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136 results about "Iron(III) oxide-hydroxide" patented technology

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH)·nH₂O [Rust]. The monohydrate FeO(OH)·H₂O (CAS 51274-00-1, C.I. 77492) is often referred as iron(III) hydroxide Fe(OH)₃, hydrated iron oxide, yellow iron oxide, or Pigment Yellow 42.

Method for directly producing high-purity electronic level cobaltous sulfate by using cobalt-containing waste

The invention provides a method for directly producing high-purity electronic level cobaltous sulfate by using cobalt-containing waste, in particular a process for producing cobaltous sulfate by using cobalt-containing waste. The method comprises the steps of: checking and classifying raw materials, wet-milling and size-mixing, acid-decomposing, filtering, washing, separating, and extracting copper sponge. The method is characterized by also comprising the steps of: removing iron with a goethite process, extracting P2O4 and removing impurities, separating nickel from cobalt, extracting N235, purifying, concentrating and crystallizing. The high purity electron level cobaltous sulfate is directly regenerated by using various kinds of cobalt wastes, the requirement of the modern high-technology industry on high purity of the cobaltous sulfate is met; the total recovery of the cobalt is higher than or equal to 98 percent; various usable elements can be comprehensively recycled, and coppersponge, tungsten carbide, iron hydroxide and nickel carbonate can be regenerated while the electronic level cobaltous sulfate as a main product is regenerated. The invention has the advantages of comprehensively utilizing waste cobalt resources, recycling the wastes, improving the enterprise benefit, and being beneficial to the development of energy conservation, emission reduction, environment protection and circular economy.
Owner:HUNAN JINYUAN NEW MATERIALS CO LTD

Methods of improving surface roughness of an environmental barrier coating and components comprising environmental barrier coatings having improved surface roughness

Methods for improving surface roughness of an environmental barrier coating including providing a component having a plasma sprayed environmental barrier coating; applying a slurry to the environmental barrier coating of the component, the slurry being a transition layer slurry or an outer layer slurry; drying the environmental barrier coating having the applied slurry; and sintering the component to produce a component having an improved surface roughness where the slurry includes a solvent; a primary transition material, or a primary outer material; and a slurry sintering aid selected from iron oxide, gallium oxide, aluminum oxide, nickel oxide, titanium oxide, boron oxide, alkaline earth oxides, carbonyl iron, iron metal, aluminum metal, boron, nickel metal, iron hydroxide, gallium hydroxide, aluminum hydroxide, nickel hydroxide, titanium hydroxide, alkaline earth hydroxides, iron carbonate, gallium carbonate, aluminum carbonate, nickel carbonate, boron carbonate, alkaline earth carbonates, iron oxalate, gallium oxalate, aluminum oxalate, nickel oxalate, titanium oxalate, solvent soluble iron salts, solvent soluble gallium salts, solvent soluble aluminum salts, solvent soluble nickel salts, solvent titanium salts, solvent soluble boron salts, and solvent soluble alkaline earth salts.
Owner:GENERAL ELECTRIC CO

Method for simultaneous removal of cadmium and thallium in raw water

The invention provides a method for simultaneous removal of cadmium and thallium in raw water. The method comprises the following steps: step A, adding sodium hydroxide into raw water, adjusting a pH value to alkalescence and then adding potassium permanganate with a concentration of 0.3 to 0.8 mg/L; step B, adding sodium hypochlorite or liquid chlorine, wherein the concentration of added sodium hypochlorite or liquid chlorine is 0.5 to 2.5 mg/L in term of effective chlorine; step C, adding limewash into raw water having undergone a full oxidation reaction and adjusting a pH value to 8.5 to 9.0; step D, adding a flocculating agent, carrying out a flocculation reaction for 10 to 20 min and then carrying out deposition for at least 0.5 h so as to remove cadmium, thallium and colloids of manganese hydroxide and iron hydroxide through coprecipitation, wherein the pH value of water after precipitation drops to 7.0 to 8.5; and step E, filtering raw water obtained after precipitation by using quartz sand. The invention has the following beneficial effects: cadmium concentration of treated water is as small as the limit of a detection method, i.e., 0.02 mu g/L, or less than 0.02 mu g/L; thallium concentration of treated water is as small as the limit of a detection method, i.e., 0.01 mu g/L, or less than 0.01 mu g/L; and the pH value, manganese ions and iron ions of the treated water all meet requirements prescribed in drinking water quality standards.
Owner:SHENZHEN WATER GRP CO LTD

