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75results about How to "Not easy to emulsify" patented technology

Extraction liquid for synchronously extracting flavone and polysaccharide of taxus chinensis and method thereof

The invention belongs to the technical field of extraction and separation of flavone and polysaccharide active ingredients in plants, and particularly relates to an extraction liquid for synchronously extracting flavone and polysaccharide of taxus chinensis and a method thereof. The method comprises the following steps of using crushed branches and leaves of taxus chinensis as raw material; under the synergetic action of ultrasonic wave and microwave, extracting and separating flavone and polysaccharide by a novel double-water phase system which is built by ionic liquid, inorganic salt and water; extracting and separating a flavone compound from an upper ionic liquid phase by an organic solvent, and recycling the ionic liquid and the organic solvent; obtaining a polysaccharide compound from a lower inorganic salt water phase by dialysis, and alcohol precipitation. The method has the advantages that the extraction efficiency is high, the separation condition is moderate, the green and environment-friendly effects of extracting solvent are realized, the recycling degree is high, and the like; the method is suitable for industrialized synchronous separation of flavone and polysaccharide compounds.
Owner:INST OF APPLIED CHEM JIANGXI ACAD OF SCI

Method for extracting hydroxyacetic acid from water solution mixture containing hydroxyacetic acid

The invention discloses a method of extracting glycolic acid from water solution mixture containing the glycolic acid. The method has the following steps: synergistic extraction agent is delivered into an extraction column from the bottom, the water solution mixture containing the glycolic acid is delivered into the extraction column from the top, extraction phase after extraction flows out of the upper part of the extraction column, and raffinate phase after extraction flows out of the lower part of the extraction column; the extraction phase flowing out of the upper part of the extraction column is delivered into a back-extraction column from the bottom; back-extraction water is delivered into the back-extraction column from the top of the back-extraction column; back-extraction water phase which flows out of the lower part of the back-extraction column is concentrated to obtain the glycolic acid; back-extraction organic phase flows out of the upper part of the back-extraction column. The method has the advantages that the technological process is simpler, the capacity of the organic phase is large, the production capacity of equipment is high, the extractant regeneration is convenient, the energy consumption during the process is small, and the manufacturing cost is low; the volatility of the extractant is small without toxicity, the emulsification is hard, the misphasing speed is high, and the separative efficiency is high; the operation is convenient and stable, and the product quality is high.
Owner:EAST CHINA UNIV OF SCI & TECH

Analysis method for simultaneous determination of 6 kinds of trace phenol environmental endocrine disrupting chemicals in solid environmental sample

The invention discloses an analysis method for simultaneous determination of 6 kinds of trace phenol environmental endocrine disrupting chemicals (EDCs) in a solid environmental sample. The method comprises the steps: carrying out microwave-assisted extraction and gel permeation chromatography purification and the like, after solid-phase extraction, concentrating with a rotary evaporimeter, then blowing to dry with moderate nitrogen, adding BSTFA and pyridine, carrying out trimethyl silylation treatment on hydroxyls of the phenol EDCs, and finally analyzing by using GC-MS. Through sample concentration, purification, derivatization and other processes, a chromatographic peak pattern is improved, the detection limit and the impurity interference are reduced, the purification effect is improved, and the instrument analysis accuracy and sensitivity are increased. The method simplifies the operations, has the advantages of high efficiency, energy saving, short phase separation time, not easy emulsification in the extraction process, no pollution, simple operations and the like, and can well suitable for analysis determination of 6 kinds of typical trace phenol EDCs in the solid environmental sample.
Owner:SOUTHWEAT UNIV OF SCI & TECH

Method for removing petroleum acid in hydrocarbon oil by using membrane dispersion extractor

