201 results about "Iron(II) sulfide" patented technology

The invention discloses a method for synchronously removing nitrogen and phosphorus in sewage containing nitrogen and phosphorus, belonging to the field of sewage treatment. The method comprises the steps of (1) screening thiobacillus denitrificans: screening thiobacillus denitrificans from anaerobic activated sludge and taking as target strain, wherein thiobacillus denitrificans utilizes sulphur source in ferrous sulfide to conduct autotrophic denitrification; (2) preparing fillers of a reactor: directly adding ferrous sulfide with the particle size smaller than 25mm in a reaction container; (3) adding sewage: feeding sewage to be treated into the reaction container, wherein the sewage to be treated is the sewage containing nitrogen and phosphorus with the pH value of 5.0-9.0; (4) conducting the autotrophic denitrification process: conducting the mixed reaction for 2 to 6d at the temperature of 10 DEG C-40 DEG C under the anaerobic condition in the reaction container, reducing NO2<-> and NO3<-> in water to be N2 by thiobacillus denitrificans while simultaneously oxidizing ferrous sulfide by thiobacillus denitrificans, and simultaneously, precipitating phosphorus in water by utilizing iron ions (being oxidation products); and (5) separating solid and liquid. According to the method, the technology for removing nitrogen by utilizing thiobacillus denitrificans and the technology for removing phosphorus by using iron ions are fused naturally, the reaction cost is low, and the processing effect is good.

The invention relates to an equipment cleaning agent which is used in the field of petroleum and chemical industry, in particular to a ferrous sulfide dirt neutral complexing cleaning agent which is used for washing a synthesized ammonia low-temperature methanol washing unit system in the petroleum chemical industry and the coal chemical industry. The ferrous sulfide dirt neutral complexing cleaning agent is prepared from the following raw materials in parts by weight: 5 to 8 parts of sodium gluconate, 7 to 11 parts of sodium salicylate, 20 to 26 parts of gadoliniam diethylene triamine pentaacetic acid, 20 to 26 parts of sodium ethylene diamine tetracetate, 40 to 46 parts of propenoic acid-itaconic acid copolymer, 25 to 32 parts of disodium polyepoxysuccinicate, 12 to 15 parts of sodium hydroxyphenylace, 3 to 7 parts of triethanolamine, 3 to 7 parts of hydrogen peroxide, 0.1 to 0.3 part of lauryl sodium sulfate, 0.1 to 0.3 part of polydimethyl siloxane fluid and 40 to 45 parts of water. The ferrous sulfide dirt neutral complexing cleaning agent is free from generating hydrogen sulfide when cleaning the ferrous sulfide dirt and corroding the equipment and has strong capacity for complexing the iron ions, the removal speed is fast, the decontamination rate is more than 98 percent, the neutralization and passivation are unnecessary to carry out after the chemical washing, and the equipment can be put into operation immediately.

The preparation method for battery grade ferrous sulfate heptahydrate crystal of the present invention includes using ferrous sulphate which is the by-product in the titanium dioxide production as raw material, using the operation of purification, filtration, crystallization and dryness, and preparing ferrous sulfate heptahydrate by using the difference of the solubility of ferrous sulphate changing with the temperature. The operation of purification includes performing reduction of ferric iron in ferrous sulphate which is the by-product in the titanium dioxide production to ferrous iron by using a reducing agent, adding ferrous sulfide to remove the heavy metal ions such as cobalt, nickel, zinc, copper, plumbum and cadmium, and using fluoride to remove calcium and magnesium ions. The preparation method uses vacuum drying and packaging, and the main content of ferrous sulfate heptahydrate in the dried material is more than 99.7%. The preparation method has simple technology and low cost, can recycle fluorinion by precipitation conversion, and can reduce the discharge of hazardous waste. Moreover, the prepared product has high purity, low impurity and ferric iron contents, and can be long-term storage. The recovery rate of ferrous sulphate is greatly improved.

