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51results about How to "Achieve cleaner production" patented technology

Comprehensive utilization method of sweet sorghum straw and juice thereof

The invention discloses a comprehensive utilization method of sweet sorghum straw and juice thereof, which comprises the following steps: juicing sweet sorghum straw, separating the juice from straw residues, performing steam explosion of the sweet sorghum straw residues to obtain steam exploded straw and a steam exploded straw eluate; performing enzymatic hydrolysis of the steam exploded straw, mixing with the sweet sorghum juice, controlling the sugar content to be 6%-7%, adding a nitrogen source, performing acetone butanol fermentation to produce acetone, butanol and ethanol; inoculating bacteria into the fermentation residues to produce feed protein; performing decoloration, detoxification, and enzymatic hydrolysis of the steam exploded straw eluate to extract xylo-oligosaccharides. The invention realizes graded utilization of saccharides, cellulose and hemicellulose in sweet sorghum, can produce xylo-oligosaccharides, and can produce fermentation products such as acetone, butanol, ethanol, feed protein and the like through biotransformation. The invention realizes the comprehensive utilization of sweet sorghum straw resources, has no waste material or pollutant discharge during the production, realizes cleaner production, and has good social benefit and economic benefit.
Owner:江苏联海生物科技有限公司

Mixed pulp compound papermaking pulp substrate as well as preparation method and application thereof

The invention provides a mixed pulp compound papermaking pulp substrate as well as a preparation method and an application thereof. The mixed pulp compound papermaking pulp substrate is prepared from following raw materials in parts by weight: 70-80 parts of bamboo pulp, 5-15 parts of reed pulp, 5-15 pats of cane syrup, 2-8 parts of fluff pulp and 0-2 parts of fly ash. The preparation method comprises the following steps: pulping, preparing the pulp, carrying out high-concentration degritting, grinding the pulp, carrying out low-concentration degritting, carrying out pressure screening, slushing, compounding and making paper with the pulp, drying and the like. The raw materials of the mixed pulp compound papermaking pulp substrate are selected from perennial wild herbaceous plants, processing industrial wastes, and fire coal wastes of power planes and industrial boilers; a product is uniform in texture and smooth in surface; no pollutants are discharged in a preparation process; water for diluting, agitating and conveying can be cyclically utilized; the mixed pulp compound papermaking pulp substrate provided by the invention can be used for producing electric mats and cockroach killing pieces or can be used as an industrial filtering material.
Owner:苏州吉臣日用品有限公司

Waste incineration improved process

The invention discloses a waste incineration improved process comprising the following step 1 of performing sorting treatment to wastes, and obtaining perishable organic matters and comburents; the step 2 of putting the comburents into an incinerator for incineration power generation; and the step 3 of degrading the perishable organic matters by using aerobes, and converting the organic matters into organic materials. The problems that the heat value of materials added to a furnace is low, and combustion-supporting materials need to be added; and the operating cost is high and the overall benefit is poor are solved. According to the improved process, the overall heat value of remaining wastes after sorting can be improved greatly, and the wastes are conveyed into the furnace and burnt quickly; the combustion-supporting materials (coal, fuel, natural gas and the like) are not required; not only are energy sources saved, but also the operating cost is reduced; not only is the amount of the wastes added to the furnace reduced, but also the combustion-supporting materials are not required; the emission of waste gas is reduced greatly, and pollution to environment by atmospheric pollutants is reduced; the cost for waste gas purification and treatment is decreased; and the problems that the heat value of the materials added to the furnace is low and the combustion-supporting materials need to be added; and the operating cost is high and the overall benefit is poor are solved.
Owner:王英宾

Technology for preparing salviae miltiorrhizae oral liquid with ceramic membrane

A technology for preparing salviae miltiorrhizae oral liquid with a ceramic membrane is characterized by comprising the following steps of decoction, concentration, centrifugal filtration through a high-speed centrifuge, primary filtering by ceramic membrane with the hole diameter of 150000-180000 molecular weight, secondary filtering by ceramic membrane with the hole diameter of 80000-120000 molecular weight, ultrafiltration by ceramic membrane with the hole diameter of 20000-50000 molecular weight, nanofiltration concentration by ceramic membrane with the hole diameter of 300-450 nanometers, concentrating medicine liquid to the amount 2.5-3.5 times that of medicinal materials, final preparation and embedment sterilization. Heating processes in the whole technology course are reduced, ceramic membrane filtering with different molecular weights and refining under normal temperature are carried out, impurities are effectively removed, effective constituents are reserved to the maximum degree, an extracting technology is shortened, pollution is lowered, energy is saved, clean production is achieved, the technology accords with traditional Chinese medicine theoretical system, an ultrafiltration membrane filtering technology is used, degerming and pyrogen effect is good, and the clarity of medicine liquid is guaranteed and improved.
Owner:江苏恒沣药业有限公司

