The invention belongs to the field of
lithium-
sulfur battery
cathode materials, and provides a preparation method of a high-performance
lithium-
sulfur battery
cathode material derived and synthesizedfrom NiZIF67@Mela. The method comprises the steps: forming N-doped hollow
porous carbon (Ni / CoCNT / NHPC) loaded with Ni and Co nanoparticles after NiZIF67 (at) Mela annealing, and growing a large number of CNTs on the surface of the carbon due to the catalytic action of Ni and Co.
Melamine provides a rich
carbon source and a
nitrogen source, the Ni / CoCNT / NHPC
electrode material has a high specificsurface area, and the
conductivity of the material is improved by CNT generated on the surface of the Ni / CoCNT / NHPC
electrode material. Besides, dissolving of
polysulfide is limited through
chemical adsorption and physical adsorption by means of
nitrogen doping and a hollow
carbon skeleton structure, the shuttle effect is inhibited, the conversion of
polysulfide is catalyzed by generated Ni and Cobimetal nanoparticles, and the obtained Ni / CoCNT / NHPC
electrode material integrates rich CNT, a complete hollow skeleton, Ni, Co and N
doping; meanwhile, the material has high specific surface area,good
conductivity, relatively strong
chemical adsorption and physical adsorption and catalytic action on
polysulfide, and the performance of the
lithium-
sulfur battery is further improved.