The invention provides a novel heat-resistant corrosion-resistant coating as well as a preparation and application method of the novel heat-resistant corrosion-resistant coating, wherein the novel heat-resistant corrosion-resistant coating comprises ethyl silicate, methyl triethoxysilane, triethylamine, ethyl alcohol, hydrochloric acid, o-cresol formaldehyde epoxy resin, dimethylbenzene, diatomite, silica, zinc oxide, zoelite powder, mica, a butyl cellosolve solvent and butyl alcohol. The novel heat-resistant corrosion-resistant coating is reasonable in components, the stability, the corrosion resistance and the heat resistance of a product are good, and the stability is high. The preparation method of the novel heat-resistant corrosion-resistant coating is simple and feasible in process, high in production efficiency and low in application cost, the operation is easy and simple to implement, the quality of a produced product is stable, and the popularization and application values are relatively high.