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48results about How to "Uniform and firm load" patented technology

Preparation method of TiO2/ZIF-8 composite photocatalyst

The invention relates to a preparation method of a TiO2-loaded composite photocatalyst. The method comprises the following steps: subjecting a mixed solution of a soluble zinc salt, 2-methylimidazoleand a first organic solvent to a heated reaction in an autoclave, subjecting 2-methylimidazole to deprotonation, self-assembling ZIF-8 from 2-methylimidazole and zinc ions, carrying out filtering, washing and drying, and then, carrying out grinding, so as to obtain ZIF-8 powder; subjecting a hydrolyzable titanium source to a hydrolysis reaction with water in a second organic solvent, so as to obtain a nano-titania containing first solution; concentrating the first solution to improve the concentration of nano-titania sol, so as to obtain a second solution; adding the ZIF-8 powder into the second solution, carrying out thorough mixing through ultrasonic oscillation, and carrying out filtering, washing and drying, thereby obtaining the TiO2 / ZIF-8 composite photocatalyst.
Owner:HUAIHUA UNIV

Mercury-free catalyst applied to stationery bed for preparing chloroethylene and preparation method thereof

The invention provides a mercury-free catalyst applied to stationery bed for preparing chloroethylene and a preparation method thereof. The catalyst takes activated carbon, pretreated by hydrochloric acid or sodium hydroxide water solution, as a carrier, and gold trichloride and ferric chloride as active components, and compared with the ordinary mercury-free catalyst, according to the preparation method of the catalyst, the gold trichloride is guaranteed not to be reduced and can be uniformly and firmly loaded on the surface of the activated carbon carrier by replacing nitrohydrochloric acid in the preparation of the catalyst with hydrogen peroxide and taking other metal chloride, capable of promoting the decomposition of the hydrogen peroxide, as auxiliaries. The catalyst has high activity and selectivity in the reaction of preparing chloroethylene in the stationery bed through acetylene hydrochlorination, and the preparation method is simple and efficient, and green and environment-friendly, and has important practical significance in the industrial application.
Owner:NANKAI UNIV

Attapulgite-graphite-like carbon nitride composite ceramic microfiltration membrane with photocatalytic performance and preparation method and application thereof

The invention relates to an attapulgite-graphite-like carbon nitride composite ceramic microfiltration membrane with photocatalytic performance and a preparation method thereof and belongs to the field of ceramic membranes. The method comprises the steps of preparing casting solution slurry from titanate coupling agent modified attapulgite and melamine; and preparing a wet membrane of the ceramic microfiltration membrane through a dip-coating method, airing at a room temperature and roasting to prepare the attapulgite-graphite-like carbon nitride composite ceramic microfiltration membrane. A separation layer of the ceramic microfiltration membrane is prepared from attapulgite fibers and graphite-like carbon nitride and the attapulgite fibers are disorderly stacked into the separation layer, so that relatively large total porosity and superficial area are provided for the separation layer; coupling of photocatalysis and separation processes can be achieved by using the photocatalytic performance of the graphite-like carbon nitride, and self-cleaning of the membrane is achieved; and the graphite-like carbon nitride is uniformly and dispersedly immobilized on the surface of attapulgite of the membrane through the chemical bonding effect, so that the disadvantages that granular graphite-like carbon nitride is easy to aggregate, difficult to separate and difficult to reuse in the using process are effectively avoided.
Owner:HUAIYIN TEACHERS COLLEGE

Broad-spectrum VOCs (Volatile Organic Compounds) catalytic combustion monolithic catalyst as well as preparation method and application thereof