The invention provides an iron-based sulfide electrode material, a preparation method and application in a solid state battery, and belongs to the technical field of secondary lithium batteries. The iron-based sulfide electrode material which is based on conversion reaction is selected from one or more of ferrous sulfide, ferriferous sulfide and hepta-ferous octa-sulfide. The preparation method of the iron-based sulfide electrode material has the advantages of being simple and short in time.

The invention relates to a carbon-coated ferrous sulfide negative electrode material, the preparation method and the prepared sodium ion battery thereof, Carbon-coated ferrous sulfide anode material refers to carbon-coated ferrous sulfide and its doped modified material, wherein the particle size of the ferrous sulfide is 100-500 nm, the mass of the carbon coating layer is 3-30% of the mass of theelectrode material, the doping modification elements are one or several of M=Co, Ni, Mn, Ti, Cu, Mg, Ba, Pb, Al, etc., and the mass of the doping modification elements is 0-30% of the mass of the negative electrode material. A metal sulfate and a carbon source are added into deionized water, stirred and dissolved uniformly at room temperature, freeze-dried to obtain a precursor, and calcined at high temperature in an inert atmosphere to obtain a carbon-coated ferrous sulfide negative electrode material. As that negative electrode material of the sodium ion battery, the invention has the advantage of abundant raw materials, simple preparation, short preparation period, low cost, no pollution, good rate performance and strong cycle stability, and is suitable for large-scale production.

The invention relates to a preparation method of nano-silica introduced magnetic vulcanized nanometer zero-valent iron. The preparation method comprises the concrete steps: (1) adding sodium borohydride and sodium persulfate into water to form a mixed solution; (2) adding nano-silica into a solution containing sodium borohydride and sodium persulfate and continuously stirring; (3) slowly dropwise adding a suspension formed in the second step under the stirring condition into a ferric salt solution by virtue of a peristaltic pump; and (4) after reaction is finished, carrying out solid-liquid separation by utilizing a magnet, respectively cleaning twice by adopting deionized water and anhydrous alcohol, and finally directly storing into a deionized water-alcohol solution, or vacuum drying and then storing in an anaerobic glove box. The invention also discloses environment repairing application of the nano-silica introduced magnetic vulcanized nanometer zero-valent iron. The preparation method is convenient and rapid and is low in cost and technical requirements; the material synthesized by the preparation method has the characteristics of both nanometer zero-valent iron and nanometer ferrous sulfide, is capable of solving the problems that the synthesized material is nonmagnetic, easily oxidized and difficultly applied in the absence of nano-silica, is excellent in inorganic and organic pollutant removing performances and has wide application prospect.

The invention discloses a sulfur-series medium-high entropy MAX phase solid solution material as well as a preparation method and application of the same, wherein the M position of the sulfur-series medium-high entropy MAX phase solid solution material comprises any three or a combination of more than four of transition metal elements Ti, Zr, Hf, V, Nb and Ta, the A position is a sulfur element, and the X position is a carbon element. The preparation method comprises the steps that ferrous sulfide serves as a high-temperature solid sulfur source, transition metal sulfide is obtained through areplacement reaction between transition metal simple substances and the ferrous sulfide, then the transition metal sulfide reacts with metal carbide, and the sulfur-series medium-high entropy MAX phase solid solution material is obtained. The ferrous sulfide sulfur source and the sulfur-containing intermediate product adopted by the invention are both stable metal sulfides, so that volatilizationof elemental sulfur in the high-temperature preparation process is avoided, and the synthesis path of a target phase is favorably controlled. The sulfur-series medium-high entropy MAX phase solid solution material is expected to have a good application prospect in the field of extreme environment structural materials such as nuclear power and high-speed rails.

The invention discloses a soil remediation agent, a preparation method and applications thereof, wherein the soil remediation agent is a soluble organic matter-ferrous sulfide nanoparticle suspensionliquid, the mass percentage concentration of the soluble organic matter is 0.06-0.4%, the soluble organic matter is one or a plurality of materials selected from humic acid, fulvic acid and tannic acid, and the particle size of the ferrous sulfide nanoparticles is 150-250 nm. According to the invention, the soil remediation agent is applied to remediation of heavy metal contaminated soil, has slow-release removal effect on heavy metals in heavy metal contaminated soil, can efficiently treat soil containing heavy metals such as chromium, arsenic, lead, zinc and the like in a low consumption manner, and has great popularization and application values.

