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45results about How to "Relieve contraction" patented technology

Lithium ferric phosphate battery adopting compound conductive agent and manufacturing method thereof

The invention discloses a manufacturing method for a lithium ferric phosphate battery adopting a compound conductive agent. The manufacturing method comprises the following steps of: dissolving anode binder polyvinylidene fluoride in N-methyl pyrrolidone and stirring, thereby obtaining anode glue; adding a carbon nano-tube/conductive polymer compound material into the anode glue and scattering; adding anode active matter LiFePO4 and stirring, thereby obtaining anode slurry; uniformly coating the anode slurry on two surfaces of an aluminum foil, drying, and then rolling and slicing, thereby obtaining anode plates; uniformly mixing cathode active matter graphite, the carbon nano-tube/conductive polymer compound material, a cathode binder and de-ionized water, thereby obtaining cathode slurry; uniformly coating the cathode slurry on two surfaces of a copper foil, drying, and then rolling and slicing, thereby obtaining cathode slices; coiling, flatly pressing and banding, and then drying for 8 hours in vacuum at 65 DEG C; filling electrolyte into a dried battery; and forming an end product of the lithium ferric phosphate battery after filling the electrolyte. According to the manufacturing method provided by the invention, the capacity, multiplying power, circulation and safety property of the battery are greatly improved.
Owner:ZHEJIANG ZHENLONG BATTERY

Silicon@carbon-graphene-based flexible composite material and preparation method thereof and lithium battery

The invention provides a silicon@carbon-graphene-based flexible composite material and a preparation method thereof and a lithium battery. The flexible composite material is prepared from graphene nanosheets and silicon@carbon particles inlaid in the graphene nanosheets, wherein the graphene nanosheets are irregularly arranged and served as a basic skeleton of the flexible composite material; thesilicon@carbon particles take a silicon particle as a core and comprise a double-carbon layer coating the surface of the silicon particle. The method comprises the following steps: adding silicon intoa solution with oxidability, washing and drying; then adding polydiallyl dimethyl ammonium chloride, stirring and drying; mixing with graphene oxide, and regulating pH; performing suction filtrationto form a film; performing freeze drying on the film; sintering to obtain the flexible composite material. With the double-carbon layer structure on the silicon surface, the flexible composite material provided by the invention can remarkably relieve the volume expansion and contraction of silicon in a cyclic process, and thus improves the electronic conductivity of the silicon particle; moreover,bending of the material can be realized, and the flexible composite material has excellent electrochemical performance.
Owner:四川天诺聚能新能源开发有限公司

Silicon-carbon composite material, preparation method thereof and lithium ion battery

The embodiment of the invention provides a silicon-carbon composite material, which comprises an inner core and a carbon layer coated on the surface of the inner core, wherein the inner core comprisesa graphite skeleton, amorphous carbon filled in the graphite skeleton structure, and a silicon material uniformly distributed in the amorphous carbon, the silicon-carbon composite material only has apore structure with a pore diameter of less than or equal to 50nm inside, and a pore structure with the pore diameter of greater than 50nm does not exist. The silicon-carbon composite material is small in internal pore size, the contact area of the silicon material and electrolyte can be effectively reduced, side reactions are reduced, and the service life of a battery is prolonged; and meanwhile, the silicon material is uniformly dispersed around the graphite skeleton without agglomeration, so that the volume expansion and shrinkage of the silicon material can be effectively relieved by thegraphite skeleton, and the structural stability and energy density of the composite material are improved. The embodiment of the invention also provides a preparation method of the silicon-carbon composite material and a lithium ion battery containing the silicon-carbon composite material.
Owner:HUAWEI TECH CO LTD

Nitrogen-doped composite planar metal lithium anode, preparation and application of nitrogen-doped composite planar metal lithium anode in lithium metal battery

The invention discloses preparation and application of a nitrogen-doped composite planar metal lithium anode. The nitrogen-doped composite planar metal lithium anode is composed of a flat plate current collector, nitrogen-doped hollow carbon nanocages, adhesive active layers and metal lithium, wherein the nitrogen-doped hollow carbon nanocages and the adhesive active layers uniformly cover two sides of the planar metal current collector, and metal lithium exists in the nitrogen-doped hollow carbon nanocages. The nitrogen-doped composite planar metal lithium anode has the advantages that the existence of the hollow carbon nanocages with high specific surface area effectively reduces the overpotential in during the nucleation and deposition of lithium metal, and the doping of nitrogen atomsprovides uniform nucleation and deposition sites, so that the lithium metal intends to grow into the hollow carbon nanocages, thereby achieving uniform deposition and dissolution in the continuous cycle process of the lithium metal. In addition, the ultrathin carbon wall effectively prevents the interface reaction from happening, and the cycle life of the lithium metal battery is greatly prolonged.
Owner:CENT SOUTH UNIV

