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56results about How to "Shorten the mass transfer distance" patented technology

Core-shell structure thermite and preparation method thereof

The invention discloses a core-shell structure thermite and a preparation method thereof. The method includes the steps: dissolving poly- 4-vinylpyridine (P4VP) in isopropyl alcohol to form mixed liquid, placing nano-silicon powder into the mixed liquid to ultrasonically treat mixture, centrifugally separating the mixture, washing separated substances by isopropyl alcohol to remove the P4VP without being coated, and drying the separated substances to obtain silicon powder coated by the P4VP; placing the silicon powder into the isopropyl alcohol, adding metal oxide micro-powder with stoichiometric ratio, and ultrasonically treating mixture to form slurry; performing vacuum drying on the acquired slurry, and grinding and crushing the dried slurry to obtain the Si@MOx nano-scale core-shell structure thermite which takes nano-silicon powder as a core and a metal oxide as a shell. According to a core-shell structure, the mass transfer distance between the silicon powder and the metal oxideis shortened, reaction activation energy is reduced, and the external work doing capability of the compound thermite is improved. The preparation method is simple and easy, the prepared core-shell structure thermite has the advantages of good combustion performance, high heat release, accurate and adjustable shell layer thickness and the like.
Owner:CHONGQING UNIV

Supergravity field micro-reactor, and method for preparing nanometer material through liquid phase precipitation method

The invention relates to a supergravity field micro-reactor for preparing a nanometer material. The supergravity field micro-reactor comprises a micro-reaction assembly, a material receiving groove provided with a material outlet, a first motor, a transmission system, a material inlet system and a support system, wherein the micro-reaction assembly comprises an upper disc and a lower disc, micro-grooves are respectively distributed on the bottom surface of the upper disc and the top surface of the lower disc, the center position of the lower disc is provided with a material inlet micro-pore channel, a 0.03-0.1 mm gap is arranged between the bottom surface of the upper disc and the top surface of the lower disc after the combination, the first motor drives the transmission system to operate so as to make the upper disc and the lower disc in the micro-reaction assembly rotate in opposite rotation directions, and an upper disc lifting system can be additionally arranged so as to conveniently adjust the gap between the bottom surface of the upper disc and the top surface of the lower disc in the micro-reaction assembly and wash the upper disc and the lower disc. With the supergravity field micro-reactor of the present invention, the nanometer material is prepared by using the liquid phase precipitation method, such that the high dispersion property and the uniform particle distribution of the nanometer material can be maintained while the treatment capacity can be increased and the clogging of the micro-reaction assembly can be avoided.
Owner:SICHUAN UNIV

Preparation method of dense sintering type composite aluminum nitride ceramics

The invention discloses a preparation method of dense sintering type composite aluminum nitride ceramics, and belongs to the technical field of inorganic ceramic materials. The preparation method comprises the following steps: firstly uniformly mixing alcohol aluminum salt, silicate ester, fatty acid, an alcohols solvent-nano-iron powder and sodium fluoride, then adding carbon fiber / graphene oxideaerogel, and carrying out ultrasonic immersing, thus obtaining a mixed immersing solution; after heating and carrying out ultrasonic reaction on the mixed immersing solution, filtering, washing, anddrying, thus obtaining loaded filling aerogel; then reducing the loaded filling aerogel by hydrazine hydrate, thus obtaining reduced loaded filling aerogel; then carrying out temperature rising reaction on the reduced loaded filling aerogel step by step under a nitrogen protection state, thus preparing composite aluminum nitride powder; then mixing the composite aluminum nitride powder with calcium oxide, magnesium oxide, polyvinyl butyral and a solvent, molding through injection molding, then carrying out high-temperature sintering, and cooling, thus obtaining the dense sintering type composite aluminum nitride ceramics. The dense sintering type composite aluminum nitride ceramics obtained by the invention has excellent mechanical performance and excellent heat conduction efficiency.
Owner:常州欧利莱照明有限公司

Preparation method for microporous membrane with structural self-regulating characteristics for membrane distillation