The invention discloses a preparation method for an iron-ferrous sulfide composite. The method comprises the steps that elemental sulfur powders and iron sulfide powders are mixed at a a mass ratio of 1: 5-60 or pyrite powders and micron-grade iron powders are mixed at a mass ratio of 1: 5-60; the obtained mixed raw materials are put into a ball mill tank of a ball mill; the ball mill tank is filled with grinding media, and the ball mill tank is in a vacuum environment or inert gas atmosphere; and the ball mill is started, the grinding speed is 400-4000 rpm, the grinding time is 2-30 hours, the grinding media and a product are separated after grinding, and the iron-ferrous sulfide composite is obtained. The grain size of the prepared iron-ferrous sulfide composite is below 10 micrometers. The preparation method is simple, the raw materials are low in cost, and poisonous and harmful dangerous chemicals are not used or generated. The prepared iron-ferrous sulfide composite can efficiently purify chlorine-contained organic pollutants and heavy metals in water, and is especially suitable for in-situ repairing of polluted underground water.

A method for improving an iron powder forming property belongs to the technical field of powder metallurgy forming. Pressed blank density can be increased by using good lubricating performance of sulfide. Iron powder and ferrous sulfide powder are mixed in a ball mill and annealed in a hydrogen furnace after being mixed evenly, and the ferrous sulfide is distributed on the surface of the iron powder evenly. In a pressing process, the ferrous sulfide has a lubricating effect, friction condition among powder particles is improved, the forming property is improved, and a blank with the density as 7.2g/cm<3>-7.6g/cm<3> can be obtained. The method has the advantages that the iron powder forming property is good, the blank with higher density can be obtained under low pressing pressure, loss of a grinding tool is reduced, simultaneously sulfur does not affect the performance of iron-based parts, and the process is simple and suitable for industrialized production.

The invention relates to a chemical stabilization repair method of lead contaminated soil. The chemical stabilization repair method comprises the steps that (1) ferrous sulfide particle suspension liquid is prepared; (2) the lead contaminated soil is pretreated, wherein the lead contaminated soil is crushed and sieved to obtain soil with the particle size smaller than 10 cm; (3) chemical stabilization treatment of the first time is carried out, a sodium phosphate solution and a sodium chloride solution are added into the soil treated through the step (2), the water content of the soil is keptbetween 30% to 50%, and after uniform stirring and mixing, moisture preserving maintenance is carried out for 2 days to 5 days; and (4) chemical stabilization treatment of the second time is carried out, calcium carbonate and the ferrous sulfide particle suspension liquid prepared in the step (1) are added into the soil treated in the step (3), the water content of the soil is kept between 40% to60%, after uniform stirring and mixing, moisture preserving maintenance is carried out for 1 week to 3 weeks, and the repaired soil is obtained. The combined repair method is provided and is combinedwith the advantages of multiple repair agents, the treatment effect of the lead contaminated soil is improved, secondary contamination is relieved, and the TCLP leaching quantity of lead in the treated soil can be reduced to be 0.25 mg/L or below.

The invention discloses a vulcanized nano zero-valent iron-acid activated montmorillonite composite material, and a preparation method and application thereof. The composite material is composed of spherical particles with nano zero-valent iron as a core and ferrous sulfide as a shell, is of a nano long-chain structure, has uniformly distributed and highly dispersed iron and sulfur elements, and has typical structural characteristics of silicate and zero-valent iron. The vulcanized nano zero-valent iron-acid activated montmorillonite composite material prepared by the invention is simple in raw material components, green, pollution-free and low in cost; and the product is convenient to transport and store. The prepared vulcanized nano zero-valent iron-acid activated montmorillonite composite material can be applied to in-situ remediation of soil polluted by various alkaline Cr (VI), the process is simple and rapid, the applicability is good, and the remediation effect is good.