Quick-positioning low-shrinkage UV moisture dual-curing polyurethane hot melt adhesive and preparation method thereof

The invention provides a fast-positioning low-shrinkage UV moisture dual-curing polyurethane hot melt adhesive and a preparation method thereof, and relates to the field of adhesives, flexible polyurethane modified dihydric alcohol with acrylate double bonds is prepared, the double bonds capable of being subjected to free radical photopolymerization are introduced into a polyurethane prepolymer, and UV illumination is carried out to obtain the fast-positioning low-shrinkage UV moisture dual-curing polyurethane hot melt adhesive. The prepolymer side chain with double bonds can be subjected to free radical photopolymerization to form a certain degree of crosslinking, so that the cohesion of the colloid is rapidly improved, the rapid positioning effect is achieved, and the main chain segment reaches the final strength through later moisture curing. In addition, the polyurethane modified polyether glycol is good in molecular chain flexibility and high in molecular adjustable degree, the flexible long chain can relieve shrinkage caused by colloidal crystallization formed by main chain crystalline polyester polyol, the cohesion strength of the colloid is guaranteed, the impact resistance of the colloid is improved, and the polyurethane modified polyether glycol has a great application prospect in the aspect of intelligent wearing.
Owner:YANTAI SEAYU NEW MATERIALS CORP LTD

Electrocatalytic oxidation filler, preparation method thereof and three-dimensional electrocatalytic oxidation device

The invention discloses an electrocatalytic oxidation filler, a preparation method thereof and a three-dimensional electrocatalytic oxidation device. The electrocatalytic oxidation filler is preparedby mixing a mixture of clay minerals and a curing agent and a mixed solution of Cu < 2 + >/Mn < 2 + > and roasting. The three-dimensional electrocatalytic oxidation device comprises an anode, a cathode and an electrocatalytic oxidation filler filled between the anode and the cathode. The electrocatalytic oxidation filler provided by the invention has the advantages of good conductivity, low energyconsumption, high stability, strong catalytic activity, no need of supporting electrolyte and the like, is widely applied to treatment of industrial wastewater as a filler of a three-dimensional electrocatalytic oxidation device, can realize effective removal of organic pollutants in the wastewater, and has relatively high use value and relatively good application prospect. The preparation methodof the filler has the advantages of being simple in process, convenient to operate, easy to control, low in raw material cost, low in energy consumption, short in consumed time, environmentally friendly and the like, is suitable for continuous large-scale batch production, facilitates industrial utilization and shows a good application prospect.
Owner:湖南海利常德农药化工有限公司

Formula and preparation method for low-shrinkage artificial inorganic stone

The invention discloses a formula and preparation method for low-shrinkage artificial inorganic stone. The inorganic stone comprises the following components in parts by weight: 20-40 parts of an inorganic cementing material, 2-10 parts of an inorganic mineral admixture, 30-80 parts of quartz sand, 6-15 parts of an expanding agent, 1-5 parts of a shrinkage reducing agent, 0.5-4 parts of a water reducing agent, 1-3 parts of an internal curing agent and 1-5 parts of chopped fibers. By adding various raw materials, the shrinkage of the inorganic stone is reduced, so the risk of cracking is lowered; the expanding agent undergoes a chemical reaction in the hydration process to generate a hydration product, so volume expansion is generated and compensates for the shrinkage of the inorganic stone; the shrinkage reducing agent reduces the surface tension of a mesoporous solution in the inorganic stone, so tension on a capillary pore wall in water loss process is reduced, and the shrinkage of the inorganic stone is reduced; the internal curing agent is added, so water required by the cement in hydration process is supplemented and self-shrinkage in water migration process is reduced; and the breaking strength of the inorganic stone is improved through the chopped fibers, so the low shrinkage performance of the artificial inorganic stone is achieved, and the artificial inorganic stone issuitable for being widely used and popularized.
Owner:四川力达建材科技有限公司

Preparation method of composite nano silicon negative electrode material based on conductive carbon aerogel and product thereof