The invention provides a broad-spectrum VOCs (Volatile Organic Compounds) catalytic combustion monolithic catalyst and belongs to the technical field of catalysts. The catalyst comprises monolithic cordierite honeycomb ceramic, an auxiliary agent coating and an active coating; the auxiliary agent coating is prepared from one of active aluminum oxide, lanthanum modified active aluminum oxide or cerium modified active aluminum oxide, a rare-earth oxide compound and a binding agent; the active coating comprises one or two of noble metal palladium or noble metal platinum. The invention further provides a preparation method and application of the catalyst. The broad-spectrum VOCs catalytic combustion monolithic catalyst provided by the invention has low ignition temperature and high conversionefficiency on methane, propane and common volatile organic compounds, such as benzene, toluene, xylol, acetone, methanol, ethanol, acetic acid and ethyl acetate; the broad-spectrum VOCs catalytic combustion monolithic catalyst has common applicability. The catalyst has low gas flow resistance, low concentration of the volatile organic compounds and a wide air speed application range.
Owner:SOUTHWEST RES & DESIGN INST OF CHEM IND

Nanofiber-based flexible array structure electrode and preparation method thereof

The invention relates to the technical field of electrochemical materials, in particular to a nanofiber-based flexible array structure electrode and a preparation method thereof. The nanofiber-based flexible array structure electrode is prepared from an inner layer spinning solution and an outer layer spinning solution through electrostatic spinning, carbonization, hydrothermal growth and electro-deposition, the inner layer spinning solution is prepared from polyacrylonitrile (PAN), purified terephthalic acid (PTA), acidized carbon nanotubes (AC-MWNTs) and a solvent, and the outer layer spinning solution is prepared from polyvinylpyrrolidone (PVP), inorganic zinc salt, PTA and a solvent. According to the preparation method of the nanofiber-based flexible array structure electrode, the flexibility of carbon fiber is improved, and ZnO can be directly added into a precursor in the coaxial spinning process, so that the outer surface of the carbon nanofiber is loaded with nano ZnO evenly and firmly, the seed crystal coating process is omitted, thus the method is simple, efficient, high in universality, low in cost and environmentally friendly, an obtained product integrates the flexiblecharacteristic and bimetallic pseudocapacitance performance, and can form an independent electrode.
Owner:HEBEI NINGFANG GRP

Method for preparing binary denitration sulfur-resistant catalyst-loaded filter material by using one-step in-situ synthesis method

The invention provides a method for preparing a binary denitration sulfur-resistant catalyst-loaded filter material by using a one-step in-situ synthesis method. The method provided by the invention is characterized in that the binary denitration sulfur-resistant catalyst-loaded filter material is prepared by taking a polyphenylene sulfide filter material treated by concentrated nitric acid as a catalyst carrier, potassium permanganate and cerous chloride heptahydrate as a catalyst precursor and deionized water is utilized as a solvent, and by using an in-situ polymerization method. The loaded filter material can be used as a dedusting agent and a denitration sulfur-resistant agent at the same time, and relatively good denitration sulfur-resistant performance can be achieved when the catalyst loading capacity is greater than 5mg / cm<2>.
Owner:厦门格锐特环保科技有限公司

Preparation method of TiO2 loaded nitric acid modified viscose-based activated carbon fiber cloth photocatalytic material

Belonging to the technical field of photocatalytic material preparation, the invention discloses a preparation method of a TiO2 loaded nitric acid modified viscose-based activated carbon fiber cloth photocatalytic material. The method includes the steps of: taking a viscose-based activated carbon fiber cloth, placing it in a nitric acid solution, conducting constant temperature treatment at 80 DEG C, carrying out washing and drying, thus obtaining a nitric acid modified viscose-based activated carbon fiber cloth; treating the dried viscose-based activated carbon fiber cloth, placing it into a TiO2 emulsion, performing ultrasonic immersing loading, and implementing drying, thus obtaining the TiO2 loaded nitric acid modified viscose-based activated carbon fiber cloth photocatalytic material. The photocatalytic material provided in the invention can be directly used for purifying decorated living rooms, new cars and other places. The preparation method of the TiO2 loaded nitric acid modified viscose-based activated carbon fiber cloth photocatalytic material in the invention has the advantages of low cost and simplicity, and has a reaction conversion rate enhanced by nearly 3 times.
Owner:ZHEJIANG UNIV

Method for preparing Pt-based catalyst by pulse electrodeposition under ultrasonic conditions