ActiveCN108654393AExcellent permeation fluxMass transfer driving force decreasedDistillationMembrane distillationLayer thickness
The invention discloses a preparation method for a microporous membrane with structural self-regulating characteristics for membrane distillation. The microporous membrane is prepared by mixing a temperature-sensitive high-molecular material having hydrophilic/hydrophobic transition characteristics with temperature change and a high-molecular membrane material and adopting a phase separation method, and the obtained microporous membrane has a double-layer membrane structure composed of a hydrophobic layer and a hydrophilic layer, wherein thicknesses of the hydrophobic layer and the hydrophiliclayer can be automatically regulated according to operating temperature in the membrane distillation process. The microporous membrane for the membrane distillation disclosed by the invention has anautomatically-adjustable hydrophobic layer thickness adapted to the operating temperature, greatly reduces mass transfer resistance and improves a permeation flux of the membrane, and at the same time, the corresponding thickened hydrophilic layer can significantly reduce temperature difference polarization and heat transfer loss of the whole membrane, and effectively solve a contradiction betweenmass transfer and heat transfer in the membrane distillation process; and the microporous membrane improves the membrane distillation process characteristics and thermal efficiency, and especially facilitates direct contact type membrane distillation concentration separation by fully utilizing waste heat of a lower-temperature material liquid, and has good application prospects.
Owner:NINGBO UNIV

Continuous adjusting electrode distance-type desalting technology and reaction module for electric adsorption-regeneratoin

ActiveCN108862489AIncrease the mass transfer distanceReduce secondary adsorptionSpecific water treatment objectivesDispersed particle separationElectricityWater productivity
The invention discloses a continuous adjusting electrode distance-type desalting technology and reaction module for electric adsorption-regeneration. A reactor comprises a continuous adjusting electrode distance-type desalting reactor box body 1, a raw water tank 2, a pure water tank 3, a final concentrated water tank 4, a power supply 5, a water pump 6, and electric conductivity instruments 7 and8. The salt-containing waste water dominant on garbage percolation liquid discharged water is treated by using the continuous adjusting electrode distance-type desalting technology and reaction module, the desalting rate can reach up to 42.6 percent, the removal rate of Cl- is 73.3 percent, the desalting speed is 90 mg/(L.h), the electrode regenerative rate is 97.3 percent, and the water productivity is 91.7 percent. By adopting the movable slot-controlled continuous adjusting electrode distance-type continuous electric adsorption-regeneration way, the reaction module has the characteristicsof simplicity in operation, stable current density, high desalting rate, high desalting efficiency, high electrode regeneration rate, scaling phenomenon, high water productivity and long electrode service life, the desalting and recycling of low-salt-content industrial waste water can be realized, and the prospect in the field of environment protection salt-containing industrial waste water treatment is wide.
Owner:BEIJING FORESTRY UNIVERSITY

Preparation method of hydrophilic and hydrophobic double-layer polyvinylidene fluoride membrane

The invention discloses a preparation method of a hydrophilic and hydrophobic double-layer polyvinylidene fluoride membrane. By preparing macromolecule cast film liquor with low critical dissolving temperature and a hydrophilic modification macromolecule solution, spin hollow fiber membranes are extruded out at the same time in suitable spinning nozzles, and the hydrophilic and hydrophobic double-layer hollow fiber membrane with a structure easy to regulate and control is obtained. During membrane preparation, the process of phase separation includes a thermally induced split-phase mechanism of a hydrophobic layer based on the low critical dissolving temperature and a non-solvent induced phase separation mechanism of a hydrophilic layer. According to the hydrophilic and hydrophobic double-layer membrane structure, boundaries of the hydrophilic layer and the hydrophobic layer are tightly combined, layering does not exist, and the membrane has the advantages of being high in porosity andthin in hydrophobic layer; during membrane distillation, the steam mass transfer distance in the membrane is reduced, mass transfer resistance is reduced, the permeating flux of the membrane is increased, meanwhile, temperature difference polarization and heat transfer loss are reduced, and application prospects are broad.
Owner:NINGBO UNIV

A kind of hierarchical porous hβ molecular sieve catalyst for preparing diphenylamine by condensation of aniline and its preparation method and application

The invention discloses a hierarchical pore Hbeta molecular sieve catalyst for preparing diphenylamine by condensing aniline. The hierarchical pore Hbeta molecular sieve catalyst is prepared by virtue of a direct synthetic method or a micropore molecular sieve modification indirect synthetic method. The invention also discloses a preparation method of the hierarchical pore Hbeta molecular sieve catalyst as well as an application in preparing diphenylamine by catalyzing the condensation of the aniline. Under the effect of a formed catalyst prepared by the hierarchical pore Hbeta molecular sieve catalyst, the aniline has a self-condensation reaction to prepare diphenylamine, the reaction temperature is 290 to 370 DEG C, the reaction pressure is 1.5MPa to 5MPa, and the airspeed is 0.1 to 0.7 / h. The molecular sieve catalyst has the advantages of good catalytic activity, good stability and high diphenylamine selectivity. Compared with the corresponding ordinary micropore Hbeta molecular sieve, the conversion rate of the aniline is at least increased by 23%, the selectivity of the diphenylamine is at least increased by 1%, and the service life of the catalyst can reach more than 7000 hours.
Owner:NANJING TECH UNIV