The invention discloses a method of detecting hydrogen peroxide, which includes steps: (1) preparation of nano ferrous sulfide: dissolving ammonium ferrous sulfate into secondary water after removing oxygen by blowing nitrogen, adding mixing solution of sulfide and surfactant into the water solution and mixing at ultrasound condition, after reaction, centrifuge washing, depositing, vacuum drying, and obtaining the nano ferrous sulfide sample; wherein mole ration of the sulfide and the surfactant is 1:1, dosing of the surfactant is 0.014N; (2) checking preparation: dropping and coating suspension and polymer film of the ferrous sulfide nano particles on glass-carbon electrode in turn, airing, and aging; (3) detection of hydrogen peroxide: continuously adding hydrogen peroxide into electrolytic cell to detect the hydrogen peroxide, recording ampere response of the hydrogen peroxide, and obtaining detection result. The invention uses nano ferrous sulfide to replace HRP for detecting hydrogen peroxide, due to nano material having large specific surface area, the method increases sensitivity of detection and is simple, convenient, fast, sensitive and stable.

The invention discloses a method for improving laterite-nickel ore carbothermic reduction selectivity. A sulfur-containing assistant is added in laterite-nickel ore and the mixture is subjected to carbothermic reduction-sorting process so that a nickel-iron product is obtained. Through action of the sulfur-containing assistant, based on an appropriate carbothermic reduction process, nickel oxide in the laterite-nickel ore is reduced into metallic nickel, iron oxide is reduced into metallic iron and other parts are bonded to sulfur in the assistant so that ferrous sulfide is obtained. The method realizes nickel and iron selective reduction/sulfuration in laterite-nickel ore carbothermic reduction, greatly improves a nickel grade of the reduced product nickel-iron, produces a high-quality nickel-iron product, satisfies requirements on stainless steel smelting raw materials, has the characteristics of strong raw material adaptability, simple processes, good product quality, low treatment cost and good nickel recovery effects, and provides a novel direction for future high-efficiency and low-cost treatment on laterite-nickel ore.

The invention discloses a method for eliminating heavy metal in industrial sewage. The method comprises the following steps: adjusting the pH value of industrial sewage to be 7-8; subsequently adding sodium sulfide, adjusting the pH value to be 9-10, and reacting sulfur ions with most heavy metal ions so as to generate a precipitate of sulfide, wherein the generation of a harmful gas hydrogen sulfide is effectively prevented; subsequently adding ferrous sulfate while stirring, and reacting with sulfur ions to generate a precipitate of ferrous sulfide and eliminate pollution caused by redundant sulfur ions; adjusting the pH value of the industrial sewage back to be neutral by utilizing the faintly acid of ferrous sulfate, wherein the pollution that a harmful gas hydrogen sulfide can be generated when the pH value is adjusted by using acid is also avoided; press-filtering and subsequently discharging. The method for eliminating the heavy metal in the industrial sewage is simple in process procedure and high in universality, and requirements for eliminating heavy metal in various industrial sewage can be met.

The invention discloses a biological ferrous sulfide composite material which comprises ferrous sulfide and synthetic bacteria bonded to the ferrous sulfide .The ratio of the number of microorganisms of the synthetic bacteria to the ferrous sulfate of unit mass is 3.3*107-5*107 cfu/mg .The synthetic bacteria mainly comprise Desulfovibrio and Clostridium .The invention further discloses a uranium-polluted underground water treatment permeation reaction wall based on the biological ferrous sulfide .The uranium-polluted underground water treatment permeation reaction wall comprises a reaction well and a reaction medium .The reaction well is arranged in soil containing uranium-polluted underground water and located on an underground water flowing path, and the top of the reaction well is flush with the ground and provided with an upward first opening .The reaction medium is arranged in the reaction well and is the biological ferrous sulfide composite material .The prepared material and the device have high removal rate for uranium in water, secondary pollution is avoided, regenerability is good, and the requirements of current underground water uranium-polluted permeation reaction wall materials are met.