InactiveCN101200653ASmall amount of lye entrainmentLow lye entrainmentRefining by dialysisSolventChemistry
The present invention relates to a method of removing petroleum acid from hydrocarbon oil by a membrane dispersion extraction device. A continuous phase of the hydrocarbon oil is heated up to 10 DEG C to 150 DEG C; deacidification solvent dispersed phase is heated up to 10 DEG C to 90 DEG C; the cubage ratio of the continuous phase and the dispersed phase is 50 to 2 ®U 1; the pressure difference of the dispersed phase and the continuous phase is 0.05MPa to 0.4MPa; the flow velocity of the dispersed phase deacidification solvent is 0.5 to 5L / <2> per hour; membrane aperture is 0.01 to 60 microns; the dispersed phase deacidification solvent is dispersed into continuous phase oil through membrane micropores; clean oil after the deacidification is obtained after sedimentation and separation. The deacidification solvent is 1 percent to 15 percent of ammonia, 20 percent to 70 percent of alcohol or 0.02 percent to 5 percent of petroleum acid or 0.004 percent to 1 percent of demulsifier and the water with the rest quantity. The contacting time of the oil and the solvent is short; mass transfer efficiency is high; the disposal capability is large; the extraction course is not emulsified easily; the hydrocarbon oil contains little alkali liquid; the device operation is convenient.
Owner:PETROCHINA CO LTD +1

Preparation method of total alkali of corydalis tuber, and corydalis tuber preparation and use thereof

The invention relates to a preparation method of total alkali of corydalis tuber, and a corydalis tuber preparation and use thereof. The preparation method of the total alkali of corydalis tuber, which is prepared by the invention, comprises: grinding, extracting and post-treatment, wherein the post-treatment comprises extracting ethyl acetate, concentrating, freezing and drying. In the invention, an ethyl acetate extracting method is adopted, so the recovery is easy, the recovery rate is high, the toxicity is low, the environment pollution is avoided, and ethyl acetate is an ideal solvent for industrial production; and the drawbacks of high volatility, low recovery rate, high production cost, and high toxicity to human beings and the environment of the conventional biological alkali extraction solvents which mainly are chloroform are overcome, and the production cost is reduced. The ethyl acetate extraction purity reaches over 80 percent. The invention also provides a corydalis tubertotal alkali preparation and the use of the corydalis tuber total alkali preparation in the preparation of medicines for treating gynecological diseases, in particular the use of the corydalis tuber total alkali preparation in the preparation of medicines for treating dysmenorrheal, abnormal menstruation or endometriosis.
Owner:傅宏征 +2

Method for extracting ursolic acid from Cynomorium songaricum by using eutectic solvent/salt aqueous two-phase system

The invention provides a method for extracting ursolic acid from Cynomorium songaricum by using a eutectic solvent/salt aqueous two-phase system. The method comprises the following steps: with the eutectic solvent/salt aqueous two-phase system as an extraction solvent, subjecting the powder of Cynomorium songaricum to ultrasonic extraction at first so as to obtain a eutectic solvent phase containing ursolic acid, then carrying out pre-extraction by using a reversed micelle solution, and carrying out standing for layering, wherein an upper phase is a reversed micelle phase containing ursolic acid; and adding absolute ethyl alcohol into the reversed micelle phase containing ursolic acid for extraction, then carrying out standing and layering, wherein a lower phase is an absolute ethyl alcohol phase containing ursolic acid, and subjecting the absolute ethyl alcohol phase containing ursolic acid to pressure-reduced concentration and vacuum drying so as to obtain ursolic acid powder. According to the invention, the eutectic solvent/salt aqueous two-phase system is employed for extraction of the powder of Cynomorium songaricum, and reversed micelle extraction is employed for separation of ursolic acid in the eutectic solvent, so the method has the characteristics of short phase-splitting time, low viscosity, small possibility of emulsification and the like; the eutectic solvent and the reversed micelle solvent can be cyclically utilized; and the method is low in extraction cost, high in the purity and yield of a ursolic acid product and is a green, highly-efficient and simple separation method.
Owner:NORTHWEST NORMAL UNIVERSITY