Filling material for sewage treatment and preparation method of filling material

The invention discloses a filling material for sewage treatment and a preparation method of the filling material. The filling material is spherical and comprises a solid sphere in the centre, a sheet-like fan-shaped expansion area and a wool area on various surfaces, wherein the sheet-like fan-shaped expansion area and the wool area on various surfaces are arranged outside the solid sphere at intervals. The preparation method comprises the steps of manufacturing a spherical basal body, forming a fan-shaped surface in the expansion area, splitting and the like. By means of the unique structure and the process thereof, the filling material disclosed by the invention is good in oxygenizing efficiency and rapid to hang; the specific surface area of the filling material is high; attachment of microorganisms is promoted through the fan-shaped wool area; an aerobic state is formed in the sphere; an anoxic state is formed even in the spherical centre; a biological membrane has multiple varieties of the microorganisms, long food chain and higher processing capacity; the filling material is simple to install and convenient to operate and manage; the basal body shape of the filling material is a sphere; under the stirring of aerated bubbles, the filling material can rotate at high speed; therefore, the filling material is low in resistance and mould releasing and updating are easy; the filling material takes synthetic fibre polyurethane, which has good hydrophilia, as a substrate material.
Owner:四川省科学城天人环保有限公司

Production system for hypochlorite

The invention discloses a production system for hypochlorite. The production system for the hypochlorite comprises a hypochlorite generator, a salt melting tank, a softener, a liquid storage tank, a speculative system, and a PLC control cabinet. The hypochlorite generator includes an electrolytic cell; the electrolytic cell comprises a shell, an electrode assembly, a plurality of water baffle plates and two sealing elements, the electrode assembly is arranged in the shell, through holes are formed in the water baffle plates, the electrode assembly is sleeved with the through holes at intervals, the water baffle plates are arranged between the electrode assembly and the inner wall of the shell, the water baffle plates are connected with the shell in a sealing mode, and the two sealing elements are correspondingly arranged on the two ends of the shell in a sealing mode. According to the production system for the hypochlorite, in the electrolytic process, it is guaranteed that salt solution can all flow through an anode plate and a cathode plate of electrode assembly by the electrolytic cell under the action of beam of the water baffle plates, so that the mass transfer distance is reduced, and the electrolytic efficiency is improved.
Owner:AWS ENVIRONMENT TECH LTD

Preparation method of ruthenium-iridium-titanium ternary metal mesh electrode containing nano tip structure

The invention belongs to the field of preparation of electrochemical electrodes, and discloses a preparation method of a ruthenium-iridium-titanium ternary metal mesh electrode containing a nano tip structure; the method comprises the following steps: (1), performing pretreatment of a titanium wire mesh substrate, including removal of a substrate oxide film and removal of oil stains; (2), performing acid etching; (3), forming a nano tip; (4), performing preparation, coating and thermal oxidation of middle-layer coating liquid; and (5), performing preparation, coating and thermal oxidation of an active layer coating solution. The surface of the prepared electrode channel contains a large number of nano tip structures, the effective reaction area of the electrode is increased, the collision opportunity of reactants and the surface of the electrode is increased, and mass transfer is promoted. The method is low in equipment requirement, low in production cost, simple to operate and easy to regulate and control. Meanwhile, the invention also discloses application of the ruthenium-iridium-titanium metal mesh electrode containing the nano-tip structure prepared by the invention to total nitrogen removal performance evaluation and control experiments in actual production wastewater, and high total nitrogen removal efficiency and low cost and energy consumption of wastewater treatment are realized.
Owner:DALIAN UNIV OF TECH

Preparation method and application of vertically-oriented magnetic nanosheet/sodium alginate composite membrane

