723results about How to "Reduce the discharge of three wastes" patented technology

The invention discloses a method for synthesizing fluorine-containing antiform alkyl cyclohexyl biphenyl single liquid crystal; in the method, bromobenzene and magnesium are selected to carry out Grignard reaction; then the reactants are coupled and hydrolyzed with alkyl cyclohexanone; dehydration, hydrogenation, transformation and iodization are carried out to synthesize alkyl cyclohexyl iodide; the Grignard reaction is carried out on fluorobromobenzene and magnesium, then low temperature coupling is carried out to synthesize p-fluoropheyl boric acid; finally, coupling reaction is carried out to synthesize the target compound; the method of the invention has the characteristics of use of highly active load catalyst, high yield, low production cost, little discharge of three wastes, reduction of generation of isomers and improvement of selectivity and yield of the target compound.

The invention discloses a preparation method of amphoteric polyacrylamide dispersion liquid. The preparation method comprises the following steps: putting a main functional monomer into a mixed system comprising an amphoteric dispersion stabilizer, a chelating agent, a pH regulator and inorganic salt deionized water solution; initiating a reaction by virtue of an initiating agent; and preparing the amphoteric polyacrylamide dispersion liquid by virtue of a dispersion polymerization method. The dispersion liquid prepared by adopting a novel amphoteric polymer dispersion stabilizer has the characteristics of good stability, high molecular weight, high dissolution rate and the like, and a synthetic process of the dispersion liquid is environment-friendly and pollution-free and is low in energy consumption, and the product is nontoxic and noncorrosive, cannot generate secondary pollution and accords with the development direction of green and environment-friendly chemical assistants. The amphoteric polyacrylamide dispersion liquid has an application prospect in the fields of water treatment, papermaking, printing and dyeing, oil fields, mining, daily chemicals and the like.

The invention provides a method for producing caprolactam by taking high-purity benzene as a raw material, and the method comprises the following steps of: A. preparing cyclohexene from the raw material benzene through hydrogenation; B. separating and purifying cyclohexene; C. carrying out hydration on the cyclohexene for preparing cyclohexanol; D. separating and purifying cyclohexanol; E. carrying out dehydrogenation on cyclohexanol for preparaing cyclohexanone; F. refining cyclohexanone; G. carrying out oximation on cyclohexanone so as to prepare cyclohexanone-oxime; H. refining cyclohexanone-oxime; I. carrying out rearrangement on refined cyclohexanone-oxime so as to prepare caprolactam; and J. refining caprolactam, wherein the high-purity benzene is adopted as a raw material, so that the purity of benzene is more than 99.95%, the sulphur content is less than 5ppm, and the methylbenzene is not more than 100ppm. The method has the beneficial effects that the high-purity benzene is adopted as a raw material, so that the impurity is less, and the product quality is high; the raw material is high in comprehensive utilization rate and low in hydrogen consumption; and the mass of the raw material and intermediate products generated in all the steps of reaction can be strictly controlled, so that the direct commercial value of the intermediate products is fully exerted, and the optimal quality of the product caprolactam can be reached.

The invention discloses a preparation method of hexamethylenediamine. The method is used for preparing 1, 6-hexamethylenediamine by virtue of carrying out ammoniation and catalytic hydrogenation on 1, 6-adipaldehyde. The method is simple in process, low in cost, high in yield, low in energy consumption and free from industrial three wastes.

The invention discloses a method for comprehensively recovering copper and indium from lead matte. The method comprises the following steps: A, crushing lead matte block materials and then ball-milling to obtain lead matte powder; B, leaching the lead matte powder obtained by ball-milling in an autoclave by using sulfuric acid and continuously introducing oxygen in the leaching process; C, after leaching, carrying out solid-liquid separation to obtain leaching residues and leachates containing copper ions and indium ions; D, selectively extracting the copper ions in the leachates by using ZJ988, obtaining copper sulfate enrichment liquid by using a sulfuric acid-copper sulfate solution to perform reverse extraction on loaded organic phase, taking the copper sulfate enrichment liquid as an electrolyte of electro-deposit copper and obtaining cathode copper through a copper sulfate electro-deposition process; E, selectively extracting the indium ions by using P204, then obtaining indium chloride enrichment liquid by using a hydrochloric acid solution to perform reverse extraction on the loaded organic phase and replacing the indium chloride enrichment liquid by using a zinc plate or an aluminum plate to obtain sponge indium. The method has the benefits that the complete separation of the copper from the indium in the lead matte is realized, recovery rate of the valuable metal is high, and the environmental friendliness is realized.

