The invention provides a wave spectrum and energy spectrum composite type X-ray fluorescence spectrophotometer. The wave spectrum and energy spectrum composite type X-ray fluorescence spectrophotometer comprises an X-ray source, a light filter switching mechanism, a sample moving platform, a sample cup, a diaphragm switching mechanism, a primary collimator switching mechanism, a dispersive crystalswitching mechanism, a secondary collimator switching mechanism, a gasflow type proportional counter, a scintillation counter, an SDD detector, a main control panel and a PC machine. The wave spectrum and energy spectrum composite type X-ray fluorescence spectrophotometer has the following advantages: detection or point/face scanning can be rapidly completed by using an energy spectrum function when the sample is subjected to integrated component analysis and distribution analysis, and the whole body or certain area of the sample can be subjected to element analysis and distribution analysisby a wave spectrum function, so that organic combination of the wave spectrum and energy wave spectrum functions is realized, the two functions can be applied to integrated element component analysisand distribution analysis of the sample, the characteristics of high resolution, rapidness, flexibility and combinability are achieved, the reliability of the analysis result can be improved and the detection efficiency can be improved obviously.