The invention discloses a method for preparing a Pt-based catalyst by pulse electrodeposition under ultrasonic conditions, and belongs to the technical field of electrodeposition. The method combinesadvantages of both pulse electrodeposition and ultrasonic conditions, and electrodeposits to prepare the Pt-based catalyst by separately preparing a desired salt solution as an electroplating solutionin an aqueous solution, an organic solvent or an ionic liquid, and using a carbon material as a carrier, and using a pulse power supply to set different pulse electrodeposition current densities, current on-off time ratios (ton / toff), temperatures and other process parameters. According to the invention, the method for preparing the Pt-based catalyst by combining the pulse electrodeposition withthe ultrasonic conditions is simple in process operation, environmentally-friendly and strong in condition controllability; and the prepared Pt-based catalyst is small in average particle size, largein specific surface area and firm to bond with the carrier.
Owner:DALIAN UNIV OF TECH

Composite nanofiltration membrane taking layered double hydroxides as modified templates and preparation method

The invention provides a composite nanofiltration membrane taking layered double hydroxides as modified templates and a preparation method, and relates to the technical field of separation membranes.The preparation method comprises the following steps: firstly, loading layered double hydroxides modified by polyphenol molecules on a support base membrane to form a modified support base membrane; and then carrying out interfacial polymerization reaction on the modified support base membrane. In the interfacial polymerization process, the loaded modified layered double hydroxides are favorable for forming an active separation layer with ultra-thin thickness and large effective area. Then, the modified layered double hydroxides are removed through acid solution etching, a large number of nanopores are formed in the connecting interface of the supporting base membrane and the active separation membrane, and the obtained composite nanofiltration membrane is excellent in separation performance and stable in structure and has industrial production and commercial application prospects.
Owner:XIAMEN UNIV OF TECH

Supported palladium-ultrathin CoNi-LDH (Layered Double Hydroxide) nanosheet composite material as well as preparation method and application thereof

The invention discloses a supported palladium-ultrathin CoNi-LDH (Layered Double Hydroxide) nanosheet composite material as well as a preparation method and application thereof. The preparation methodcomprises the following steps: firstly, preparing ultrathin CoNi-LDH nanosheets by using a one-step hydro-alcohol thermal-solvent method, and supporting noble metal Pd nanoparticles by the ultrathinCoNi-LDH nanosheets as a carrier so as to obtain the supported palladium-ultrathin CoNi-LDH nanosheet composite material. The composite material can be applied to an electrocatalytic ethanol oxidationreaction, and has the advantages of high mass activity, good stability, good anti-poisoning ability and the like. The advantages can be attributed to the following aspects: (1), the ultrathin carriercan provide a larger electrochemical activity area, good electrical conductivity, and good CO poisoning resisting ability; and (2), the Ni-based LDH carrier can remove carbonaceous intermediates nearPdNPs sites, the Co element which is highly dispersed in laminates can achieve uniform and solid loading of PdNPs and is beneficial to sufficient utilization of PdNPs, and thus catalytic activity andstability can be synergistically improved.
Owner:BEIJING UNIV OF CHEM TECH

In-situ supported denitration sulfur-resistant catalyst compound filter material and preparation method thereof

The invention discloses an in-situ supported denitration sulfur-resistant catalyst compound filter material and a preparation method thereof. The preparation method includes the steps: taking PPS (polyphenylene sulfite) needled felts as filter materials; performing surface pretreatment on the needled felt filter materials by the aid of sodium dodecyl benzene sulfonate; cladding filter fiber surfaces by the aid of pi-pi conjugation mechanisms, and adsorbing added cobalt ions to fiber material surfaces through electrostatic interaction; adding potassium dichromate to serve as oxidizing agents; performing oxidation-reduction reaction on PPS filter fiber surfaces, and forming Cr2O3 and CoOx catalysts on the fiber material surfaces in situ to form the compound filter material with an efficient denitration sulfur-resistant function. The method has the advantages that the method is simple in preparation process, environmentally friendly and low in production cost, the catalysts and filter materials are firmly combined and the like, the prepared compound filter material is excellent in low-temperature activity, has excellent denitration effect on nitrogen oxide in flue gas and high sulfur-resistant function and can solve the problems that a tail purification system is complicated, high in cost and the like in the prior art.
Owner:FUZHOU UNIV

