The invention provides a method for preparing an aluminum-
silicon-iron
alloy by virtue of aluminum-ash pre-treatment carbothermic reduction. The method comprises the following steps that secondary aluminum ash, waste
cathode carbon blocks and paper pulp
dry powder are uniformly mixed and are made into
powder, then the mixture is pressed into
pellets, and is subjected to high-temperature
vacuum distillation, so that
fluoride and
chloride in the aluminum ash as well as
fluoride and
metal sodium in the waste
cathode carbon blocks are volatilized and then are separated from the aluminum ash and the waste
cathode carbon blocks respectively, and meanwhile,
cyanide in the waste cathode carbon blocks is decomposed; then
distillation residues are smashed, the smashed
distillation residues are matched and mixed with
fly ash, high-temperature reduction is conducted on a material mainly composed of aluminum
oxide and
silicon dioxide in an
electric arc furnace by taking
fixed carbon in the waste cathode carbon blocks as a
reducing agent so as to prepare the aluminum-
silicon-iron
alloy with certain components; and meanwhile,
decomposition of aluminum
nitride in the aluminum ash and complete
decomposition of the
cyanide in the waste cathode carbon blocks are completed in the high-temperature reduction process, and the comprehensive utilization of various kinds of dangerous waste and
solid waste is realized in the same process.