The invention discloses a nerve-like
nitrogen-
doped carbon confinement multi-component
composite material for
lithium-
sulfur battery diaphragm modification and a preparation method, and relates to the technical field of
lithium-
sulfur batteries. The
composite material comprises a three-dimensionally connected nerve-like
nitrogen-
doped carbon network and
metal carbide nanoparticles confined at network nodes, the nerve-like
nitrogen-
doped carbon network is composed of
carbon fibers and nodes which are connected with each other, the
diameter of the nodes is larger than that of the
carbon fibers, and the
metal carbide nano-particles are wrapped by the graphitized nitrogen-doped
carbon layer and embedded and combined at the nodes. The preparation method comprises the steps of precursor solution preparation, hydrothermal self-
assembly,
freeze drying and segmented heat treatment. According to the invention, the neural
network structure is constructed and the
metal carbide nanoparticles are confined in situ at the nodes, so that the
physical barrier,
chemical adsorption and catalytic conversion of
polysulfide are realized, the shuttle effect is favorably inhibited, and the
cycling stability and rate capability of the
lithium-
sulfur battery are improved.