The invention discloses a preparation method of a composite nano silicon negative electrode material based on conductive carbon aerogel and a product thereof, and the preparation method comprises the following steps of: (1) dissolving pretreated waste biomass and a fiber additive in an aqueous solution of an alkaline substance together, and performing stirring to obtain reticular solid gel; (2) drying the reticular solid gel, and performing screening to obtain a carbon aerogel precursor; (3) taking a gaseous silicon source and the carbon aerogel precursor as raw materials, and carrying out a chemical vapor deposition process to prepare a compound of carbon aerogel and nano silicon; and (4) blending the compound of the carbon aerogel and the nano silicon with a carbon source, and conducting heating and carbonizing to obtain the composite nano silicon negative electrode material based on the conductive carbon aerogel. According to the preparation method disclosed by the invention, the waste biomass is used as the raw material, the cost is low, the prepared negative electrode material is high in strength and good in conductivity, and the assembled battery has a relatively high first effect.
Owner:云南锂宸新材料科技有限公司

Preparation method of flexible spinning hollow carbon self-supporting electrode

PendingCN114388788AHigh controllability of operation stepsIncrease transfer rateCell electrodesElectrospinningElectrically conductive
The invention discloses a preparation method of a flexible spinning hollow carbon self-supporting electrode, which comprises the following steps: carbonizing phenolic resin at high temperature to obtain solid carbon spheres, etching with hydrofluoric acid to obtain hollow carbon spheres, uniformly mixing the hollow carbon spheres with polyacrylonitrile, obtaining a flexible spinning composite material through an electrostatic spinning technology, and finally, preparing the flexible spinning hollow carbon self-supporting electrode. The flexible spinning composite material is subjected to pre-oxidation and high-temperature carbonization to obtain the flexible self-supporting electrode. The prepared flexible spinning composite material is mainly formed by compounding hollow carbon spheres and polyacrylonitrile, the pore size distribution and the specific surface area of the flexible spinning composite material can be effectively changed by controlling the proportion of the hollow carbon spheres, and then the electrochemical performance of the flexible spinning composite material is regulated and controlled; meanwhile, polyacrylonitrile can provide a good three-dimensional flexible conductive framework after high-temperature carbonization, so that the conductivity is improved, the cycling stability of the self-supporting electrode is improved, and the volume expansion and shrinkage performance of the self-supporting electrode in the ion transmission process is relieved.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY

A kind of nitrogen self-doping carbon-coated silicon oxide negative electrode material, preparation method and application thereof

The invention discloses a nitrogen self-doping carbon-coated silicon oxide negative electrode material and its preparation method and application. The preparation method of the nitrogen self-doping carbon-coated silicon oxide negative electrode material first passes trimethylbenzene in an alcohol aqueous solution The block copolymer is combined with dopamine or acrylate monomer, and then the pH is adjusted so that the dopamine / acrylate monomer self-polymerizes on the outer layer of trimethylbenzene, and the block copolymer is used as a buffer layer, and then the block is removed by alcohol washing Copolymer and trimethylbenzene, and then form a nitrogen self-doped carbon coating layer by high-temperature carbonization, and then put silicon dioxide into the coating layer in the form of a salt solution, and then obtain a nitrogen self-doped carbon coating layer by magnesia thermal reduction reaction Coated silicon negative electrode material, which has high theoretical specific capacity and good cycle stability, and has a certain degree of stretching elasticity, and can alleviate the volume expansion and contraction caused by silicon oxide when deintercalating lithium, effectively overcoming the silicon volume. Loss and chalking results from expansion and contraction.
Owner:云南锂宸新材料科技有限公司

Steel-solid waste concrete combined bearing platform with composite structure and construction method thereof

The invention provides a steel-solid waste concrete combined bearing platform with a composite structure and a construction method thereof. According to the steel-solid waste concrete combined bearing platform with the composite structure and the construction method thereof, six steel plates are adopted to form a closed box body, so that the tensile strength and the crack resistance of the outermost layer of the bearing platform are improved, and the bearing capacity and the rigidity of the bearing platform are greatly improved; a shear-resistant truss is arranged between a column foot and a pile body, and effective transmission of concentrated loads is achieved through the multiple pieces of profile steel arranged in the inclined direction; and stress coordination trusses are arranged between the adjacent concrete-filled steel tube piles to enhance the overall coordination between the concrete-filled steel tube piles, the shear-resistant trusses and the stress coordination trusses greatly increase the interface bonding degree of the steel tubes and the bearing platform, reinforcing connecting plates are arranged at the joints of the steel tubes and the steel plates to increase the connecting degree of the steel tubes and the steel plates, and the integrity of the whole combined bearing platform is greatly improved. Solid waste concrete with the solid waste replacement rate lower than 30% is adopted in the bearing platform box body, the adverse effect caused by shrinkage of mass concrete can be relieved, and the demonstration effect on engineering application and popularization of the solid waste concrete is achieved.
Owner:HARBIN INST OF TECH

