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117results about How to "Improve media resistance" patented technology

High-performance silicone-acrylate-modified water-based epoxy emulsion and production method thereof

InactiveCN102336874AImprove adhesionExcellent closed shielding performanceAnti-corrosive paintsFilling pastesWater basedChemical industry
The invention discloses a high-performance silicone-acrylate-modified water-based epoxy emulsion and a production method thereof, relating to the technical field of production of coatings used in the chemical industry field. The emulsion is prepared with a core-shell mechanism process; in a core layer, a grafted polymer consists of low molecular bisphenol A epoxy resin, epoxy group siloxane and acrylic ester; a shell body consists of hydroxyl-containing siloxane and acrylic ester; and the shell body and the core layer are subjected to interpenetration graft polymerization. In the invention, epoxy resin is modified with an organic silicon acrylic acid monomer, so that a dense crosslinked netlike structure with a special interpenetration network and excellent enclosed shielding performance is obtained. Multiple series of anti-corrosive paints can be prepared on the basis of the high-performance silicone-acrylate-modified water-based epoxy emulsion provided by the invention by taking mixed modified amine as a curing agent. The emulsion has the advantages of easy and convenient production process, saving in energy, environmental friendliness, easiness for coating construction, low sensitivity to water vapor and temperature, extremely high substrate adhesion, high corrosion resistance, high chemical stability and wide formula adjusting range.
Owner:IANGSU JINLING SPECIAL PAINT CO LTD

High-functionality hydroxyl-terminated polyurethane aqueous dispersion as well as preparation method and application thereof

InactiveCN106866923AIncreased average hydroxyl functionalityIncrease crosslink densityPolyurea/polyurethane coatingsEthylenediamineNitrogen gas
The invention discloses a high-functionality hydroxyl-terminated polyurethane aqueous dispersion as well as a preparation method and application thereof. The preparation method comprises the following steps: adding aliphatic diisocyanate, polyvalent alcohol, a hydrophilic chain-extending agent and a catalyst into a reaction kettle; carrying out temperature rise reaction under the protection of nitrogen gas and cooling when the NCO percent of a system reaches a theoretical value; dropwise adding an acetone solution of a dihydric alcohol chain-extending agent and a crosslinking agent, continuously reacting and diluting with acetone when the NCO percent of the system reaches the theoretical value; cooling, and adding triethylamine for neutralizing; adding water for dispersing, and adding alcamines compounds for terminating; finally, carrying out post chain extending by using ethidene diamine to obtain the hydroxyl-terminated polyurethane aqueous dispersion. According to the high-functionality hydroxyl-terminated polyurethane aqueous dispersion disclosed by the invention, an alcamines terminating agent with polyhydroxy functionality is adopted, and a polyhydroxy functional group is introduced on a polyurethane chain segment by a terminating reaction of an amine group and an NCO group; the obtained aqueous dispersion has the advantages of high solid content, small particle size and stable storage; a two-component waterborne polyurethane coating prepared by the high-functionality hydroxyl-terminated polyurethane terminating dispersion has the characteristics of high drying speed of the coating, excellent medium resistance and environment friendliness of a product.
Owner:SOUTH CHINA UNIV OF TECH

Sealant of silane-terminated polymer and preparation method thereof

The invention discloses a sealant of a silane-terminated polymer and a preparation method thereof. The sealant comprises the following main components by mass: 25%-55% of a silane-terminated polymer, 0.5%-10% of a catalytic silane coupling agent, 0.1%-1% of a self-polymeric silane coupling agent, 5%-40% of a plasticizer, 10%-60% of a filling material, 0.1%-2.5% of an ultraviolet absorber, 0.1%-2.5% of a hindered amine ultraviolet stabilizer, and 0.01%-0.5% of an organotin catalyst. The method specifically consists of: (1) adding high molecular weight and low-unsaturation polyether polyol, an isocyanate compound, and an organotin catalyst into a stirring tank in order at room temperature, and heating the mixture to a temperature of 40DEG C-60DEG C, then conducting heat preservation till isocyanate content in the mixture stabilized; (2) then adding an active group methyldimethoxysilane as an end capping agent, continuing preserving heat for reaction till the isocyanate content becomes 0, thus obtaining a silane-terminated polymer; (3) adding the above silane-terminated polymer, the catalytic silane coupling agent, the self-polymeric silane coupling agent, the plasticizer, the filling material, the ultraviolet absorber, and the hindered amine ultraviolet stabilizer into the stirring tank, carrying out blending for 30-45min under vacuum protection, thus obtaining the sealant of a silane-terminated polymer.
Owner:TONSAN ADHESIVES INC

