The application discloses a method for deeply removing
fluorine in
zinc sulfate solution, which comprises the following specific steps: (1) adding aluminum
sulfate into the pre-neutralized
zinc sulfate solution to perform pre-defluorination, and then performing liquid-
solid separation to obtain defluorinated solution; (2) sequentially adding calcine and slaked
lime into the defluorinated solution, and then performing liquid-
solid separation. The method does not change the main process
route, only adds aluminum sulfate particles into the pre-neutralized solution, and outputs defluorination
slag by pressure
filtration to open a channel, and the
fluorine in the solution is removed by the aid of 10% iron ions in the process, the process adjustment does not need additional investment, and the original matching equipment and facilities can completely realize the removal of
fluorine in the solution, the economic cost of the method is less than that of defluorination by a defluorination agent, the defluorination rate is high, the pre-removal of aluminum sulfate reaches 60%, the deep removal of fluorine by
colloidal iron is realized, and the total fluorine removal rate reaches more than 90%.