The invention discloses a preparation method of a vertical orientation magnetic nanosheet/sodium alginate composite membrane. By means of the magnetic field responsiveness of a magnetic nanosheet, a vertical orientation structure is formed in a magnetic field so as to prepare a high-performance pervaporation composite membrane; wherein the magnetic nanosheets comprise nanosheets with intrinsic magnetic responsiveness or other nanosheets which generate magnetic responsiveness by loading magnetic response particles. The preparation method specifically comprises the following steps: uniformly dispersing magnetic nanosheets, physically blending the dispersion with sodium alginate to form a membrane casting solution, carrying out standing treatment for defoaming, spin-coating the membrane casting solution on a polyacrylonitrile ultrafiltration membrane, drying the composite membrane in a magnetic field at room temperature, and carrying out crosslinking treatment to obtain the magnetic nanosheet/sodium alginate composite membrane with vertical orientation. The preparation method is simple and controllable, and the raw materials are cheap and easily available. The composite membrane is suitable for pervaporation ethanol dehydration, has high permeation flux and high selectivity to water molecules, and has good operation stability at high temperature.
Owner:TIANJIN UNIV

Electrochemical filter for removing total nitrogen in water

The invention belongs to the technical field of water treatment, and discloses an electrochemical filter for removing total nitrogen in water. A water body to be treated is continuously pumped into a cathode reaction chamber through a water inlet, sequentially flows through a three-dimensional nano tip porous cathode and an anode under certain current and voltage, and reacts for a certain period of time, and finally, nitrate nitrogen, ammonia nitrogen and nitrite nitrogen in the water body are converted into nitrogen. The mass transfer distance from a substance to the surface of an electrode can be shortened by utilizing a micron-sized aperture electrode, the collision opportunity of pollutants and the electrode in the liquid flowing process is increased by the nano-tip structure in the pore channel, and meanwhile, reaction ions are limited in the internal channel of the three-dimensional nano-tip porous electrode; and the repulsive interaction of like ions under the action of electric field force is weakened, and the problems that a traditional electrochemical reactor electrode is small in effective reaction area, too large in distance between two electrodes, low in mass transfer efficiency and low in reaction efficiency, reactants are rejected by the electrode, reactant gas is accumulated, and the reactor is difficult to amplify are solved.
Owner:DALIAN UNIV OF TECH

A method for detecting methylmercury, ethylmercury and inorganic mercury in aquatic feed

The invention discloses a method for detecting methyl mercury, ethyl mercury and inorganic mercury in aquatic feed. The method comprises the following steps: drying an aquatic feed sample and preparing the sample into powder; adding L-cysteine; after vibrating and centrifuging, extracting supernatant liquid and filtering to prepare a sample to be detected; preparing the sample to be detected into a solution to be detected with the concentration of 10 micrograms / L by using the L-cysteine, and detecting by using a high performance liquid chromatography-cold steam generation atom fluorescence spectrophotometer. According to the method disclosed by the invention, the L-cysteine is used as an only extracting agent for mercury forms in the aquatic feed; the various forms of the mercury can be simply, rapidly and reliably extracted from the aquatic feed with a complicated base body by adopting a vibration and separation extraction form; after the extraction is finished, extra operations are not needed and an extracting solution is directly injected into the high performance liquid chromatography-cold steam generation atom fluorescence spectrophotometer to be analyzed; compared with reported methods, the method is simple and rapid, reagents are green and toxin-free, and the method is accurate and sensitive and has low detection limit.
Owner:四川威尔检测技术股份有限公司 +2

Filler for sewage treatment and preparation method thereof

The invention discloses a filling material for sewage treatment and a preparation method of the filling material. The filling material is spherical and comprises a solid sphere in the centre, a sheet-like fan-shaped expansion area and a wool area on various surfaces, wherein the sheet-like fan-shaped expansion area and the wool area on various surfaces are arranged outside the solid sphere at intervals. The preparation method comprises the steps of manufacturing a spherical basal body, forming a fan-shaped surface in the expansion area, splitting and the like. By means of the unique structure and the process thereof, the filling material disclosed by the invention is good in oxygenizing efficiency and rapid to hang; the specific surface area of the filling material is high; attachment of microorganisms is promoted through the fan-shaped wool area; an aerobic state is formed in the sphere; an anoxic state is formed even in the spherical centre; a biological membrane has multiple varieties of the microorganisms, long food chain and higher processing capacity; the filling material is simple to install and convenient to operate and manage; the basal body shape of the filling material is a sphere; under the stirring of aerated bubbles, the filling material can rotate at high speed; therefore, the filling material is low in resistance and mould releasing and updating are easy; the filling material takes synthetic fibre polyurethane, which has good hydrophilia, as a substrate material.
Owner:四川省科学城天人环保有限公司

