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414results about How to "Qualitatively accurate" patented technology

Infrared photoacoustic spectroscopy detection device and method for decomposed components of sulfur hexafluoride under partial discharge

The invention relates to an infrared photoacoustic spectroscopy detection device and method for decomposed components of sulfur hexafluoride under partial discharge, belonging to the technical field of partial discharge on-line monitoring of SF6 gas insulating electrical equipment. The device of the invention mainly comprises an induction voltage regulator, a corona free experimental transformer, a partial discharge free protective resistor, a standard capacitive voltage divider, a non-inductive resistor, a GIS analog element, a wide-frequency high-speed ultrahigh-capacity digital storage oscillograph and an infrared photoacoustic spectroscopy system. In the method of the invention, infrared photoacoustic spectroscopy detection is carried out on the decomposed gas of SF6 under partial discharge in the GIS analog element by the device of the invention. The invention has high sensitivity, little gas consumption, multiple detection components and strong anti-jamming capability, can effectively detect SF6, CF4, SO2F2, SOF2, SO2, HF and the like as low as 0.01 muL/L, and is suitable for on-line detection. The invention can be widely used for detection of partial discharge decomposed gas of SF6 in the SF6 gas insulating electrical equipment, especially the GIS equipment.
Owner:CHONGQING UNIV

Automatic constant temperature type photoacoustic detection device for SF6 decomposed components and experiment method thereof

The invention which relates to an automatic constant temperature type photoacoustic detection device for SF6 decomposed components and an experiment method thereof belongs to the technical field of SF6 gas insulation device partial discharge online monitoring. The device is characterized in that an automatic constant temperature system is arranged in present infrared photoacoustic spectrum monitoring systems; and according to the method, the device is utilized to detect the SF6 gas partial discharge decomposed components in a GIS (gas insulated substation) simulation element under automatic preset temperature constancy conditions. According to the invention, the influence of external environment can be eliminated, the gas components of SO2, CO2, CF4, SO2F2, SOF2 and the like with the concentrations of low to 0.01muL/L can be effectively detected, the accuracy, the detection precision and the stability are high, and performances of a solid state relay are stable, so the long-term effective working of the automatic constant temperature system can be guaranteed. The device which can be widely applied to the field of the SF6 gas insulation equipment partial discharge online monitoring is especially suitable for detecting the SF6 gas partial discharge decomposed components in the GIS.
Owner:CHONGQING UNIV

Railway roadbed geological radar defect map analysis method and device

The invention relates to the technical field of railway engineering detection, and provides a railway roadbed geological radar defect map analysis method and device in allusion to problems existing inthe prior art. The railway roadbed geological radar defect map analysis method comprises the steps of forming forward modeling on geological radar electromagnetic waves, preliminarily establishing aroadbed defect map, analyzing feature laws of the simulated defect map in various types of geological radar images, and forming a railway roadbed simulated geological radar typical defect map featurelibrary; setting a typical roadbed defect test area, and performing field testing by using geological radar nondestructive testing equipment, and respectively generating profile grayscale maps or waveform maps of a compaction area and the roadbed typical defect test area correspondingly; and performing comparative analysis on the generated profile grayscale maps or waveform maps of the compactionarea and the roadbed defect test area according to the simulated geological radar typical defect map feature library, and summarizing a railway roadbed actual measurement geological radar typical defect map feature library; and performing rapid non-destructive detection and defect judgment on the actual railway roadbed according to the geological radar typical defect map feature library.
Owner:CONSTR COMPANY OF CHINA RAILWAY NO 8 ENGNEERING GRP

Method for screening pesticide and veterinary drugs in infant formula food by ultra-high performance liquid chromatography-quadrupole static electric field track ion trap mass spectrum

The invention discloses a method for screening pesticide and veterinary drugs in infant formula food by ultra-high performance liquid chromatography-quadrupole static electric field track ion trap mass spectrum, and belongs to the technical field of food safety inspection. The method comprises the following steps: preprocessing a sample by an optimized QuEChERS method; screening by applying ultra-high performance liquid chromatography-quadrupole static electric field track ion trap mass spectrum; selecting a positive ion or negative ion mode for scanning by adopting full-scan / data dependence acquisition, full-scan / variable data independence acquisition and full-scanning / full-ionic acquisition fragmentation acquisition scan modes to obtain complete primary and secondary maps; and processing the primary and secondary maps by applying Exact Finder 2.5 software to extract compound information. According to the method, information in the established spectrum library is compared with the screening result of a to-be inspected object so as to ensure the composition of pesticide and veterinary drugs in an infant formula food. The mass spectrum instrument used in the method has the main advantages of high resolution ratio, accurate qualitative and quantitative results, high sensitivity, high quality precision and the like. The method can be applied to analysis of complex substrates.
Owner:SHAANXI UNIV OF SCI & TECH

