The invention provides a method for determining electrode reaction parameters. The method comprises the following steps: accessing three electrodes of a three-electrode system reaction device to an electrochemical workstation, measuring initial data by utilizing a cyclic voltammetry, processing the initial data to obtain electrochemical reaction parameters and data relationship graph; processing the initial data, namely, firstly reading files in batch, storing the read data by adopting a four-layer data structure, reading the information of temperature and scanning rate from a file name, correcting and preprocessing the data after all data is read and stored, drawing according to a result after the correction, judging the reaction type, and combining a computational formula to obtain the diffusion coefficient, reaction activating energy and rate constant data, and finally displaying the calculation result and graph. By adopting the method, the reaction kinetics and the thermodynamics parameters of the electrode can be conveniently measured, the determination period is greatly shortened, the overall workload is alleviated, the overall price is low, and the final calculation result and drawn graph can meet the majority of requirements.