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324 results about "Samarium oxide" patented technology

Samarium(III) oxide is used in optical and infrared absorbing glass to absorb infrared radiation. Also, it is used as a neutron absorber in control rods for nuclear power reactors. The oxide catalyzes dehydration of acyclic primary alcohols to aldehydes and ketones. Another use involves preparation of other samarium salts.

Method for preparation of low carbon alcohol by hydrogenolysis of sugar and sugar alcohol

The invention relates to a method for preparation of low carbon alcohol by hydrogenolysis of sugar and sugar alcohol. The method adopts sugar and sugar alcohol as the raw materials, takes one or more than two of iron, cobalt, nickel, copper, zinc, tin, platinum, ruthenium, palladium, iridium and other transition metals as the catalyst active component, and employs a rare earth oxide like promethium oxide, gadolinium oxide, terbium oxide, holmium oxide, erbium oxide, thulium oxide, cerium oxide, lanthanum oxide, praseodymium oxide, neodymium oxide, scandium oxide, yttrium oxide, dysprosium oxide, europium oxide, samarium oxide, ytterbium oxide, lutecium oxide and the like as the assistant. Under a temperature of 150-320DEG C and an H2 pressure of 1-20MPa, catalytic hydrocracking is carried out in a water solution to obtain ethylene glycol, propylene glycol, glycerol and other low carbon alcohols. The method provided by the invention has the advantages that: the rare earth oxide is added as the assistant to realize hydrocracking of sugar and sugar alcohol, rare earth oxides are insoluble in water and easy to separate, and at the end of reaction, the reaction system has no need for additional acid to neutralize.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Aluminum-lithium-samarium alloy and fused salt electrolysis preparation method thereof

The invention provides an aluminum-lithium-samarium alloy and a fused salt electrolysis preparation method thereof. The aluminum-lithium-samarium alloy is prepared by the following steps of: heating LiCl and KCl serving as an electrolyte system to 630 DEG C for fusion in an electrolytic furnace; uniformly mixing Sm2O3 powder and AlCl3 and tabletting the mixture, adding the mixture into fused salt in the form of grains to ensure that the mass ratio of the AlCl3, LiCl to KCl is 6.2-11.0 percent to 44.5-46.9 percent to 44.5-46.9 percent, wherein the amount of the added Sm2O3 is 1 percent of the weight of the electrolytic fused salt; and taking metal molybdenum as a cathode and graphite as an anode and performing electrolysis for 2 to 6 hours to deposit the Al-Li-Sm alloy close to the cathode of the fused salt electrolysis cell, wherein the electrolysis temperature is between 630 and 720 DEG C, the cathode current density is 6.4A/cm<2> and the anode current density is 0.5A/cm<2>. By completely using metal compounds as raw materials and adding aluminum chloride, the chlorination of samarium oxide is realized and the aluminum-lithium-samarium alloys of different components are obtained by controlling the conditions such as the proportion of the electrolytes, the electrolysis time, the temperature, the current density and the like. The alloy and the method have the advantages of simple whole process, low requirements on equipment, low energy consumption and low pollution.
Owner:HARBIN ENG UNIV

Gradient type macromolecule-based neutron absorption grid tray material and preparation method thereof

The invention discloses a gradient type macromolecule-based neutron absorption grid tray material which comprises a fast neutron slow absorption layer, an intermediate energy neutron absorption layer and a heat neutron absorption layer, wherein the three absorption layers are formed by gradient lamination; a neutron absorption body material doped in the fast neutron slow absorption layer is a lithium fluoride, lithium hydride or boron carbide absorption body material; a neutron absorption body material doped in the intermediate energy neutron absorption layer is a samarium oxide neutron absorption body material; a neutron absorption body material doped in the heat neutron absorption layer is a gadolinium oxide or cadmium oxide neutron absorption body material. The invention also discloses a preparation method of the gradient type macromolecule-based neutron absorption grid tray material. The gradient type macromolecule-based neutron absorption grid tray material has the characteristics of high absorption efficiency, long service life, high mechanical property, simple technology and the like, has a certain absorption effect on gamma photons, can be used for spent fuel storage and neutron sources of other types and has a wide application prospect.
Owner:ZHONGXING ENERGY EQUIP