Attapulgite for UV protection and preparation method thereof

The invention belongs to the field of nano-materials and inorganic non-metallic materials and relates to attapulgite for UV protection and a preparation method thereof. Attapulgite carries rutile-type nanometer titanium dioxide, aluminum hydroxide and fatty acid. The alkali activated attapulgite is conducive to uniform and firm immobilization of rutile-type nanometer titanium dioxide on the surface of attapulgite. The protection material has good light stability (weatherability), can be used for outdoor organic polymer material UV protection and does not discolor. The hydrophobicity of the material surface improves dispersibility and compatibility in a nonpolar organic system.
Owner:江苏纳欧新材料有限公司

Preparation method of nitrogen doped loaded Bi203/Si02 light catalyst

The invention provides a preparation method of a nitrogen doped loaded Bi2O3 / SiO2 light catalyst. Macroporous SiO2 serves as a carrier, and Bi2O3 is uniformly loaded in pore passages of SiO2 to form a Bi2O3 / SiO2 composite macroporous material, and then the nitrogen doped Bi2O3 / SiO2 visible light catalyst is prepared by a precipitation method. According to the method, macroporous SiO2 serves as the carrier, comprises a nano thin layer bent and extending three-dimensionally as a three-dimensional macroporous material, produces a capillary effect, achieves nanoscale dispersion of an absorbed substance and realizes more uniform and stable load of nitrogen and Bi2O3 to achieve efficient catalysis and recycling of the catalyst; and on the other hand, the SiO2 carrier serves as a catalyst and improves visible light catalysis capability of a material to a certain extent. Therefore, the nitrogen doped loaded Bi2O3 / SiO2 light catalyst prepared with the method has good visible light catalysis capability and absorption capability.
Owner:NINGBO DIYANG ELECTRONICS TECH

Biomass carbon dot/wood composite photocatalytic material and preparation method and application thereof

The invention discloses a preparation method of a biomass carbon dot / wood composite photocatalytic material. The preparation method comprises the following steps: S01, treating wood flour to obtain xylose, S02, taking the obtained xylose as a carbon source substance and thionyl chloride as a sulfur and chlorine co-doping agent, fully dissolving the xylose and the thionyl chloride into deionized water, uniformly mixing to form an initial substance, and then transferring the initial substance into a hydrothermal reaction kettle, S03, after the reaction of the initial substance is finished and the initial substance is cooled to room temperature, centrifuging the obtained reaction solution, transferring the centrifuged reaction solution into a cellulose dialysis bag for dialysis treatment, andfreeze-drying the purified biomass carbon dot solution to obtain a pure biomass carbon dot solid, and S04, loading the biomass carbon dots on the wood veneer. The invention further discloses the biomass carbon dot / wood composite photocatalytic material and an application thereof. According to the biomass carbon dot / wood composite photocatalytic material and the preparation method and applicationthereof, the preparation process is simple, industrial production can be realized, and the biomass carbon dot / wood composite photocatalytic material has the advantages of no pollution and recyclability.
Owner:NANJING FORESTRY UNIV

Composite catalytic filter material for degrading dioxin at low temperature and preparation method thereof

ActiveCN112044175AExcellent low temperature activity and selectivityImprove catalytic activity and resistance to chlorine poisoningDispersed particle filtrationCatalyst activation/preparationEnvironmental chemistryOxidation Activity
The invention discloses a composite catalytic filter material for degrading dioxin at low temperature and a preparation method thereof, and belongs to the technical field of waste incineration tail gas treatment. The composite catalytic filter material loaded with a VOx-MnCeOx three-way catalyst is prepared by taking a high-temperature-resistant filter material as a catalyst carrier and the stepsof filter material activation, in-situ precipitation, V active component impregnation and low-temperature plasma oxidation. The catalyst has the advantages that (1) the catalyst has excellent low-temperature activity and selectivity on catalytic degradation of dioxin; (2) the active component V with high activity and excellent chlorine poisoning resistance is added into the filter material, and the V active component is effectively oxidized through low-temperature plasma, so that the catalytic activity and the chlorine poisoning resistance are improved; and (3) the catalyst is uniformly and firmly loaded on the surface of the filter material through an in-situ precipitation method, the preparation conditions are mild, the original performance and stability of the filter material are maintained, and the service life is long.
Owner:ZHEJIANG UNIV

