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121 results about "Magnetic molecules" patented technology

A magnet is an object that has a magnetic field strong enough to influence other materials. The molecules in a magnet are aligned to all face one way, which gives the magnet its magnetic field. Sometimes the molecules can align permanently, making a permanent magnet.

Preparation of magnetic molecularly imprinted polymer and application in complex sample pre-processing

The present invention specifically adopts a simple method for preparing a molecularly imprinted polymer and directly applies the molecularly imprinted polymer to the extraction separation of trace substance in the complex sample pre-processing. The invention adopts a chemical coprecipitation method for preparing Fe3O4 magnetofluid. Then the surface of Fe3O4 magnetofluid is modified with oleic acid. The template molecules and functional monomers are realized with preassembling and are mixed with the cross linker and modified magnetofluid. Then the mixture is added into the polymer solvent containing dispersing agent. After the reaction is finished, magnetic field separation is executed. The polymer is dried after eluting the formwork molecules. A three-phase extraction system which is established on the base of magnetic molecularly imprinted polymer can be directly applied to the extraction separation of complex samples of food, environment and biological sample. The method of the invention has excellent selectivity and can eliminate the matrix interference in the sample. Furthermore as the polymer has excellent magnetism, the polymer can excellently realize the separation to the sample matrix after the extraction, and the polymer has broad application prospect in the complex sample pre-processing.
Owner:JILIN UNIV

Temperature-sensitive magnetic sulfadimidine molecular imprinted adsorbent as well as preparation method and application thereof

The invention discloses a temperature-sensitive magnetic sulfadimidine molecular imprinted adsorbent as well as a preparation method and application thereof, belonging to the technical field of preparation of environment functional materials. A gamma-Fe2O3/SiO2 magnetic composite material is prepared by using a sol-gel method and is subjected to vinyl modification by using 3-(methylacryloyloxy) trimethoxypropylsilane; with a vinyl-modified magnetic composite material (MPS (Modified Polystyrene)-gamma-Fe2O3/SiO2) as a substrate material, sulfadimidine as a template molecule, acrylamide as a functional monomer, N-isopropylacrylamide as a temperature-sensitive monomer, ethylene glycol-bis(methylacrylic acid) ester as a cross-linking agent and 2,2'-azobisisobutyronitrile as an initiator, a temperature-sensitive magnetic molecular imprinted polymer is prepared by using a free group polymerization process and is applied to selective recognition and separation of the sulfadimidine in an aqueous solution; and the obtained polymer has the advantages of remarkable heat and magnet stability, sensitive magnet and heat inducting effect, higher adsorption capacity, reversible adsorption/release function along with the temperature and remarkable recognition performance of a sulfadimidine molecule.
Owner:JIANGSU UNIV

Construction and application of impedance type electrochemical sensor based on molecularly imprinted polymer with magnetic surface

The invention discloses a construction method of an impedance type electrochemical sensor based on a molecularly imprinted polymer with a magnetic surface and an application of the sensor in protein detection, and belongs to the technical field of electrochemical sensing. The construction method comprises the following steps: synthesizing the molecularly imprinted polymer on the surface of a magnetic nano particle by taking hemoglobin as a template molecule and dopamine as a monomer and by using the self polymerization performance and the good adhesive capacity of the dopamine; eluting the hemoglobin, so as to prepare the molecularly imprinted polymer with the magnetic surface, wherein the molecularly imprinted polymer with the magnetic surface has the good identification effect on the hemoglobin; and fixing the polymer on the surface of a magnetic glassy carbon electrode under the action of a magnetic field, so as to construct a hemoglobin sensing interface based on the molecularly imprinted polymer with the magnetic surface, wherein the hemoglobin sensing interface based on the molecularly imprinted polymer with the magnetic surface is used for hemoglobin detection. The constructed electrochemical sensor based on the molecularly imprinted polymer with the magnetic surface is simple in method, high in hemoglobin detection sensitivity and good in selectivity.
Owner:NANCHANG UNIV

