The present invention relates to the technical field of ultra-
high performance concrete preparation, and specifically discloses a preparation method of a surface-modified composite micro-nano ultrafine
powder and ultra-
high performance concrete thereof. The preparation method comprises the following steps: (1) dissolving isobutyl
triethoxysilane and polyacrylate in
acetone or
ethyl acetate to obtain a surface modifier solution. (2) adding industrial
solid waste micro-nano ultrafine
powder having gelling activity to
anhydrous ethanol dissolved with hexadecyl trimethyl
ammonium bromide for reaction. After completion, a
solid product is separated, washed, and dried to obtain a pre-treated micro-nano ultrafine
powder. (3) adding the pre-treated micro-nano ultrafine powder to the surface modifier solution, then adding a pH
regulator to adjust the
reaction system to acidity, separating the
solid product after the reaction, washing, and
drying to obtain a surface-modified composite micro-nano ultrafine powder. The present invention uses modified micro-nano ultrafine powder to not only improve the dispersibility in concrete, but also significantly improve the mechanical
properties of concrete.