Ferronickel hydroxide/reduction-oxidation graphene electrochemical oxygen evolution catalyst with nickel foam as carrier and preparation method of ferronickel hydroxide/reduction-oxidation graphene electrochemical oxygen evolution catalyst

The invention relates to a ferronickel hydroxide/reduction-oxidation graphene electrochemical oxygen evolution catalyst with nickel foam as a carrier and a preparation method of the ferronickel hydroxide/reduction-oxidation graphene electrochemical oxygen evolution catalyst. The nickel foam is used as the carrier of the catalyst, ferric hydroxide, nickel hydroxide or a compound of the ferric hydroxide and the nickel hydroxide is used as the active component of the catalyst, and reduction-oxidation graphene is used as the conductive material of the catalyst. The catalyst is prepared through a water heating and impregnation method. Firstly, the nickel foam is subjected to ultrasonic cleaning and drying; then, a certain amount of nickel salt and a certain amount of urea are weighed, dissolvedin deionized water and stirred to be evenly mixed at the room temperature; then, oxidized graphene is added, ultrasonic treatment is conducted, and evenly-dispersed mixed liquor is obtained; the nickel foam and the mixed liquor are transferred into a water heating kettle and react for 12 h to 24 h at the temperature being 120-200 DEG C; the nickel foam subjected to reaction is cleaned and dried;and finally, after the nickel foam is soaked in an iron salt solution with the concentration ranging from 5 mmol/L to 30 mmol/L for 0 h to 48 h, cleaning and drying are conducted, and the ferronickelhydroxide/reduction-oxidation graphene electrochemical oxygen evolution catalyst with the nickel foam as the carrier is obtained. The catalyst is good in catalysis activity and high in stability; andthe preparation method is simple and controllable, and industrial popularization is facilitated.
Owner:EAST CHINA UNIV OF SCI & TECH

Preparation method of bagasse active carbon/ferric oxide

The invention discloses a preparation method of bagasse active carbon/ferric oxide, which comprises the following steps of: adding 800ml of distilled water into a 2L beaker, adding 100ml of 0.01-0.1mol/L hexadecyl trimethylamine bromide into the 2L beaker, heating and boiling; slowly dropwise adding 100ml of 0.5-2.5mol/L ferric chloride solution in stirring to obtain a brownish red colloid; adding 20-60g of bagasse into the brownish red colloid, stirring and standing for 24 hours; slowly adding ammonia water with the volume ratio of 1.0-10.0 percent into the 2L beaker under stirring by using an automatic titrimeter and regulating pH to 7.4 to obtain water solution of a bagasse/iron hydroxide mixed suspended matter; filtering the water solution of the bagasse/iron hydroxide mixed suspended matter and drying 105-110 DEG C to obtain a bagasse/iron hydroxide mixture; respectively carbonizing the bagasse/iron hydroxide mixture at 400-600 DEG C to obtain an active carbon/ferric oxide composite; and grinding the active carbon/ ferric oxide composite with over 60 meshes. The preparation method has the advantages of simple process and low cost, and the prepared product can be widely applied to dephosphorization production procedures in city town sewage treatment plants.
Owner:GUILIN UNIVERSITY OF TECHNOLOGY

Method of comprehensively recycling valuable metals in plating sludge

The invention belongs to the technical field of plating sludge treatment and discloses a method of comprehensively recycling valuable metals in plating sludge. The method comprises: extracting value metals from plating sludge by leaching, and isolating acid leaching residue and acid leaching liquid; adding iron powder, stirring, and filtering to isolate copper powder and a mother liquid; adding hydrogen peroxide and sodium carbonate solution, adding a composite flocculating agent so that iron ions in the solution form iron hydroxide precipitate and chromium ions form chromium hydroxide precipitate, wherein the precipitates settle fast, and isolating ferrochromium slag and a mother liquid containing zinc and nickel; using P507 extracting agent to extract zinc in the mother liquid containingzinc and nickel, back-extracting an organic phase via sulfuric acid to obtain zinc sulfate solution, and crystallizing to obtain zinc sulfate septahydrate; adding the sodium hydroxide solution into nickel raffinate, filtering to obtain nickel hydroxide precipitate, adjusting mother liquid pH to 7 for the filtrate through sulfuric acid, and crystallizing to isolate sodium sulfate decahydrate. Precipitate washing liquids herein are cyclically used, emission of wastewater is decreased, and significant economic and social benefits are created.
Owner:JIANGXI UNIV OF SCI & TECH

