in boron content, and compared with a traditional plate electrode, the silicon-based boron-doped diamond electrode has the advantages of being low in cost and extremely high in specific surface area, and relatively high current intensity is provided by using relatively low current density, so that the a wide application prospect is provided.

The invention discloses a hydrogenation catalyst composition and a preparation method thereof. The hydrogenation catalyst composition comprises an aluminum oxide carrier, an active metal and an auxiliary agent, wherein the active metal is selected from one or more of VIII family and/or VIB family metallic elements, and the auxiliary agent is selected from one or two of silicon or zirconium; the concentration of silicon and/or zirconium in the catalyst, in the form of oxides, are gradually increased from centers to outer surfaces of catalyst particles, wherein the concentration of silicon and/or zirconium at a position of 1/3R of particles is 0.1-0.5wt%, the concentration of silicon and/or zirconium at a position of 2/3R is 0.5-1.0wt%, the concentration of silicon and/or zirconium at a position of R is 1.0-3.0wt%, and R is the semi-diameter of the catalyst particles by taking the center of the catalyst as an initial point. The catalyst prepared by adopting an impinging stream co-precipitation gel forming mode in the invention is centralized in particle size distribution, and has an ideal pore structure, and the auxiliary agent and the active metal are distributed in the catalyst in a gradient increase mode, so that the deactivation rate of the catalyst can be effectively reduced, and the desulfurization and denitrification capacities of the catalyst are improved.

A preparation method of a ZSM-5 molecular sieve is characterized in that the method comprises the following steps: allowing a first mixture obtained by uniformly mixing a silicon source, an alkali, crystal seeds and water to stay in a closed reaction kettle at a constant temperature of 150-200DEG C for 10h or below, adding a second mixture obtained by uniformly mixing an aluminum source, the alkali and water, carrying out hydrothermal crystallization on the above obtained third mixture in the closed reaction kettle at 140-180DEG C for 5-20h, and recovering the finally obtained product, wherein a molar ratio of M2O/SiO2 of the first mixture is 0.03-0.07, a molar ratio of H2O/SiO2 of the first mixture is 5-10, the addition amount of the crystal seeds is 1-10% of the weight of the silicon source calculated by silica, a molar ratio of SiO2/Al2O3 of the first mixture is 20-100, a molar ratio of M2O/SiO2 of the third mixture is 0.03-0.15, and a molar ratio of H2O/SiO2 of the third mixture is 5-15. The method has the advantages of no use of a template, high yield of a single kettle, and high silicon utilization rate.

The invention relates to a lead-free piezoceramic material with manganese doping with bismuth titanate sodium group and a preparation method thereof, belonging to the field of functional ceramics. The invention selects 80.15-84.61wt% of Bil/2Nal/2TiO3, 10.26-13.19wt% of Bil/2K1/2TiO3, 2.17-5.44wt% of BaTiO3 as the substrate, and takes 0.32-1.28wt% of MnCO3 as the doping material, controls the pre-synthesizing temperature to a range of 800-950 DEG C and preserves the temperature for 1-4 hours; and keeps the sintering temperature to a range of 1130-1190 DEG C and preserves the temperature for 1-4 hours to obtain the novel lead-free piezoceramics. The piezoceramics obtained by utilizing the method provided in the invention have the advantages of high piezoelectric constant (191) and mechanical quality factor (314), good microcosmic structure, complete growth of crystal particles. The lead-free piezoceramics provided in the invention can be used for manufacturing piezoelectric devices such as piezoelectric sensor and actuator and the like.