Anti-wrinkle skin tightening emulsion containing polypeptides

The invention discloses an anti-wrinkle skin tightening emulsion containing polypeptides. The emulsion contains snake venom peptide in a mass fraction of 0.05-0.1%, acetyl tetrapeptide-2 in a mass fraction of 0.05-0.15%, hexapeptide-11 in a mass fraction of 0.1-0.15%, and acetyl octapeptide-3 in a mass fraction of 0.1-0.2%. According to the anti-wrinkle skin tightening emulsion containing polypeptides, the polypeptides which have different action principles and influence different metabolic pathways are compounded, so that an anti-wrinkle effect with quick effect, wide application spectrum andlasting effect is achieved. Based on the anti-wrinkle skin tightening emulsion containing the Chang 'e compound anti-wrinkle polypeptides, the test shows that the anti-wrinkle effect is obvious.
Owner:HUBEI YANGGUANG SCI & TECHCAL MEDICINES

Functional denitration filter material prepared with ring opening polymerization method

ActiveCN107233795AThe protective film is thin but firmThe reaction synthesis method and operation are simpleOrganic-compounds/hydrides/coordination-complexes catalystsDispersed particle separationPre treatmentStrong acids
The invention provides a preparation technology for coating a filter material with an efficient denitration catalyst with a ring opening polymerization method. Firstly, a PPS (polyphenylene sulfide) filter material is pretreated with strong acid, so that more active oxygen-containing functional groups such as hydroxyl, carboxyl and the like are obtained on the surface. The PPS filter material can be used as a modified monomer due to existence of these oxygen-containing functional groups, then, acrylamide is uniformly dispersed on the PPS surface under the ultrasonic action, potassium permanganate is used as an initiator, a ring opening polymerization reaction is conducted on the PPS surface, meanwhile, a produced manganese catalyst firmly coats the PPS surface, and the compound filter material with the efficient denitration function is prepared.
Owner:FUZHOU UNIVERSITY

Composite filter material loaded with three-way denitrification and anti-sulfur catalyst in situ and preparation method thereof

The invention discloses a ternary denitration sulfur-resistant catalyst in-situ loaded compound filter material and a preparation method thereof. The preparation method includes: taking a polyphenylene sulfide filter material as a catalyst carrier, and adopting lauryl sodium sulfate for surface modification of a polyphenylene sulfide needled felt to activate the polyphenylene sulfide filter material; taking potassium permanganate, anhydrous ferric chloride and cerium trichloride heptahydrate as catalyst precursors and taking deionized water as a solvent to realize one-step in-situ loading of a MnO2-Fe2O3-CeOx catalyst on the surface of the activated polyphenylene sulfide filter material. The compound filter material is firm in combination of the catalyst and polyphenylene sulfide fibers, excellent in low-temperature activity and denitration effect on nitric oxides in smoke and great in sulfur resistance, and defects of high cost, complexity and the like of a tail purification system in the prior art can be overcome. The ternary denitration sulfur-resistant catalyst in-situ loaded compound filter material and the preparation method thereof have advantages of technical simplicity in preparation, environment friendliness, low production cost and promising application prospect.
Owner:FUZHOU UNIV