The invention provides a preparation method and application of a chitosan-stabilized zirconium-modified nanometer ferrous sulfide composite material, belonging to the technical field of environmentally functional composite nanomaterials. The preparation method specifically comprises the following steps: firstly, preparing zirconium oxide with controllable granularity and relatively high purity by adopting a sol method, and dissolving chitosan by using a dilute acid solution; and adding a ferrous chloride solution into the obtained chitosan solution under the protection of nitrogen, carrying out uniform stirring, adding the zirconium oxide sol, continuing stirring, dropwise adding a sodium sulfide solution, conducting reacting, and performing standing to obtain the chitosan-stabilized zirconium-modified nanometer ferrous sulfide composite material. The material is synthesized by adopting a one-step coprecipitation method, raw material cost is low, a preparation process is simple, the defects that ferrous sulfide is easy to agglomerate, low in reaction activity and poor in stability are overcome, meanwhile, the material has a more stable removal effect on molybdate in water, and the material has a good market application prospect in treatment of molybdenum pollution of surface water and underground water.

The invention relates to porous ferrous sulfide nanowires and nitrogen doped carbon composite material and a preparation method thereof; the material can be used as a long-life and high-rate lithium ion battery negative electrode active material, is nanowires formed by compositing an in-situ generated ferrous sulfide nano-crystalline grains and nitrogen doped carbon, has a porous structure, and has the length of 1-10 [mu]m, the width of 100-500 nm and the thickness of 8-15 nm. The composite material has the beneficial effects that the simple hydrothermal and calcining method is only adopted, and the prepared material has high yield and good dispersibility, and makes great efforts to explore large-scale synthesis of nano materials with excellent performance and high rate; the method is simple in process, meets the requirements of green chemistry, has low requirements for equipment and has great potential for application; and the method shortens the diffusion distance of lithium ions andelectrons, buffers the volume change during the cycle process, thereby effectively improving the electrochemical performance of the material.

The invention relates to the field of water treatment, and in particular relates to a treatment method of water polluted by mercury. The method comprises the following steps: (1) regulating the pH value of mercury-containing sewage to be 6-6.5, and adding sodium alcohol ether sulfate and sodium hypochlorite into the mercury-containing sewage, wherein the additive amount of sodium alcohol ether sulfate accounts for 1-2 times of the mass concentration of mercury in the sewage, and the additive amount of sodium hypochlorite accounts for 3-5 times of the mass concentration of mercury in the sewage; (2) regulating the pH value of the sewage to be 8-9, and then adding poly p-tert-butylphenol disulfide, ferrous sulfide and sodium hydrogen sulfate into the sewage under the conditions that the mass ratio of p-tert-butylphenol disulfide to ferrous sulfide to sodium hydrogen sulfate is (1-2) to (2-4) to 5, and the mass concentration of poly p-tert-butylphenol disulfide in the sewage is 1-5%; (3) then adding a flocculating agent, calcium oxide and alkylphenol polyoxyethylene into the sewage under the conditions that the mass ratio of the flocculating agent to calcium oxide to alkylphenol polyoxyethylene is 1 to 3 to 2, and the additive quantity of the flocculating agent is 0.1-0.3% of the quantity of the sewage; (4) standing the sewage for 3-5 days in a separation tank, and then performing solid-liquid separation; (5) adsorbing the separated sewage by adopting an activated carbon absorber, and then discharging the sewage.

The invention discloses a magnesium-aluminum double-metal hydroxide loaded ferrous sulfide composite material as well as a preparation method and an application thereof. The preparation method comprises the following steps: by taking magnesium-aluminum layered double-metal hydroxide as a carrier of the composite material, firstly mixing a ferrous sulfate solution with Mg2Al-LDH, then dropwise adding a sodium sulfide solution into a reaction system, and carrying out standing, centrifuging, washing and drying on an obtained turbid liquid under an anaerobic condition, thereby obtaining the FeS@Mg2Al-LDH composite material. According to the composite material, agglomeration of FeS particles is effectively inhibited, the synergistic effect of the FeS material and the Mg2Al-LDH material is achieved, the acid and alkali resistance and oxidation resistance of the material are improved, the treatment effect on mercury in a water body is improved, and the composite material has wide applicationprospects in environmental remediation.