Detection method of polyamine substances in tobacco roots, stems and leaves

The invention discloses a detection method of polyamine substances in tobacco roots, stems and leaves. The method comprises the steps that vortex extraction is conducted on tobaccos to obtain polyamines through a pre-cooled perchloric acid solution, derivatization is conducted through 3,5-dinitro benzoyl chloride, extraction and concentration are conducted on a derivative product through vortex auxiliary-liquid-liquid microextraction, and detection is conducted through an ultra-efficient liquid chromatography-photodiode array detector. In addition, in order to obtain the best enrichment factors and the recovery rate in vortex auxiliary-liquid-liquid microextraction, method optimization is conducted through fractional factorial design and Doehlert design. Compared with other methods of analyzing and detecting the polyamines, the detection method of the polyamine substances in the tobacco roots, stems and leaves has the advantages of being rapid in derivative reaction, stable in product, high in sensitivity, good in reproducibility, green and friendly to environment and the like, and accurate qualitativeness and quantification can be conducted on the polyamines in the tobacco roots, stems and leaves. In addition, other four kinds of polyamines, namely, tyramine, 1,3-propylene diamine, high spermidine and canavalmine are identified through high-resolution mass spectrometry, wherein the canavalmine is found in the tobaccos for the first time.
Owner:GUIZHOU TOBACCO SCI RES INST

Method for detecting related substances of ibuprofen and its sodium salt and preparation

The invention provides a method for detecting related substances of ibuprofen or its sodium salt and preparation. The related substances comprise impurities A, B, C, D, E and F. The method comprises (1) preparation of a test sample solution: taking an appropriate amount of ibuprofen or ibuprofen sodium raw materials, putting the materials into a certain volume of a container, dissolving the materials, diluting the solution until a desired volume marked by a scale, shaking the solution, and filtering the solution to obtain a certain concentration of the test sample solution, and (2) sample detection: pouring the test sample solution into a chromatographic instrument, and acquiring a chromatogram map of the related substances separated effectively under chromatographic conditions of use of a chromatographic column containing octadecyl silane chemically bonded silica as a filler having size of 250*4.6mm and pore sizes of 5 micrometers and having a column temperature of 20 to 40 DEG C, use of a mobile phase having a volume ratio of organic phase acetonitrile to a water phase phosphoric acid aqueous solution of 32% to 48% and phosphoric acid content of 0.01 to 0.1% in the phosphoric acid aqueous solution, a flowing rate of 1.0 to 2.3 ml/min, and a detection wavelength of 205 to 225nm. The method can realize effective separation of a variety of impurities.
Owner:CHINA PHARM UNIV

Method for detecting monocyclic aromatic pollutants in engine tail gas

The invention discloses a method for detecting monocyclic aromatic pollutants in engine tail gas. The method comprises the following steps: collecting tail gas to be detected by using an engine tail gas sampling unit, and putting the active-carbon tail gas to be detected in a test tube as the sample; adding dichloromethane into the sample, putting the test tube in an ultrasonic extractor to carry out ultrasonic extraction, filtering the extract liquor, evaporating and setting to the marked volume to concentrate the extract liquor, and preserving at low temperature; carrying out chromatographic analysis on the extract liquor preserved at low temperature; and carrying out linear regression by using the concentration of monocyclic aromatics as the horizontal ordinate and the peak area as the vertical coordinate to calculate a standard operation curvilinear equation, substituting the chromatographic result into a standard operation curvilinear equation, and calculating the concentration of monocyclic aromatics in the sample. The invention can quickly and accurately carry out qualitative and quantitative analysis on monocyclic aromatics and has the advantages of high sensitivity and selectivity and good reproducibility; and the relative standard deviation does not exceed 6.5%, the detection limit is 0.003-0.009 mg / m3, and the recovery rate is 87.5-95.2%.
Owner:JIANGSU UNIV

Experiment system for simulating cable burning under fire environment and method thereof

The invention discloses an experiment system for simulating cable burning under the fire environment and a method thereof. The experiment system for simulating cable burning under the fire environment comprises a weighing device which is provided with a sample frame used for fixing cable samples; a heating device which comprises a radiation heating shell and an igniter, wherein the radiation heating shell covers the weighing device, and the igniter is arranged in the cavity of the radiation heating shell and used for igniting the cable samples fixed on the sample frame; multiple thermocouples and heat flow meters; and a smoke collection device which comprises a smoke collection hood and a smoke composition analyzer, wherein the smoke collection hood is connected with the radiation heating shell of the heating device, and smoke emitted by burning of the cable samples is guided to the smoke composition analyzer through the smoke collection hood. According to the experiment system for simulating cable burning under fire environment and the method thereof, more accurate nature determination and classification of the burning characteristics of the cables are facilitated so that deeper research and analysis can be performed in the aspect of cable fire dynamics.
Owner:INST OF IND TECH GUANGZHOU & CHINESE ACADEMY OF SCI +1

Method for qualitatively and quantitatively testing and analyzing impurities in steel

