The invention relates to the technical field of ingot casting of solar energy batteries, in particular to a production method of a large polycrystalline ingot. Silicon nitride and water are mixed uniformly through electric mixing for 15-30 minutes, and the mixture is used as a coating liquid, the coating liquid is uniformly coated on the inner surface of a crucible after the crucible is preheated, and then high-temperature baking is carried out on the crucible, a silicon material is loaded in the baked crucible, and then charging is carried out on the crucible loaded with the silicon material, shielding gas-argon passes through a polycrystalline furnace after vacuumizing is carried out on the polycrystalline furnace, the polycrystalline furnace is heated to melt the silicon material, and then, the melted silicon material is gradually crystallized from the bottom part to the top part through directional solidification, and then discharging is carried out after gradual cooling is carried out through high-temperature annealing, the crucible is disassembled after the discharged polycrystalline ingot is cooled at room temperature, so as to obtain the polycrystalline silicon ingot which is sliced to prepare the battery. The large charging amount is realized, the capacity of the casting ingot is improved, the utilization rate of the polycrystalline ingot is improved, the cost is reduced, the requirements of a high-load slicer are met, and the crystal quality is kept to be unchanged.