The application belongs to the field of membrane
catalysis and
separation technology, and particularly relates to a Cu(I)-MOF
mixed matrix membrane, a preparation method, a
photocatalysis-separation integrated device using the same and application. The
mixed matrix membrane is prepared by mixing Cu(I)-MOF and a PEGBEM-POEM
copolymer solution according to a
specific mass ratio to obtain a
casting solution, and then performing blade
casting and
drying; wherein the Cu(I)-MOF is synthesized from Hdmtz, Hdetz and
copper oxide nanoparticles. The integrated device comprises a reactor shell provided with multiple parallel baffle assemblies, the
mixed matrix membrane is fixed in the baffle assemblies, the internal space is divided into reaction-separation units in series, and a
light source is arranged. After humid CO2 is introduced into the device, a photocatalytic reduction reaction occurs on the surface of the membrane under light to generate CO, and the
high selectivity of the membrane to CO is used to realize in-situ separation and multi-stage purification of CO and O2. The application realizes efficient conversion and separation of CO2 into high-purity CO.