Method for preparing magnetic molecularly-imprinted adsorbent

The invention discloses a method for preparing a magnetic molecularly-imprinted adsorbent and belongs to the technical field of preparation of environment-friendly functional materials. The method comprises the following steps of dispersing nanometer chitosan particles serving as stable particles in a solution as a water phase; mixing toluene serving as an oil-phase solvent and a pore-forming agent, methyl methacrylate serving as a functional monomer, ethylene glycol di(methacrylate) serving as a crosslinking agent, 2,2'-azobisisobutyronitrile serving as an initiator and magnetic carrier oil acid-modified nanometer ferriferrous oxide and molecularly-imprinted erythromycin to obtain a mixture serving as an oil phase; mixing the oil phase and the water phase to form a stable Pickering emulsion, preparing magnetically imprinted polymer microspheres by virtue of heat-induced reaction and applying the magnetically imprinted polymer microspheres in the adsorption and separation of erythromycin in an aqueous solution. The product has the imprinted hole and magnetic characteristics and is conducive to specific adsorption of target molecules, the magnetic carrier is conducive to the separation of the adsorbent and internal imprints can prevent the automatic falling and magnetic flux leakage of the target molecules after the target molecules are adsorbed and a better absorption effect is achieved.
Owner:CHANGZHOU UNIV

Magnetic molecular targeted ultrasound contrast agent microsphere and preparation method thereof

The invention relates to a novel magnetic molecular targeted ultrasound contrast agent, in particular to a gas-wrapped magnetic liposome microsphere suspension with the mean diameter of 1-4 micrometers and a preparation method thereof. The preparation method of the magnetic molecular targeted ultrasound contrast agent microsphere comprises a condition that a lipid layer of the microsphere and/or the surface of the lipid layer contains (or connects) magnetic response materials. A contrast agent microsphere wall material contains phospholipids, polyethylene glycol (PEG), PEG phospholipid polymers, biotinylated and/or polypeptide modificatory PEG phospholipid polymer, poloxamer, ligands (monoclonal antibodies or polypeptide, and the like) and the magnetic response materials and/or avidin bridging materials, wherein the ligand (monoclonal antibodies or polypeptide, and the like) has specific affinity to target molecules, the wrapped gas is a fluorine carbon gas, and a solvent is an aqueous medium (distilled water). The invention also provides the preparation method of the magnetic molecular targeted ultrasound contrast agent microsphere, which comprises a condition that the specific ligand is connected with the microsphere in a covalence and avidin bridging way. The novel magnetic molecular targeted ultrasound contrast agent has good targeted developing effect, can be used for evaluating the change of vessel endothelial molecules of an arterious and venous system of an organic tissue and has good application prospect in treatment.
Owner:NANFANG HOSPITAL OF SOUTHERN MEDICAL UNIV

Preparation and application methods for novel magnetic molecular sieve adsorbent material

The invention relates to a preparation method for a novel magnetic molecular sieve adsorbent material which is used for removing antibiotic pollutants in water treatment, has good adsorption performance and can be easily separated by using a magnetic separation method. The preparation method comprises the following steps: mixing soluble manganese salt and ferric salt according to a mol ratio of 1: 2, adding alkali to neutralize an obtained mixture and then carrying out microwave-assisted hydro-thermal synthesis, crystallization, magnetic field separating, rinsing and drying so as to obtain a ferromanganese magnetic spinel material; adding prepared magnetic spinel into a mixed solution consisting of cetyltrimethylammonium bromide, ethanol, ammonia water and deionized water, carrying out ultrasonic and vigorous stirring, adding ethyl orthosilicate, then continuing stirring for a reaction and then successively carrying out pumping filtration, rinsing with pure water, drying under vacuum, grinding and calcining under the protection of nitrogen so as to prepare the novel magnetic molecular sieve adsorbent material. The magnetic molecular sieve adsorbent material has the characteristics of rapid adsorption, high efficiency magnetic separation and a high adsorption removal rate when used as an adsorbent for removal of tetracycline antibiotic pollutants like terramycin and aureomycin in waste water and is suitable for popularization and application.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