Recycling method of samarium cobalt magnetic waste material

The invention relates to a recycling method of a samarium cobalt magnetic waste material. The method is characterized by comprising the steps of: a, leaching a samarium cobalt waste material with dilute hydrochloric acid, and after the complete reaction, filtering to remove substances insoluble in acid; b, regulating pH of a leaching solution, precipitating rare earth elements in the solution with oxalic acid to generate a grey and white oxalate precipitate, filtering, drying and calcining the precipitate to obtain solid samarium oxide; c, precipitating samarium, oxidizing Fe<2+> into Fe<3+> in a filtrate by an oxidant, regulating the pH value to precipitate iron in the solution before cobalt, and filtering; and d, removing iron, adjusting the pH value of filtrate, adding oxalic acid to obtain a cobalt oxalate precipitate, and conducting filtration, drying and calcination to obtain cobalt oxide. The method has the following advantages: hydrochloric acid optimal solution, oxalic acid precipitation, iron removal by oxidation and calcination method are employed according to the chemical properties of the elements contained in the waste material, so as to successfully extract valuable elements in the samarium cobalt in waste material; the recycling process is simple in process and low in production cost and the does not produce secondary pollution of the environment; and the prepared samarium oxide and cobalt oxide products have high extraction rate.
Owner:NAT ENG RES CENT OF RARE EARTH METALLURGY & FUNCTION MATERIALS

Samarium doping gadolinium aluminate base fluorescent powder body and preparation method thereof

The invention relates to a samarium doped gadolinium aluminate phosphor powder body and a preparation method thereof. The chemical constituent formula of the phosphor powder body is Gd1-x1-x2A1yOz:Smx1, Rex2, wherein the y value range is 0 to 5 / 3, the RE is the rare earth element ion and / or one or more of transition metal ions, the X1 is Sm doped gram molecular weight and is larger than 0.01 and smaller than 0.1, the X2 is RE doped gram molecular weight, and the content is 1 to 0.1 time of the content of Sm. The invention adopts the preparation process that gadolinium oxide, samarium oxide and RE iron in the stoichiometric ratio are dissolved in acetic acid at 60 to 70 DEG C, then aluminium nitrate is added and is uniformly stirred; ethylene glycol is mixed into the reacting solution according to the mole number of the ethylene glycol / the mole number of metallic ion being over than or equal to 3 and less than or equal to 1.5, and is uniformly stirred; the solution is stirred and vaporized at 60 to 70 DEG C, then is dried and ground, pre-burning is performed for 2 to 3 h at 600 to 800 DEG C in air atmosphere, and the temperature increasing speed is less than and equal to 5 DEG C / min; after the pre-burnt powder is ground, agglomeration is performed for 3 to 4 h over 1000 DEG C in air atmosphere. The processing is simple, the materials are cheap and available, and the powder has large luminescent intensity and even grain size distribution under the stimulation of the blue light and the near ultraviolet.
Owner:NANCHANG UNIV

Easy-to-clean industrial ceramic and preparation method thereof

Belonging to the technical field of industrial ceramics, the invention relates to an easy-to-clean industrial ceramic and a preparation method thereof. The easy-to-clean industrial ceramic comprises a green body and a glaze surface covering the green body. The easy-to-clean industrial ceramic is characterized in that the glaze surface is fritted glaze made from the following raw materials by weight part: 20-40 of feldspar, 10-20 of flint clay, 10-20 of cooked talc, 5-10 of Datong soil, 1-2 of stalactite, 1-3 of quartz, 1-2 of barium titanate, 1-2 of bismuth oxide, and 0.1-0.5 of an improver; the improver is a mixture of yttrium oxide, cerium oxide and samarium oxide in a weight ratio of 1:1:1; or the improver is a mixture of cerium oxide, samarium oxide and gadolinium in a weight ratio of 1:1:1. The green body is prepared from the following raw materials: 30-35 parts of coal gangue, 17-22 parts of feldspar, 8-12 parts of quartz, 8-13 parts of calcined Datong soil, 10 parts of calcined high alumina bauxite, 5-10 parts of Jiexiu soil, 5-10 parts of zimujie clay, 1-3 parts of Suzhou clay, 5-8 parts of Fangzi clay, and 1-3 parts of cooked talc. According to the invention, a layer of ceramic glaze is attached to the industrial ceramic surface, and the preparation process is optimized so as to obtain industrial ceramic with a super smooth surface, and the industrial ceramic has excellent antifouling and easy-to-clean performance.
Owner:山东隆嘉新材料科技有限公司
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