Ammonium polyphosphate solutions containing multi-functional phosphonate corrosion inhibitors

A corrosion-inhibited fire retardant composition is provided that comprises at least one ammonium polyphosphate, at least one suspending agent, at least one phosphonate selected from a group consisting of aminotri(methylenephosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, hexamethylenediaminetetra(methylenephosphonic acid), diethylenetriaminepenta(methylenephosphonic acid), salts thereof, and mixtures thereof and a corrosion inhibiting system. The corrosion inhibiting system is comprised of at least one corrosion inhibiting compound selected from a group consisting of azoles, insoluble ferric pyrophosphate, soluble ferric pyrophosphate, ferrous oxalate, ferric citrate, ferrous sulfate, ferric ammonium citrate, insoluble ferric orthophosphate, soluble ferric orthophosphate, ferric ammonium oxalate, ferric ammonium sulfate, ferric bromide, ferric sodium oxalate, ferric stearate, ferric sulfate, ferrous acetate, ferrous ammonium sulfate, ferrous bromide, ferrous gluconate, ferrous iodide, ferric acetate, ferric fluoroborate, ferric hydroxide, ferric oleate, ferrous fumarate, ferrous oxalate, ferrous oxide, ferric lactate, ferric resinate, and any combination thereof. Methods of making and using the same are also described. In addition, agricultural plant nutrients comprising the same are provided.
Owner:PERIMETER SOLUTIONS LP

Method for establishing photo-Fenton system for tetracycline degradation based on composite bismuth ferrite material

The invention relates to method for establishing a photo-Fenton system for tetracycline degradation based on a composite bismuth ferrite material. The method specifically comprises the following steps that 1, bismuth nitrate and ferric chloride are added to a nitrate solution, stirring is performed achieve dissolution, then a sodium hydroxide solution A is dropwise added, a pH value is regulated to be 9-10, and a mixed reaction solution is prepared; 2, graphite oxide is added to the mixed reaction solution, and ultrasonic operation is performed to obtain the co-precipitate of iron hydroxide, hydroxide bismuth and graphene; 3, the co-precipitate is centrifugally cleaned with pure water for several times, then a sodium hydroxide solution B is added to the co-precipitate to make the co-precipitate completely dissolved, and the co-precipitate is transferred to a hot water kettle for hydrothermal reaction; 4, the composite material is put in the Fenton system for tetracycline wastewater degradation. Compared with the prior art, the preparation method is simple, the controllability is good, the pollutant degradation efficiency is high, meanwhile the material stability is good, and the method can be repeatedly adopted, is low in cost and has a very good application prospect.
Owner:TONGJI UNIV

Method for separating and recycling arsenic and iron from biological oxidation solution of sulfide ore

The present invention provides a method for separating and recycling arsenic and iron form the biological oxidation solution of sulfide ore and belongs to the technique. According to the method, firstly magnesium oxide is added into the biological oxidation solution of sulfide ore, then the pH value is adjusted to 5-6 so that the arsenic and iron in the biological oxidation solution generate coprecipitation, and the precipitate comprising iron and arsenic precipitate and the neutralizing agent are obtained through separating. Then the lime is added into the neutralizing solution so that the pH value obtains 8-10. The magnesium sulfate in the neutralizing agent and the lime generate calcium sulfate and magnesium hydroxide precipitate. The precipitate containing calcium sulfate and the treated water are separated. The separated water returns to the production system and the precipitate is recycled as the building material. After the coprecipitate is dried, water is added for leaching the magnesium sulfate in the coprecipitate. The precipitate after leaching and the water extract are separated. The water extract is combined with the neutralizing agent for entering the processing operation of the neutralizing agent. The arsenic in the precipitate after leaching is leached by the sodium hydroxide solution, and the arsenic leaching solution and the iron hydroxide precipitate are obtained after separation. The arsenic leaching solution is heated, evaporated and condensed to the arsenic content of 40g / L-60g / L. Then the solution is cooled for crystallizing. The sodium arsenate and the crystal mother liquor are obtained through separation. The mother liquor returns to the arsenic leaching system.
Owner:CHANGCHUN GOLD RES INST +1