Upwelling bipolar three-dimensional electrochemical reactor

The invention relates to an upwelling bipolar three-dimensional electrochemical reactor, and relates to a three-dimensional electrochemical reactor, which solves the problems of being low in current efficiency and poor in wastewater treatment effect in the existing three-dimensional electrochemical reactor. The upwelling bipolar three-dimensional electrochemical reactor disclosed by the invention comprises a cathode of a working electrode, an anode of the working electrode, organic glass screens and a particle electrode; the cathode is clamped between the two layers of organic glass screens, so that a cathode component is formed; the anode is clamped between the two layers of organic glass screens, so that an anode component is formed; the cathode component and the anode component are alternatively arranged at intervals along the vertical direction of the three-dimensional electrochemical reactor; a reaction unit is formed between the cathode component and the anode component adjacent to each other; the particle electrode is filled in the reaction unit; and a water outlet is formed below an overflow weir. According to the invention, the mass transfer distance of pollutants is shortened through the particle electrode, therefore, the current efficiency is increased, electrochemical reaction units are easy to increase, and finally, the removing rate of COD (Chemical Oxygen Demand) in wastewater is above 80%.
Owner:HARBIN INST OF TECH

Hydrophobic/hydrophilic composite membrane with nuclear track etching membrane as base membrane as well as preparation method and application of same

The invention discloses a hydrophobic/hydrophilic composite membrane taking a nuclear track etching membrane as a base membrane as well as a preparation method and application of the same. The nucleartrack etching membrane is a polyethylene glycol terephthalate nuclear pore membrane, wherein one surface of the hydrophobic/hydrophilic composite membrane is a hydrophobic polyvinylidene fluoride membrane, and the water contact angle is 90-100 degrees; a hydrophilic polyethylene glycol terephthalate nuclear pore membrane is arranged on the other surface of the membrane, and the water contact angle is 55-65 degrees. The hydrophobic/hydrophilic double-layer membrane prepared by the method is narrow and uniform in pore size distribution, good in air permeability and good in mechanical strength.A novel composite membrane structure with excellent performance is provided for membrane distillation, wherein waste heat of low-temperature feed liquid is fully utilized for direct contact type membrane distillation, concentration and separation, and the permeation flux and the heat efficiency of the process are improved. The prepared hydrophobic/hydrophilic composite membrane is good in application effect in direct contact membrane distillation and stable in operation; compared with a PVDF hydrophobic membrane supported by polyester non-woven fabric, the permeation flux of the hydrophobic/hydrophilic composite membrane is increased by 23.70%.
Owner:TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGY

Preparation method of low-resistance and high-selectivity mixed matrix membrane based on hollow MOFs material

The invention discloses a preparation method of a low-resistance and high-selectivity mixed matrix membrane based on a hollow MOFs material, and belongs to the technical field of membrane separation.The preparation method comprises the following steps: firstly, taking nano-sized carboxylated polystyrene as a hard template, enabling MOFs to grow on the surface of polystyrene, preparing nano-scalehollow MOFs microspheres through DMF etching, and blending the prepared hollow MOFs material with a polymer matrix to obtain the mixed matrix membrane. According to the preparation method, the nanoscale hollow MOFs are used as the filler, and the nanoscale MOFs material is beneficial to improving the compatibility between the MOFs and the matrix, so that the defect-free mixed matrix membrane is prepared, and the selectivity is improved; and besides, due to the existence of the hollow structure, the mass transfer distance of the mixed matrix membrane can be effectively reduced, so that the masstransfer resistance of the membrane is reduced, and the gas permeation rate is increased.
Owner:DALIAN UNIV OF TECH

Reactor capable of stratification and near true plug-flow conditions and its treatment method

The present invention provides a reactor capable of realizing stratification and close to real plug-flow conditions and a treatment method thereof. The reactor includes a reactor body filled with a composite biological carrier, and the composite biological carrier is a plurality of Layer structure, the composite biological carrier is provided with layered channels along the flow direction; the composite biological carrier includes at least one layer of main biological carrier and at least one layer of secondary biological carrier, and the porosity of the main biological carrier is higher than that of the secondary biological carrier. By adopting the technical scheme of the present invention, the fluid can reach a real pushing flow state in the biofilm reactor, and the fluid realizes a layered flow system in the narrow flow channel, and the waste water and the biofilm attached to the fixed biological carrier The maximum distance between convective and diffusive mass transfer is drastically reduced, and the overall reactor volume can typically be reduced by 25% compared to conventional systems. Moreover, due to the absence of anti-mixing and short flow, the system runs more stably and has higher processing efficiency.
Owner:柏中环境科技(上海)股份有限公司 +1
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