Method for preparing propylene glycol monomethyl ether acetate (PMA) by continuous reaction and distillation

ActiveCN101838196AReduce the unit consumption of acetic acidReduce equipment corrosion rateOrganic compound preparationCarboxylic acid esters preparationDistillationFixed bed
The invention discloses a method for preparing propylene glycol monomethyl ether acetate (PMA) by continuous reaction and distillation. The method comprises the following steps of: mixing propylene glycol methyl ether and acetic acid serving as raw materials in a mol ratio of 1 to 1, and preheating the mixture; allowing the mixture to enter a fixed bed reactor for pre-reaction and then enter an esterification reactor for temperature raising and further reaction; performing rectification, condensing and phase-splitting on the gasified reaction crude product to obtain an oil phase and a water phase; refluxing a part of the upper-layer oil phase to an esterification tower top and the rest to a crude ester jar for preliminary treatment and then light components removal treatment; refluxing a part of the collected lower-layer water phase to the esterification tower top and allowing the balance to the recovery section for treatment, wherein the catalyst for the fixed bed reaction is sulfonyl strongly acidic ion-exchange resin; and the catalyst for the esterification reactor is one of sulfuric acid, methanesulfonic acid, p-toluenesulfonic acid and mixed catalyst A. The method realizes the continuous and pollution-free production of the PMA.
Owner:JINJIANG TAIXING CHEM IND CO LTD

Chemical reaction system for producing oxalic acid diester and oxalic acid as main products by using sodium formate as raw materials

The invention discloses a chemical reaction system for producing oxalic acid diester and oxalic acid as main products by using sodium formate as raw materials. The chemical reaction system comprises a first reaction unit, a second reaction unit and a third reaction unit, wherein the sodium formate is subjected to dehydrogenation reaction to generate sodium oxalate in the first reaction unit; in the second reaction unit, the sodium oxalate is mixed with solvents, then, the oxalic acid is added, the reaction is carried out, and then, the solid and liquid separation is carried out, wherein the solid phase is phosphate, and the oxalic acid diester is rich in the liquid phase; and in the third reaction unit, the oxalic acid diester-rich liquid phase is subjected to distillation separation, then, the oxalic acid diester is respectively subjected to hydrolysis, hydrogenolysis and ammonolysis, and oxalic acid, alcohol, glycol and oxamide are obtained. The chemical reaction system disclosed by the invention has the advantages that the influence on environment is avoided, the environment problems of lead-containing sewage and other waste discharge do not exist, phosphates from sodium ions and with higher additional values are generated, the process separation becomes simple, the implementation is easy, and the production process reaches the requirements of clean production and energy saving environment-friendly type production process.
Owner:天津市碳一有机合成工程设计有限公司

Method for recycling phosphorous acid from dimethyl ester rectification residual liquid

The invention provides a method for recycling phosphorous acid from a dimethyl ester rectification residual liquid, wherein the method mainly includes the following steps: (1) heating the dimethyl phosphite rectification residual liquid, and decoloring with active carbon; (2) filtering the solution after decoloring in the step 1 while being hot, and collecting the filtrate; (3) dropping hydrochloric acid, controlling the dropping speed, the acidolysis temperature and the vacuum degree, and stirring fully until acidolysis is completed; (4) when no obvious gas is discharged after acid dropping, stopping acid dropping, after the acid dropping is stopped, if gas is still discharged, requiring to appropriately supplement hydrochloric acid, and allowing tail gas generated in the acidolysis process to be merged into a chloromethane recycling header pipeline; and (5) obtaining an aqueous solution having chloromethane gas removed, namely liquid phosphorous acid, concentrating and crystallizing the aqueous solution, and purifying to obtain solid phosphorous acid with the content of more than or equal to 98% or directly taking as an aqueous solution for use. The method achieves clean production, reduces three-waste emissions, improves the by-product recovery rate, and reduces the production cost.
Owner:ANHUI DONGZHI GUANGXIN AGROCHEMICAL CO LTD