The invention discloses a method for preparing a pure acrylate copolymer coating emulsion for a building external wall elastic coating, including a preparation method of a seed emulsion, a pure acrylate type elastic emulsion prepared from the seed emulsion and a preparation method thereof, as well as an elastic coating prepared from the elastic emulsion added with auxiliaries, a filler and the like, wherein the ratio (by wt) of comonomers St:MMA:BMA:BA of the copolymer of the seed emulsion is (32-42):(18-27):(18-27):(12-22); the hansch constant of the polymer of the seed emulsion is 3.00-3.81 pKa; and the elastic emulsion is obtained through seed polymerization of a monomer mixture which is composed of acrylic acid (AA), acrylamide (AM), butyl acrylate (BA), methyl methacrylate (MMA) and n-butyl methacrylate (BMA) in a monomer ratio (wt) of (0.8-5):(0.8-5):(25-45):(7-33):(7-33). As the elastic coating prepared from the pure acrylate type elastic emulsion prepared by the method provided by the invention is obviously improved in properties such as stain resistance, weather fastness, low-temperature elasticity, adhesiveness, water tolerance and the like, the elastic coating can be used as an external wall decorative coating high in requirement for durability and thus can be widely applied to the field of building coating.

The invention provides a synthesis method of 5-bromo-2-chloro benzoic acid.The method includes the following steps of A, making 2-chlorine benzotrichloride and bromide reagents react under the effect of a catalyst to obtain 2-chloro-5-bromine benzotrichloride, wherein bromide reagents include one or more of bromine, N-bromosuccinimide, dibromohydantoin and hydrobromic acid; B, conducting hydrolysis reaction on 2-chloro-5-bromine benzotrichloride in the step A under the acid condition to obtain 5-bromo-2-chloro benzoic acid.According to the method, 2-chlorine benzotrichloride which is low in price and easy to obtain is adopted as the raw material, operation is easy, intermediates do not need to be purified, 5-bromo-2-chloro benzoic acid is synthesized through a one-pot method, purity is high, yield is high, three-waste emission is little, and production cost is low.It is shown through experiment results that 2-chloro-5-benzoic acid obtained according to the synthesis method has yield larger than 95% and purity of 80-92%.

A method for realizing the solid phase synthesis of cetrorelix comprises the following steps that: Fmoc-Linker-MBHA-Resin is used as a starting raw material and is connected in turn with amino acid with Fmoc-protecting groups according to a solid phase synthesis method, so as to obtain protective decapeptide resin; meanwhile, the Fmoc-protecting groups are divested in turn; one sort of HBTU/HOBT or DIC/HOBT is used as condensing agent to carry out synthesized peptide, thereby obtaining protective decapeptide resin; acetylation reaction is carried out, and then protecting group side chain divesting and peptide cutting are carried out synchronously to obtain cetrorelix acetate which is separated and purified through C18 or C8 chromatographic column; finally, cetrorelix acetate acetate or trifluoroacetate is obtained after freeze drying.

The invention relates to a novel method for generating bisphenol A and dialkyl carbonate by chemical degradation of waste polycarbonate (PC) to realize chemical recycling of the bisphenol A and the dialkyl carbonate. The method is characterized in that reusable ionic liquid such as chloridized 1-allyl-3-methylimidazole and bromized 1-butyl-3-methylimidazole is taken as a reaction medium and catalyst, and subjected to hydrolysis reaction or alcoholysis reaction at a temperature of between 60 and 170 DEG C; after reaction is over, bisphenol A products are obtained after extraction, distillation and other operations (as for alcoholysis reaction, the dialkyl carbonate is obtained simultaneously); reclaimed ionic liquid is directly reused without any treatment; and the yield of the bisphenol A is more than 93 percent. Compared with the prior art, the method has the characteristics that: firstly, the method overcomes the defects in the prior art that high-concentration inorganic strong acid/strong alkali is applied and can not be recycled; and secondly, due to adoption of the ionic liquid which has certain solubility on the PC as the reaction medium and the catalyst, the method relieves the reaction conditions on one hand and can realize reutilization of the ionic liquid on the other hand, and obviously solves the problems of equipment corrosion and environmental pollution.

The invention relates to a method and a device for treating dichlorosilane waste by utilizing reactive distillation. A reactive distillation tower is divided to three segments, namely a distillation segment, a reaction segment and a stripping segment, wherein a tower top condenser is arranged on the top of the reactive distillation tower; a tower bottom reboiler is arranged at the bottom of the reactive distillation tower; a cooler is arranged at the bottom of the reactive distillation tower; an inlet of the cooler is connected with a tower bottom material outlet through a pipeline; an outlet of the cooler is connected with an inlet of a low-temperature cooler; and an outlet of the low-temperature cooler is connected to the reactive distillation tower through a pipeline. Raw materials silicon tetrachloride and dichlorosilane respectively enter the reactive distillation tower from the top and the bottom of the reaction segment to generate a disproportionated reaction in the reaction segment so as to produce trichlorosilane, and the trichlorosilane is continuously moved out of the reaction segment under the action of distillation separation; and the silicon tetrachloride in the materials of the tower returns back to the reactive distillation tower through external circulation from the top of the reaction segment so as to further react, and therefore the conversion rate of the reaction can be improved. The conversion rate of the dichlorosilane can achieve 98.50% and the purity of the trichlorosilane in the materials on the top of the tower can achieve 98.48%.