The invention belongs to the technical field of pigment synthesis and discloses a low-hexavalent-chromium precipitated copper and chromium black pigment as well as a preparation method and applicationthereof. The method comprises the following steps: (1) preparing a nitrate solution, preparing raw materials into the nitrate solution containing Cu<2+>, Cr<3+> and Fe<3+>; (2) preparing a combustionsolution, mixing the nitrate solution and auxiliary fuel to obtain the combustion solution; (3) carrying out low-temperature self-propagating combustion: after evaporating and concentrating the combustion solution, heating the solution in a heating device and initiating the self-propagating combustion; collecting a combustion product; (4) mixing and carrying out ball milling: carrying out the ball mixing on the combustion product and inorganic salt and mixing to obtain a mixture; (5) carrying out high-temperature calcining: putting the mixture into the heating device and carrying out the high-temperature calcining; (6) carrying out post-treatment: carrying out water washing on a product obtained by the high-temperature calcining and drying to obtain the copper and chromium black pigment.The copper and chromium black pigment prepared by the preparation method has the advantages of high purity, complete crystalline grains, good dispersity and low hexavalent chromium content; the pigment has a small average grain diameter which can reach 0.5mu m.

The invention discloses a hydrogenation catalyst composition and its preparation method. The hydrogenation catalyst composition comprises an alumina carrier, active metal and an auxiliary agent, wherein the active metal is one or more metals selected from VIII group and/or VIB group metallic elements; and the auxiliary agent is one or two elements selected from silicon or zirconium. Concentration of silicon or zirconium in the catalyst is metered according to oxide and gradually decreases from the catalyst granule center to the external surface. Content of silicon and/or zirconium at R of granules is 1.0-3.0 wt%; content of silicon and/or zirconium at 1/3 of R is 0.5-1.0 wt%, and content of silicon and/or zirconium at 2/3 of R is 0.1-0.5 wt%, wherein R is radius of catalyst granules with the catalyst center as the starting point. The catalyst prepared by an impinging stream co-precipitation gelling mode has the following advantages: particle size distribution is centralized; the catalyst has an ideal pore structure; contents of the auxiliary agent and the active metal in the catalyst are reduced gradiently; inactivation rate of the catalyst can be effectively reduced; and metal-removal and metal-holding capabilities of the catalyst are enhanced.

The invention discloses a thermal-shock-resisting soft magnetic ferrite material and a preparation method thereof. The thermal-shock-resisting soft magnetic ferrite material is characterized by comprising the following raw materials in parts by weight: 50 to 70 parts of iron sesquioxide, 10 to 20 parts of nickel oxide, 5 to 10 parts of zinc oxide, 0.5 to 0.8 part of copper oxide, 0.2 to 0.3 part of vanadium pentoxide, 0.1 to 0.3 part of polyvinylpyrrolidone, 0.4 to 1 part of saw dust, 0.02 to 0.06 part of sodium lignin sulfonate, 2 to 4 parts of organic silicon resin and an appropriate amount of deionized water. By adopting the copper oxide, a crystal grain is more complete, the tissue is compacter, the temperature property can be improved, the thermal shock resistance can be improved, and the magnetic hysteresis loss can be reduced; the vanadium pentoxide is transformed to liquid phase at high temperature and is sintered, and the crystal grain is refined, so that the crystal interface and porosity in the crystal grain can be reduced, the starting magnetic conductivity can be enhanced. The soft magnetic ferrite material has characteristics of high strength, high starting magnetic conductivity and high thermal shock resistance and is capable of meeting the miniaturization requirement of a surface-mounted product.

The invention discloses an alumina carrier and its preparation method. With the weight of the carrier as the basis, auxiliaries account for 2-5% when metered on the basis of oxide. The auxiliaries are one or two elements selected from silicon or zirconium; content of silicon or zirconium in alumina decreases progressively from the center of carrier particles to the external surface; content of silicon and/or zirconium at the particle center is 1.5-3.5 wt%; content of silicon and/or zirconium at 1/3 of R is 0.5-1.5 wt%; and content of silicon and/or zirconium at 2/3 of R is 0.1-0.5 wt%, wherein R is radius of the carrier particle with the alumina center as the starting point. The alumina carrier has high degree of crystallinity, complete crystalline grain and centralized particle size distribution. Distribution of the auxiliaries in alumina decreases gradiently. The alumina carrier is suitable for preparation of a hydrotreating catalyst with high demetalization and good metal-holding capabilities.