Pseudo template magnetic molecule imprinted polymer for pesticide residue detection of waterborne sample and application

The invention provides a pseudo template magnetic molecule imprinted polymer for pesticide residue detection of a waterborne sample. The polymer Fe3O4@MIPs is prepared by comprising the steps that oleic acid-coated Fe3O4 nanoparticles, pseudo template molecules and functional monomers MAA are added into pore-forming agents, and after self-assembly is performed, cross-linking agents EGDMA and initiating agents AIBN are added in the mixture; after the cross-linking agents EGDMA and the initiating agents AIBN are completely dissolved, the mixture is dropwise added into polyvinyl pyrrolidone water solutions to complete a polymerization reaction; after Fe3O4@MIPs containing the pseudo template molecules is separated through an external magnetic field, the pseudo template molecules are removed, vacuum drying is performed, and the polymer is prepared. According to the polymer, the Fe3O4 nanoparticles are coated with oleic acid, and therefore the agglomeration phenomenon in the Fe3O4 preparation process is effectively avoided; a molecular imprinting polymerization reaction is performed by taking a compound of which the structure is similar to that of target pesticide as the pseudo template molecules, and therefore the phenomenon that a high result or a false positive result caused by the template leakage problem is effectively avoided; the target pesticide is easily and quickly separated from and brought away from the liquid sample through the magnetism of the polymer; the polymer is high in selectivity, little in interference, easy to operate, capable of being reused after being eluted, suitable for being used in the waterborne sample and good in effect.
Owner:HUNAN AGRICULTURAL UNIV

Magnetic molecularly-imprinted polymer for identifying and enriching varieties of trace antibiotics and preparation method and application thereof

The invention discloses a magnetic molecularly-imprinted polymer for identifying and enriching varieties of trace antibiotics and a preparation method and application thereof. The method comprises the following steps of mixing multiple types of template molecules and functional monomers, then, carrying out prepolymerization, then, adding surface modified Fe3O4 magnetic fluid, a cross-linking agent and an initiating agent so as to carry out polymerization reaction, collecting a polymer, which is obtained after the polymerization reaction is ended, with a magnetic substance, eluting the template molecules, then, washing with deionized water, and then, drying, thus obtaining the magnetic molecularly-imprinted polymer for identifying and enriching various of trace antibiotics. According to the magnetic molecularly-imprinted polymer for identifying and enriching varieties of trace antibiotics and the preparation method and application thereof, the varieties of trace antibiotics can be selectively identified and enriched and quickly, simply and conveniently separated at one time, so that the cost and time are greatly reduced, the efficiency is effectively increased, and the magnetic molecularly-imprinted polymer has a broad application prospect in the pretreatment of complicated samples in the fields of food, environment and the like.
Owner:武夷学院

Magnetic field-induced preparation method of molecularly-imprinted magnetic enrichment material of trace quantity of chlorophenol pollutant molecules in seawater

InactiveCN104130441AAvoid easy reunionAvoid low magnetic contentOther chemical processesSeawater treatmentSolid phase extractionAmino functionalized
The invention discloses a magnetic field-induced preparation method of a molecularly-imprinted magnetic enrichment material of trace quantity of chlorophenol pollutant molecules in seawater. The preparation method comprises that under magnetic field induction, an epoxy group-functionalized magnetic polymer is prepared by suspension polymerization and in-situ oxidation, a chlorophenol environmental pollutant polyamine template molecule is obtained by an intermolecular hydrogen bonding self-assembling technology, an amino-functionalized magnetic molecularly-imprinted composite material bonding with the template molecule is prepared under magnetic field induction, and in the presence of an acid/alcohol extractant, through pH adjustment, the template molecule is eluted and the chlorophenol molecule-imprinted magnetic composite material is obtained. The preparation method has simple processes and a low cost and realizes uniform particle size distribution and stable properties of the desired product. The molecularly-imprinted magnetic enrichment material can realize high-efficiency and high-selectivity adsorption and removal of trace quantity of chlorophenol pollutants in seawater and can be used for base dispersion-magnetic solid phase extraction detection of trace quantity of chlorophenol pollutants in seawater.
Owner:NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG

