The invention discloses an anion coating solution for air purification. The anion coating solution is prepared from, by weight, anion powder, distilled water, sodium polyacrylate, lauryl glucoside, glycol, 2-imidazolidone, citric acid, zinc oxide, lauryl betaine, tert-butyl acetate and a monoalkoxy-titanates coupling agent; nanoscale tourmaline powder, nanometer titania, sodium silicate, methyl alcohol and 2-alkyl acetamido ethyl imidazoline are added into a high pressure reaction kettle, the mass ratio of the nanoscale tourmaline powder to the nanometer titania, sodium silicate to the sodium silicate to the methyl alcohol to the 2-alkyl acetamido ethyl imidazoline is 1:(3-5):(1.5-2):(2-4):(3-5), and the prepared slurry mixed solution is subjected to a hydrothermal reaction. The anion coating solution can be thoroughly attached to the surfaces of pollutants, no dead corner exists during formaldehyde removal, the using effect is more obvious and more direct, the interfacial effect is larger, the toxic gas adsorption rate is further increased, the adsorptivity is stronger, and a formed nanometer film and the surface of an object are fused more directly.