Method for preparing 1,5-pentamethylene diisocyanate

The invention relates to a method for preparing 1,5-pentamethylene diisocyanate (PDI). The method comprises the following steps: taking o-dichlorobenzene as a solvent and trimethylchlorosilane as a catalyst, carrying out luminescence reaction on 1,5-pentanediamine and phosgene at 15-30 DEG C under normal pressure to generate diaminoformyl chloride; after the reaction is finished, heating the reaction materials to 110-120 DEG C, and evaporating out a small amount of solvent and all the catalyst for recycling; continuously introducing a certain amount of phosgene into the diaminoformyl chloride,heating to 150-170 DEG C, and carrying out thermal photo-chemical reaction until the material becomes clear and transparent; and after the photo-chemical reaction is finished, carrying out reduced pressure distillation to remove the solvent, and continuously carrying out reduced pressure distillation to obtain the 1,5-pentamethylene diisocyanate product. Trimethylchlorosilane is used as a catalyst, so that the generation of hydrochloride can be avoided, and the generation of polymerization byproducts caused by the secondary reaction of amine with acyl chloride and isocyanate generated in thelow-temperature photo-chemical reaction can also be avoided; the PDI product yield and the product quality in the photo-chemical reaction process are greatly improved.
Owner:甘肃银光聚银化工有限公司

Method using glycerol and silicon tetrachloride to prepare epichlorohydrin and white carbon black

The invention relates to a method using glycerol and silicon tetrachloride to prepare epichlorohydrin and white carbon black, which belongs to the technical field of chemical industrial preparation. The method comprises using biomass glycerol in grease processing byproducts and silicon tetrachloride in polysilicon industry byproducts, hydrolyzing the silicon tetrachloride in a non-proton solvent to obtain silica gel and byproduct hydrochloric acid (HCl), chloridizing the glycerol in the present of a catalyst by the byproduct HCl to achieve glycerol dichloride and byproduct water which is used for hydrolysis of the silicon tetrachloride. The silica gel is thermally treated to obtain the white carbon black, and the glycerol dichloride is saponified to obtain the epichlorohydrin. The white carbon black and the epichlorohydrin can be prepared on the situation without external sources of water and HCl, so that the purposes of saving energy, reducing emission, cleaning production and reducing product cost are achieved. The method uses the non-proton solvent as a reaction medium, thereby improving heat and mass transfer in a coupling reaction process, improving reaction selectivity, preventing generated silica gel from being adhered to equipment and pipelines to block the equipment and the pipelines and enabling reaction to stably run for a long time.
Owner:CHANGZHOU UNIV

Circulating high-temperature flue gas flowing-state non-blocking tubular bagasse drying system

A bagasse heating and drying system is composed of a high-temperature flue gas pipe inlet, a high-pressure fan, a flue gas pipe, a bagasse inlet, a discharging valve, cyclone-type fire extinguishers, a cyclone separator, a flue and a circulating high-pressure fan. The high-temperature flue gas pipe inlet is mounted in front of a high-temperature coal economizer, the high-temperature fan is connected with an incoming and outgoing pipe of the high-temperature flue gas pipe, and a bagasse inlet and the discharging valve are mounted above the high-temperature flue gas pipe. A small amount of high-temperature flue gas in front of the coal economizer is utilized to heat and dry bagasse, and the bagasse is enabled to reach high temperature before catching fire and enabled to be fully burnt in the process of burning, so that temperature of a hearth is increased, heat radiation is enhanced, and heat efficiency of a boiler is improved; the flue gas after being dried is drawn by the circulating high-pressure fan into the boiler to serve as disturbing air to be used so as to realize heat balance running of the boiler; balance ventilation is adopted, so that the drying system is enabled to run under a non-blocking state and enabled to realize clean production, energy conservation and emission reduction, and plays an important role in promoting economy development of cane sugar industry and improving enterprise benefit and social benefit.
Owner:覃天毕
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