The invention discloses an
oxygen vacancy type Bi2O2CO3 / MIL-101-NH2 composite catalyst as well as a preparation method and application thereof, and belongs to the technical field of
catalytic oxidation and the field of
water environment treatment. According to the composite catalyst provided by the invention, MIL-101-NH2 is loaded on the surface of Bi2O2CO3, so that a
heterojunction structure rich in
oxygen vacancies is formed; the Bi2O2CO3 is of a cluster flower-shaped structure with the
diameter of 2 to 3 [mu] m; the MIL-101-NH2 is of a fusiform particle structure with the length of 500-1000 nm, is rich in
oxygen vacancies, and is dispersed and loaded in the stamens of the Bi2O2CO3. The composite catalyst provided by the invention shows relatively high
catalytic oxidation performance in a test of treating an antibiotic
water body by photocatalytic activation of peroxymonosulfate (PMS), can effectively remove
antibiotics in water within a short time, and has excellent application potential in antibiotic treatment.