The invention provides a method for qualitatively and quantitatively testing and analyzing impurities in steel. The method includes the following steps of firstly, preparing a to-be-tested sample, wherein the to-be-tested sample is ground and polished, and the surface is clean, smooth and free of peculiar objects; secondly, observing the to-be-tested sample in a metallographic microscope, and determining the size range of the impurities; thirdly, adjusting testing parameters of a scanning electron microscope according to the impurity size range determined in the second step, and conducting scanning electron microscope testing and EDS energy spectrum component analysis on the to-be-tested sample to obtain size, shape and component data of the impurities in steel. By setting the component content standard, size and length standard and shape standard of the impurities in steel in application software and related accessories of the scanning electron microscope and setting the proper testing parameters according to the size of the impurities in steel, the properties of the impurities in steel can be accurately, qualitatively and quantitatively analyzed, analyzing and testing are accurate and comprehensive, artificial influence factors are small, and the evaluation result is specific, precise and visual.
Owner:CENT IRON & STEEL RES INST

Method for measuring dimethyl fumarate in product by gas chromatography-mass spectrometry

The invention discloses a method for measuring dimethyl fumarate in a product by gas chromatography-mass spectrometry. The method comprises the following steps of: pretreating a dimethyl fumarate product to be detected by using an ultrasonic extraction method; setting the temperature of a sample injection port of a gas chromatography-mass spectrometer to be 240-280 DEG C, a flow rate to be 0.8-1.5 ml/min and the temperature of a port to be 280-300 DEG C, and selecting a weak polar column for a chromatographic column; enabling a sample to enter the chromatographic column through the sample injection port, and carrying out temperature programming on the temperature of the chromatographic column to separate the components of the sample by the chromatographic column; and enabling the components separated by the chromatographic column to enter a mass spectrometric detection part through the port of the gas chromatography-mass spectrometer, wherein an electron impact ion source is adopted as the ion source of the mass spectrometric detection. The method for measuring the dimethyl fumarate in the product by the gas chromatography-mass spectrometry has low detection limit, good detection effect, little consumption of analysis solvent and low detection cost.
Owner:NINGBO PTS PROD TECH SERVICE

Method for detecting residual quantity of sodium nitrophenol in aquatic product

The invention discloses a method for detecting residual quantity of sodium nitrophenol in an aquatic product and belongs to the technical field of detection of aquatic products. The method comprises the following steps of: extracting and purifying a sample; drawing a standard curve; and determining and quantifying apparatus conditions. According to the method disclosed by the invention, an APCI (Atmosphere Pressure Chemical Ionization) ion source is selected by a mass spectrometer, so that the sensitivity of sodium orotho-nitrophenolate is improved by dozens of times; neutral alumina is adopted for purifying, so that interfering substances such as fat in the sample can be effectively removed, and the concentration time is shortened; sodium hydroxide is added during the concentration process, so that the sodium orotho-nitrophenolate exits in the sample in the form of sodium salt, thereby enabling the recovery rate of the sodium orotho-nitrophenolate to be more than 70%. Phosphoric acid is added after the concentration for neutralizing the excessive sodium hydroxide, so that the pH of the purifying liquid kept at about 3, and the requirements of upper solid-phase extractor column can be satisfied. The method disclosed by the invention fills up the blank that no method is provided for detecting residual quantity of sodium nitrophenol in aquatic products and other animal foods at present, and has great significance in accurately and scientifically evaluating the quality safety of the aquatic products and making the novel standards of harmful substances in the aquatic products.
Owner:YELLOW SEA FISHERIES RES INST CHINESE ACAD OF FISHERIES SCI

Method for simultaneously measuring Amadori compounds in tobaccos

The invention discloses a method for simultaneously measuring Amadori compounds in tobaccos, relates to a method for measuring important ingredients in tobaccos, and particularly relates to a method for simultaneously measuring nine Amadori compounds in tobaccos by the aid of liquid chromatography-tandem mass spectrometry. The method includes steps of 1, sample extracting: smashing tobacco samples, extracting the tobacco samples by methanol-aqueous solution, filtering the tobacco samples and collecting filter liquor; 2, purifying: adding normal hexane into the filter liquor, repeatedly extracting the filter liquor, removing impurities such as coloring matters in the filter liquor, concentrating the filter liquor by methanol-aqueous phases until the filter liquor is dry, diluting the filter liquor by methanol-aqueous solution until the volume of the diluted filter liquor meets requirements, and filtering the filter liquor by an organic filter membrane to obtain test samples; 3, measuring: analyzing the test samples via HPLC-MS/MS (high-performance liquid chromatography-mass spectrometry/mass spectrometry), and performing multi-reaction monitoring scanning on the test samples in a cation ionization mode. The method has the advantages that the Amadori compounds in complicated systems of the tobaccos can be effectively extracted and analyzed and can be detected jointly, the sensitivity and the interference resistance are high, and the method has popularization and application value.
Owner:HONGTA TOBACCO GRP
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