Method for removing multiple pollutants in copper smelting waste acid by using Bayer process red mud

The invention relates to a method for removing multiple pollutants in copper smelting waste acid by using Bayer process red mud. The method comprises the steps of oxidizing trivalent arsenic into pentavalent arsenic in the waste acid by using a way of continuously aerating while heating; then, adding Bayer process red mud particles, controlling an arsenic-iron molar ratio and a pH value, forming amorphous iron arsenate by using iron in the Bayer process red mud and arsenic in the copper smelting waste acid, and then oxidizing to form stable iron arsenate so as to remove the arsenic in the waste acid and absorb the multiple pollutants in the waste acid. After the scheme is adopted, iron salt used for treating the arsenic does not need to be additionally added, so that the economic cost is reduced; the method realizes the co-disposal of the solid waste produced by the copper smelting industry and the Bayer process red mud produced by the alumina industry, and reduces the secondary pollution to the environment. The method also can obtain iron hydroxide with an economic value by controlling the pH value while changing the Bayer process red mud waste into valuable and treating the wasteacid; due to the increment and decrement of input cost, an enterprise can obtain considerable economic benefit.
Owner:KUNMING UNIV OF SCI & TECH

Method for preparing high-power lithium iron phosphate composite materials

The invention relates to a method for preparing high-power lithium iron phosphate composite materials, which belongs to the technical field of the preparation of lithium battery materials. The invention aims to provide the method for preparing the high-power lithium iron phosphate composite materials which can solve the problem that lithium iron phosphate has low electronic conductivity and difficult ion diffusion in high rate discharge. The invention is technically characterized by making carbon nanotubes reflux in concentrated nitric acid containing iron salt, adding ammonia water and hydroxide ions in a lithium source into the concentrated nitric acid to react to obtain iron hydroxide suspension solution embedded with the carbon nanotubes; then adding phosphate solution into the iron hydroxide suspension solution to obtain iron phosphate suspension solution embedded with the carbon nanotubes; and performing distillation on the iron phosphate suspension solution under reduced pressure to obtain a precursor of the lithium iron phosphate, and grinding the precursor and performing high-temperature sintering in a reductive and inert atmosphere to obtain the high-conductivity lithium iron phosphate composite materials. The lithium iron phosphate composite materials have good shapes with an average grain diameter of 10 to 100nm and excellent electrochemical performance, are particularly suitable for ultrahigh rate discharge requirement, and can meet the requirement of sustained 30C discharge and pulse 100C discharge.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY

Preparation method of battery grade iron phosphate with low impurity, high iron-phosphorus ratio and large specific surface

ActiveCN108455547ALow content of metal impurity ionsLow total water contentMaterial nanotechnologyPhosphorus compoundsSulfate radicalsManganese
The invention discloses a preparation method of a battery grade iron phosphate with low impurity, high iron-phosphorus ratio and large specific surface. The iron-phosphorus ratio in the current iron phosphate is 0.97 to 1.00, however a small amount of iron hydroxide is contained in the iron phosphate and absorbs a large amount of impurity ions, so that the contents of S, Mn and Mg impurity ions are high, and the requirement of battery grade iron phosphate is difficult to meet. The method comprises the following steps: firstly, preliminarily purification and impurity removal: removing titanium,copper and aluminum impurity metal ions at high temperature; secondly, deep purification and impurity removal: removing manganese and magnesium metal ion impurities at low temperature; thirdly, performing ageing to remove sulfate radical in crude iron phosphate, adding alkali to control the endpoint pH value to be 5.5 to 6.5, and removing acidic salt; fourthly, washing and drying; fifthly, performing low-temperature calcinations to remove crystal water. Iron phosphate obtained through the method has the advantages that the iron-phosphorus ratio reaches greater than 0.975, the contents of mainimpurity elements Mn, Mg and S are smaller than 30ppm, the contents of other elements are smaller than 10ppm, the specific surface is adjustable between 8 to 12m2/g, and the total water content is smaller than 0.3 percent.
Owner:취저우화여우코발트뉴머터리얼컴퍼니리미티드 +1
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