Arsenic removing apparatus for drinking water

The invention relates to the removal of arsenic in drinking water, in particular to a drinking-water arsenic-removing device which comprises a closed hollow cylinder; the upper part of the cylinder is provided with a water outlet, and the lower part of the cylinder is provided with a water inlet; two cylindrical filter elements are vertically arranged inside the cylinder in parallel; the bottom of the filter element on the right is communicated with the water inlet of the cylinder, and the top thereof is provided with a water outlet; the middle and upper part, the middle part and the middle and lower part of the filter element on the right are respectively provided with a detachable hole-born supporting board along radial direction; the three supporting boards divide the cavity in the filter element on the right into four parts which are a filter bed A, a filter bed B, a filter C and a filter D from top to bottom; the bottom of the filter element on the left is provided with a water inlet, and the top of the filter element on the left is communicated with the water outlet of the cylinder; and loaded drinking-water arsenic-removing nano-adsorbing agent is filled in the filter element on the left. The arsenic-removing device has wide application range and can reduce arsenic content in the drinking water to safe standard, thus being suitable for the drinking requirement of scattered towns and citizens.
Owner:SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI

Photocatalytic net for water purification and its preparation and application

The invention relates to water purification materials and their preparation, in particular to photocatalytic nets for water purification and their preparation and application. The photocatalytic net for water purification is composed of a net plate made of metal aluminum or aluminum alloy, an oxide film layer evenly distributed on the surface of the net plate, and a photocatalyst coating attached to the outer surface of the oxide film layer. The preparation includes pretreatment of the screen, oxidation treatment, surface cleaning of the base material, carrying out photocatalyst loading on the base material by vacuum evaporation, annealing treatment and the like. The invention solves the technical problems of poor stability of the photocatalytic layer and high production cost in the prior art. It has the advantages of good photocatalytic performance and mechanical strength, firm coating adhesion, and low production cost.
Owner:北京中环达生态科技有限公司

Quaternary ammonium salt disinfectant concentration detection chemical indicator card, mother liquor and preparation method of quaternary ammonium salt disinfectant concentration detection chemical indicator card

The invention discloses a quaternary ammonium salt disinfectant concentration detection chemical indicator card and a preparation method thereof. The chemical indicator card comprises absorbent paper loaded with color-changing reaction active matter and a PVC carrier strip, the absorbent paper is further loaded with adjuvants including a leveling agent, a color fixing agent and a pH buffering agent, and the adjuvants are mixed according to a certain preparation sequence. The color-changing reaction active matter, the leveling agent, the color fixing agent and the pH buffering agent are firstly prepared into mother liquor, then the absorbent paper is soaked in the mother liquor, dried and pasted to the PVC carrier strip, and the chemical indicator card for detecting the concentration of the quaternary ammonium salt disinfectant is obtained and can be used for rapidly detecting the concentration of quaternary ammonium salt sterilization factors in the quaternary ammonium salt disinfectant. The invention is suitable for detection of sterilization factors when quaternary ammonium salt on the surface of an object in a hospital is disinfected, and the detection range is 0-1000 ppm.
Owner:HANGZHOU HYGEN HEALTH BIOTECHNOLOGY CO LTD

A kind of photolysis oxidative fission VOC treatment device

The invention relates to the technical field of waste-gas treatment and particularly relates to a device for photolytic oxidation treatment of VOC (Volatile Organic Compound) pollutants. The device comprises a reaction box body 1, a gas inlet 2, a catalyst layer 3, a catalytic light source 4 and a gas outlet 6, wherein the gas inlet 2 is positioned at the left and lower part of the reaction box body 1; the gas outlet 6 is arranged at the right and upper part of the reaction box body 1 and is higher than the catalytic layer 3; one or more catalyst layers 3 parallel to the bottom surface of thereaction box body 1 is / are arranged above the gas inlet 2; each catalyst layer 3 corresponds to a group of catalytic light sources 4 which are arranged above the corresponding catalyst layer 3. The device has the beneficial effects that by adoption of the photocatalyst prepared by a specific preparation method, a higher VOC treatment effect can be realized only by a simple device, and simultaneously certain treatment capability for heavy metal ions is achieved and the maintenance cost is low.
Owner:褚福友 +1

Multifunctional antibacterial and antiviral composite material and application thereof