Preparation method of ultraviolet light curing composite binding agent

The invention discloses a preparation method of an ultraviolet light curing composite binding agent, belonging to the field of the binding agent. The preparation method comprises the following steps: preparing polyester polyol: preparing the polyester polyol by primary esterification, secondary esterification and condensation polymerization; preparing epoxy modified polyurethane prepolymer: reacting hydroxyl-containing epoxy resin, the prepared polyester polyol and isocyanate to prepare the epoxy modified polyurethane prepolymer; and preparing epoxy modified urethane acrylate: reacting the prepared epoxy modified polyurethane prepolymer with an ultraviolet light initiator and a polymerization inhibitor and preparing the epoxy modified urethane acrylate, namely the ultraviolet light curing composite binding agent. By designing chain segments of a polyester structure and properly matching the types and quantity of alcohol acids, the invention prepares high-performance polyester, and introduces the epoxy resin into the polyurethane prepolymer chain segments so as form the ultraviolet light curing composite binding agent at the two ends, thus improving the binding and anti-medium performances of the ultraviolet light curing composite binding agent, omitting the adding of a polyfunctional active diluent with larger toxicity and being more environment-friendly.
Owner:NANTONG GAOMENG NEW MATERIAL

Emulsion used for quick-drying high-gloss high-weatherability waterborne alkyd paint, and preparation method thereof

The invention discloses an emulsion used for quick-drying high-gloss high-weatherability waterborne alkyd paint, and a preparation method thereof. The emulsion is composed of 28 to 16.5 parts of alkydresin; 5 to 15 parts of an alcohol ether solvent; 7 to 38.5 parts of an acrylate monomer initiator solution; 1.3 to 4.5 parts of a neutralizer; and 58.7 to 25.5 parts of deionized water. The preparation method comprises following steps: an alkyd resin with an appropriate acid value is prepared, alcohol ether is taken as a solvent, under the effect of an oil soluble initiator and a chain transferring agent, an anionic unsaturated monomer, a short chain unsaturated monomer, a long carbon chain acrylate monomer, and the alkyd resin are subjected to free radical copolymerization to prepare an acrylic acid modified alkyd resin; amine neutralizing is carried out, and water is adopted for dispersion so as to obtain the emulsion used for quick-drying high-gloss high-weatherability waterborne alkyd paint. The preparation method possesses following characteristics: monomer kind selection and composition range is wide; the raw materials are easily available; the process is convenient to control;popularization and applications in practical industrialized production are convenient; and the waterborne alkyd paint prepared from the emulsion possesses quick drying performance, high gloss, and high weatherability.
Owner:陕西宝塔山油漆股份有限公司

Normal-temperature self-crosslinking type core-shell structure acrylate emulsion as well as preparation and application thereof

The invention belongs to the technical field of film printing materials, and discloses a normal-temperature self-crosslinking type core-shell structure acrylate emulsion as well as preparation and application thereof. The preparation method comprises the steps: carrying out dehydrogenation condensation reaction on a vinyl polyether monomer and a hydrogen-containing silane coupling agent to obtain a modified macromonomer; heating a core-layer monomer emulsion composed of styrene, methacrylate and acrylate to 55-85 DEG C, and then adding an initiator solution to carry out polymerization reaction to obtain a core-layer emulsion; and dropwise adding a shell monomer emulsion composed of methacrylate, acrylic acid and a modified macromonomer and an initiator solution, and continuously carrying out a polymerization reaction to obtain the normal-temperature self-crosslinking type core-shell structure acrylate emulsion. According to the invention, the modified macromonomer with the specific structure is used as a shell polymerization monomer, so that the product can be endowed with a normal-temperature cross-linking characteristic, the adhesive force is enhanced, the wettability is improved, and the water resistance is good. The emulsioncan be used for preparing water-based ink and water-based latex paint.
Owner:李星明

Rubber-polytetrafluoroethylene compounded sealing ring

The invention relates to a rubber-polytetrafluoroethylene compounded sealing ring which comprises a ring-shaped body, wherein the ring-shaped body is a silicon rubber ring-shaped body or a fluororubber ring-shaped body. The sealing ring is characterized in that a polytetrafluoroethylene felt pad is wrapped outside the ring-shaped body. The compounded sealing ring can be used for comprehensively improving the mechanical property and the chemical stability of a rubber sealing ring as well as the wear resistance and the medium corrosion resistance of a compounded sealing ring, enhancing the corrosion resistance, the adhesion resistance and the sealing rebound resilience of rubber, increasing the oil resistivity on the surface of the rubber, obviously improving the high-temperature and low-temperature resistance of the surface of the rubber, obviously reducing the friction consumption, keeping the physical mechanical property of the rubber unchanged and also improving the strength and the hardness of the rubber. In addition, the invention also ensures that the using range of the rubber sealing ring is further expanded, and moreover, the service life of the rubber sealing ring coated with the polytetrafluoroethylene felt pad is obviously prolonged by 5-6 times. The rubber-polytetrafluoroethylene compounded sealing ring is suitable for equipment of pipeline systems in the chemical industry, and the like.
Owner:SHANGHAI JINYOU FLUORINE MATERIALS
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