The invention provides a method for constructing a super-hydrophobic PVDF
nanofiber membrane based on interface self-
polymerization and application of the super-hydrophobic PVDF
nanofiber membrane, and particularly relates to the technical field of super-hydrophobic materials. The preparation method comprises the following steps: dissolving PVDF in N, N-
dimethylformamide to prepare a membrane
casting solution, preparing a PVDF
nanofiber base membrane by using an electrostatic
spinning process, dissolving OTS containing active groups in an
organic solvent, sequentially adding nanoparticles, PDMS and a cross-linking agent to prepare an oil-
phase reaction solution, soaking the base membrane in
ethanol, cleaning with deionized water,
drying water drops on the surface of the base membrane by blowing, pouring the oil-
phase reaction solution into the surface of the base membrane, introducing a high-hydrophobicity
silane polymer into PDMS in situ by utilizing a
hydrolysis self-
polymerization reaction of OTS on a water-oil interface, pouring away the oil-
phase reaction solution, and cleaning and
drying a membrane body to obtain the super-hydrophobic PVDF nanofiber membrane. The method is simple in preparation process, does not need a modification device, is excellent in hydrophobicity and stable in property, is suitable for the fields of oil-water separation, self-cleaning coatings,
membrane distillation and the like, and has a good industrial application prospect.