Electrocatalytic oxidation filler and its preparation method, three-dimensional electrocatalytic oxidation device

The invention discloses an electrocatalytic oxidation filler, a preparation method thereof, and a three-dimensional electrocatalytic oxidation device. The electrocatalytic oxidation filler is a mixture of clay minerals and a curing agent, Cu 2+ / Mn 2+ The mixed solutions are mixed and then roasted. The three-dimensional electrocatalytic oxidation device comprises an anode, a cathode and an electrocatalytic oxidation filler filled between them. The electrocatalytic oxidation filler of the present invention has the advantages of good conductivity, low energy consumption, high stability, strong catalytic activity, and no need for supporting electrolytes. As a filler for a three-dimensional electrocatalytic oxidation device, it is widely used to treat industrial wastewater, and can realize The effective removal of organic pollutants has high use value and good application prospects. The preparation method of the filler of the present invention has the advantages of simple process, convenient operation, easy control, low raw material cost, less energy consumption, short time consumption, green environmental protection, etc., is suitable for continuous large-scale batch production, is convenient for industrial utilization, and shows good application prospect.
Owner:湖南海利常德农药化工有限公司

A kind of vacuum arc extinguishing chamber contact

The invention provides a vacuum arc extinguishing chamber contact, which includes an anode side contact piece, a cathode side contact piece, an anode side conductive rod, a cathode side conductive rod, an anode side cup holder, anode side spring No. No. 1 spring, No. 1 spring on the cathode side, and No. 2 spring on the cathode side. The invention adopts a spring with high temperature resistance, high strength and high elastic coefficient to achieve the effect of buffering and shock absorption, which is beneficial to the huge impact when the contact is opened and improves the overall mechanical strength. At the same time, springs are used to cleverly design the conversion between the normal working structure of the contact and the structure during breaking. During normal operation, the conductive rod contacts the contact piece, and the cross-sectional area through which the current flows increases, which is beneficial to reducing the temperature rise. Extend contact life. The rotation direction of the spring is clockwise (from the anode to the cathode), and the current during interruption can be used to generate a magnetic field, which strengthens the longitudinal magnetic field twice, alleviates arc contraction and is beneficial to arc extinguishing. The use of springs can effectively control the pressure between the dynamic and static contacts to achieve an effective balance between the increase in contact resistance due to too small pressure and the deformation caused by excessive pressure. The number of slots in the contact piece is increased, which further suppresses eddy currents and reduces residual magnetism. Compared with traditional cup-shaped longitudinal magnetic contacts, the vacuum arc extinguishing chamber contacts provided by the present invention have smaller temperature rise during rated operation, larger longitudinal magnetic field during breaking, higher breaking success rate, strong impact resistance, and small residual magnetism. It helps to further improve the breaking capacity of vacuum circuit breakers.
Owner:SICHUAN UNIV

NCM ternary positive electrode material with lithium vacancy structure on surface

The invention relates to an NCM ternary positive electrode material with a lithium vacancy structure on the surface, and belongs to the field of chemical energy storage batteries. The method comprises the following steps: adding a weak oxidant into an organic solvent, and uniformly stirring and mixing to obtain a mixed solution; then adding an NCM ternary positive electrode material with micron-sized secondary particles into the mixed solution, and carrying out heat preservation at 20-60 DEG C for 12-24 hours to obtain a turbid liquid; and carrying out solid-liquid separation, and carrying out heat treatment on the collected solid material in an oxygen atmosphere at 200-600 DEG C for 1-10 hours to obtain the NCM ternary positive electrode material with a lithium vacancy structure on the surface, so that formation of lithium vacancies is beneficial to reducing the migration energy when Li < + > migrates among octahedral positions, and diffusion of Li < + > in the material is accelerated. Increase of the migration rate of Li < + > is beneficial to improving the rate capability of the material and reducing the polarization phenomenon at the same time. In addition, rapid movement of Li < + > also helps to improve the uniformity of Li distribution in the material and improve the cycling stability of the material.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY
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