Preparation method and application of magnetic 5A molecular sieve

The invention discloses a preparation method and application of a magnetic 5A molecular sieve. The method comprises the steps of adding FeCl2.4H2O and FeCl3.6H2O into water, performing ultrasonic agitation and heating, then adding NH3.H2O to obtain a solid-liquid mixture, then performing magnetic adsorption, washing and drying to obtain magnetic Fe3O4; using sodium aluminate as an aluminum source, sodium silicate asa silicon source, sodium hydroxide as a base source and water as a solvent, adding calcium chloride, citric acid and the magnetic Fe3O4, and preparing the 5A molecular sieve inan ultrasound field. According to the preparation method and application provided by the invention, the magnetic 5A molecular sieve is prepared by usingultrasonic heating and adding an auxiliary agent, the magnetic molecular sieve has the advantages of high specific surface area, strong adsorption property, easinessin separation from the reaction liquid through additionally added magnetic field and the like. The synergistic effect of the ultrasonic wave and the auxiliary agent on the preparation of the magnetic 5A molecular sieve can increase the chemical reaction speed, save energy and protect the environment, and make the prepared magnetic 5A molecular sieve uniform in particle size and regular in morphology.
Owner:XIAN UNIV OF SCI & TECH

Method for removing drugs in soil by utilizing magnetism molecular imprinting-electromagnetism grating combination

The invention relates to a method for removing drugs in soil by utilizing magnetism molecular imprinting-electromagnetism grating combination. The drugs are one or more of carbamazepine, clofibric acid or diclofenac. The method comprises the following specific steps of: fully mixing preprocessed soil and a magnetism molecularly imprinted polymer, absorbing the drugs in the soil on the surface of the magnetism molecular imprinting, and separating the water soil and the magnetism molecularly imprinted polymer after reaction through an electromagnetism grid; and absorbing the magnetism molecular imprinting on the grid through a magnetic field generated by the electromagnetism grid after electrification, and effectively separating the magnetism molecular imprinting and the grid. The method provided by the invention has the advantages that the operation is simple, the effect is obvious, the arbamazepine, the clofibric acid and the diclofenac and the like in the soil are removed in one time, the drugs absorbed on the magnetism molecular imprinting are recovered and separated through the electromagnetism grid; a magnetism molecular imprinting technology is utilized to restore the soil polluted by the drugs and has the advantages that the cost is low, the restoring efficiency is high and the like; and an electromagnetism grid device is utilized to recycle the resources, so that secondary pollution is not caused.
Owner:TONGJI UNIV

Preparation method and application of mixed five-template magnetic imprinted polymer

The invention discloses a suspension polymerization preparation method of a mixed five-plate magnetic imprinted polymer. The method comprises preparation, modification of magnetic microspheres, preparation of a polyvinyl alcohol dispersant, dissolution, prepolymerization, polymerization, template molecular elution and drying. The preparation method uses five substances as template materials, addsmodified magnetic microspheres in the polymerization process and synthesizes magnetic molecularly imprinted polymer for specifically recognizing a triazole substance, a pyrethroid substance, a triazine substance, a carbamate substance and a phenyl urea substance by a suspension polymerization method. In the method, the preparation conditions are easy to be controlled, and the prepared polymer hasgood stability, high strength, acid and alkali resistance, no need of grinding and column packing, and can adsorb a plurality of substances at the same time, and has high adsorption efficiency. The method is suitable for the preparation of mixed five-template magnetic imprinted polymer microspheres, and the prepared product can be further used for the separation and enrichment of samples during simultaneous analysis of the plurality of pesticide residues in food, feed and other samples.
Owner:HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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