The invention discloses an analysis method for simultaneous determination of 6 kinds of trace phenol environmental endocrine disrupting chemicals (EDCs) in a solid environmental sample. The method comprises the steps: carrying out microwave-assisted extraction and gel permeation chromatography purification and the like, after solid-phase extraction, concentrating with a rotary evaporimeter, then blowing to dry with moderate nitrogen, adding BSTFA and pyridine, carrying out trimethyl silylation treatment on hydroxyls of the phenol EDCs, and finally analyzing by using GC-MS. Through sample concentration, purification, derivatization and other processes, a chromatographic peak pattern is improved, the detection limit and the impurity interference are reduced, the purification effect is improved, and the instrument analysis accuracy and sensitivity are increased. The method simplifies the operations, has the advantages of high efficiency, energy saving, short phase separation time, not easy emulsification in the extraction process, no pollution, simple operations and the like, and can well suitable for analysis determination of 6 kinds of typical trace phenol EDCs in the solid environmental sample.