Method for grouping high-yttrium rare earth ore and separating yttrium oxide

ActiveCN110002487AAvoid problems with low separation factorsAvoid problems such as difficult to quickly analyzeRare earth metal oxides/hydroxidesRare earth metal compounds preparation/treatmentRare-earth elementIsooctyl alcohol
The invention relates to a method for grouping high-yttrium rare earth ore and separating yttrium oxide, and belongs to the technical field of rare earth extraction separation. The problem of restriction of industrial application by naphthenic acid replacement needed in the long-term process flow of separation of yttrium oxide from an existing naphthenic acid system and HAB mixed system and the problem of difficulty in rapid onsite analysis of the change of the concentrations of two extractants in the HAB system is solved. The system comprises the following steps: grouping erbium and thulium by a P507-isooctyl alcohol mixed system to obtain a high-yttrium concentrate and a thulium-ytterbium-lutetium concentrate, separating the high-yttrium concentrate and the thulium-ytterbium-lutetium concentrate to prepare lutetium oxide and other heavy rare earths, separating the high-yttrium concentrate by a carboxylic acid extractant HA-TBP mixed system to prepare yttrium oxide, and grouping the La to Er concentrate by adopting a P507 system to separate other single rare earth elements. The grouping and separating method has the advantages of advanced and reasonable process, short process flow, low production cost, strong adaptability, and easiness in operation control, has better comprehensive, technological and economic indicators than the naphthenic acid technology, and has practical application values.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Method for separating rare earth ions by extraction of liquid-liquid-liquid three-phase system

InactiveCN102382982BSpeed ​​up clarification and phase separationReduce usageProcess efficiency improvementInorganic electrolyteIonic liquid
The invention relates to a method for separating rare earth ions by extraction of a liquid-liquid-liquid three-phase system, and belongs to the technical field of rare earth extraction and separation. The method comprises the following steps of: adding a chemical complexing agent into an aqueous solution containing the rare earth ions, regulating the acidity of the solution, adding a water-soluble high polymer and an inorganic electrolyte salt, oscillating and mixing at room temperature, and obtaining a liquid phase system of upper and lower layers; adding a hydrophobic ionic liquid, fully mixing the solution at room temperature, and obtaining an insoluble three-liquid phase coexistence system of upper, middle and lower layers; and respectively taking the upper, middle and lower phases of the three-liquid phase system, and reclaiming the rare earth ions by using an electro-deposition method. According to the method, a volatile organic solvent is not used, so that the phase forming behavior and the phase separation process of the three-phase system are easily artificially controlled; and light, medium and heavy rare earth ions are selectively enriched or grouped and separated in three different liquid phases respectively. Compared with conventional oil-water two-phase separation, the method has the advantages that: the process flow is greatly simplified, the method is quick in phase separation and avoids emulsifying, and the hydrophilic and hydrophobic properties of the ionic liquid three-phase system are easily controlled.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Method for separating yttrium oxide from middle-yttrium europium-rich rare earth ore by grouping

ActiveCN109881005AAvoid problems with low separation factorsLow costRare earth metal compoundsProcess efficiency improvementLutetiumHolmium
The invention relates to a method for separating yttrium oxide from middle-yttrium europium-rich rare earth ore by grouping, and belongs to the field of rare earth extraction separation. The problem that the industrial application is limited due to the fact that the problems that naphthenic acid needs to be replaced in the long using process of the technological process of separating the yttrium oxide by an existing naphthenic acid system and an HAB mixed system and the difficulty of rapid analysis of the concentration changes of two extraction agents of the HAB system on the site is solved. The method comprises the steps that firstly, dysprosium and holmium grouping is carried out by adopting a P507 mixed system to obtain a yttrium-rich material 1 and light-medium rare earth enrichment, and single rare earth is separated from the light-medium rare earth enrichment by the P507 system; then the yttrium-rich material 1 is subjected to erbium and thulium grouping by adopting P507-isooctylalcohol and other mixed systems, a yttrium-rich material 2 and thulium-ytterbium-lutetium enrichment are obtained, and single heavy rare earth is separated from the thulium-ytterbium-lutetium enrichment; and finally, the yttrium oxide is separated and prepared by the yttrium-rich material 2 by adopting an HA-TBP mixed system. The grouping separating method has the advantages of advancement and reasonability, short technological process, low production cost, high adaptability, easy operation and control, and comprehensive technical and economic index performance is better than a naphthenic acid process, and practical application value is achieved.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI
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