The invention belongs to the technical field of
hydrogen energy resources, and particularly relates to an
oxide composite coating as well as a preparation method and application thereof. The
oxide composite coating provided by the invention comprises a
chromium layer, a
chromium /
chromium oxide composite layer, a
chromium oxide layer, a
chromium oxide / aluminum
oxide composite layer, an aluminum oxide layer, an aluminum oxide /
erbium oxide composite layer and an
erbium oxide layer which are sequentially stacked, the
mass percentage content of chromium in the chromium /
chromium oxide composite layer is reduced in a gradient manner; the
mass percentage content of chromium oxide in the chromium oxide / aluminum
oxide composite layer is reduced in a gradient manner; the
mass percentage content of aluminum oxide in the aluminum oxide /
erbium oxide composite layer is reduced in a gradient manner. A composite
transition layer with gradient composition change is introduced into the interface of the substrate / oxide layer and the interface of the oxide layer / oxide layer, so that the obvious interface is eliminated, and the interlayer bonding force is greatly improved.
Chromium oxide, aluminum oxide and erbium oxide are all excellent
hydrogen barrier materials, the multilayer structure and the interface thereof can effectively prolong the
permeation path of
hydrogen, and the
hydrogen permeation barrier coefficient is improved.