The invention provides a multifunctional antibacterial and antiviral composite material and application thereof. The multifunctional antibacterial and antiviral composite material sequentially comprises rod-like cellulose nanocrystals, titanium dioxide growing on the surfaces of the rod-like cellulose nanocrystals and graphene nanosheets loaded on the surfaces of the titanium dioxide from inside to outside. The rod-like cellulose nanocrystal is used as a matrix, and the obtained rod-like semiconductor antibacterial and antiviral composite material has good dispersity and can be uniformly and firmly loaded on the surface of a fabric especially when being used for fabric modification. A layer structure formed by titanium dioxide and graphene nanosheets has good antibacterial, antiviral and photocatalytic formaldehyde removal effects; in addition, the material can be endowed with a friction power generation function, when the material is used for air filtration, under blowing of airflow and dust, friction is continuously performed to store charges, and the anti-virus and filtering performance of the charges is improved. Preferably, silicon dioxide also grows between the rod-like cellulose nanocrystals and the titanium dioxide, so that the filtering performance is further improved.
Owner:广东极客亮技术有限公司

A nanofiber-based flexible array electrode and its preparation method

The invention relates to the technical field of electrochemical materials, in particular to a nanofiber-based flexible array structure electrode and a preparation method thereof. The nanofiber-based flexible array structure electrode is prepared from an inner layer spinning solution and an outer layer spinning solution through electrostatic spinning, carbonization, hydrothermal growth and electro-deposition, the inner layer spinning solution is prepared from polyacrylonitrile (PAN), purified terephthalic acid (PTA), acidized carbon nanotubes (AC-MWNTs) and a solvent, and the outer layer spinning solution is prepared from polyvinylpyrrolidone (PVP), inorganic zinc salt, PTA and a solvent. According to the preparation method of the nanofiber-based flexible array structure electrode, the flexibility of carbon fiber is improved, and ZnO can be directly added into a precursor in the coaxial spinning process, so that the outer surface of the carbon nanofiber is loaded with nano ZnO evenly and firmly, the seed crystal coating process is omitted, thus the method is simple, efficient, high in universality, low in cost and environmentally friendly, an obtained product integrates the flexiblecharacteristic and bimetallic pseudocapacitance performance, and can form an independent electrode.
Owner:HEBEI NINGFANG GRP

A kind of preparation method and application of green titanium series polyester catalyst

The invention relates to a preparation method and application of a green titanium-based polyester catalyst, which is characterized in that it comprises the following steps: dissolving ethyl orthosilicate in absolute ethanol, adding an appropriate amount of acidified attapulgite, stirring evenly, and continuing to drip Add a mixed solution of titanium tetraisopropoxide and absolute ethanol, add dropwise a mixed solution of deionized water and absolute ethanol, heat in a water bath, hydrolyze for several hours, stop heating and stirring, wash with absolute ethanol, dry and grind to obtain It is a new type of green titanium-based catalyst. The advantage of the present invention is that the titanium oxide / silicon oxide / attapulgite composite titanium-based catalyst is prepared by the mixed hydrolysis method, and silicon oxide is used to suppress the crystallization of titanium oxide, and at the same time, the attapulgite is used as a carrier to improve the dispersion of titanium oxide and silicon oxide properties, making the activity of the catalyst more stable, thereby reducing the side reactions of the polyester and improving the hue of the polyester produced.
Owner:常州大学盱眙凹土研发中心

A kind of composite catalytic filter material for degrading dioxin at low temperature and preparation method thereof

The invention discloses a composite catalytic filter material for low-temperature degradation of dioxins and a preparation method thereof, belonging to the technical field of waste incineration tail gas treatment. The high-temperature-resistant filter material is used as a catalyst carrier, activated by the filter material, precipitated in situ, and impregnated with V active group and low-temperature plasma oxidation steps to prepare loaded VO x -MnCeO x Composite catalytic filter material for three-way catalyst. The advantages of the present invention are: (1) excellent low-temperature activity and selectivity for catalytic degradation of dioxins; (2) active component V with high activity and excellent chlorine poisoning resistance is added to the filter material, through Effectively oxidize V active components, improve catalytic activity and chlorine poisoning resistance; (3) achieve even and firm loading of the catalyst on the surface of the filter material by in-situ precipitation method, mild preparation conditions, maintain the original performance and stability of the filter material, long lasting.
Owner:ZHEJIANG UNIV
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