The invention belongs to the field of polypeptide synthesis, relating to a method for preparing teriparatide by solid-liquid combination. The method adopts a liquid phase mode to synthesize a part of dipeptide and tripeptide fragments, feeding is performed by the synthesized dipeptide and tripetide fragments, 13 steps of solid phase coupled reaction are reduced, the coupling efficiency is greatly improved, not only is the generation of racemization impurities difficult to be purified and removed at the 34th site tail end avoided, but also the generation of missing peptides at multiple sites is avoided, and the purity of the final target peptide reaches 75 percent or more. Compared with the prior art, the method provided by the invention is simple in synthetic route, less in solid phase coupling steps, mainly solves the problems that a peptide sequence is too long and coupling is difficult, and that the missing peptides are easily generated, the fragment synthesis technology is well developed, the materiel cost is lowered, and the industrialized mass production can be carried out.

The invention belongs to the chemical field, in particular to method and equipment for producing C1-C2 low-carbon alcohol ester of C4-C6 diacid. The method is characterized by comprising the following steps of: adding a catalytic agent, C4-C6 diacid and C1-C2 alcohol to a dispensing kettle, stirring and heating to enable the solid diacid to be dissolved; and then continuously delivering feed liquid to an esterification reactor to carry out esterification reaction under the conditions of a certain pressure, a certain reaction temperature and the like; continuously delivering an obtained esterification reaction mixture to a flash evaporator for flash evaporation; separating out unreacted alcohol and generated water from the upper part of the flash evaporator; discharging the product ester and unreacted raw material acid from the lower part of the flash evaporator; and then rectifying to obtain the C1-C2 alcohol ester of the C4-C6 diacid. The invention has the characteristics of low energy consumption and continuous esterification production, and aims to solve the problems existing in the aspects of long time, high energy consumption and the like in the esterification reaction for traditionally producing the C1-C2 low-carbon alcohol ester.

The ester ether compound with high acidolysis activity is synthesized through the reaction between benzil acid (2,2-diphenyl glycolic acid) and phenols, each of which has at residual active point in its benzene ring, in the presence of p-toluene sulfonic-acid catalyst in 0.1-2 % and methyl benzene, dimethyl benzene and other benzene compound as solvent to synthesize a serial addition compound of benzil acid and phenols which may be further dewatered to produce lactone compound; and the etherification of the said addition compound or the lactone compound the ether compound, such as vinyl ethylether, dihydropyran, dihydrofuran, dihyidropyrrole, etc. at below 70 deg.c. The ester ether compound may be used as photothermal imaging information record material.

The invention discloses a new method of chloroethylene through acetylene method and specific equipment, which comprises the following steps: disposing raw material gas strictly; reacting two-segment compensation; recycling heptane; cooling; radiating; providing specific catalyst and reactor to synthesize chloroethylene; disposing effluent with mercury to obtain high-purity chloroethylene monomer.

The invention discloses a co-production method for methyl benzoic acid and phthalic acid. The co-production method comprises the following steps: (1) continuously introducing fresh dimethylbenzene, a catalyst and oxygen-containing gas into a primary oxidation reactor for a reaction to obtain a primary oxidation reaction solution containing methyl benzoic acid and an eight-carbon oxygen-contained compound; (2) carrying out continuous cooling, crystallization and filtration on the primary oxidation reaction solution to obtain filter liquor and filter cake, circulating 1-98% of the filter liquor back the primary oxidation reactor continuously, and continuous rectifying the filter cake continuously, to obtain a low-boiling point front cut fraction, distillation raffinate and a methyl benzoic acid product separately; (3) adding the remaining filter liquor in the step (2) and the obtained front cut fraction and distillation raffinate in the step (2) into a secondary oxidation reactor continuously, and meanwhile continuously introducing a Co/Mn/Br catalyst, acetic acid and oxygen-containing gas into the secondary oxidation reactor for an oxidation reaction to obtain a secondary oxidation reaction mixture; and (4) continuously cooling, crystallizing and filtrating the secondary oxidation reaction mixture to obtain a filter liquor and a phthalic acid product. The co-production method has advantages of a simple process, a low cost, a high yield, good selectivity, good economic benefits, and environmental protection.

The present invention relates to an activated coke for absorbing persistent organic pollutant like dioxin in flue gas and a preparation method thereof by using coal quality semi coke as a raw material. The preparation method is as follows: crushing the coal quality semi coke; impregnating the coal quality semi coke with an impregnating solution containing metal hydroxide or alkali metal carbonate activator and compound surfactant, and naturally drying; and finally activating the impregnated and dried semi coke at 800-950 DEG C to prepare the activated coke for absorbing dioxin in flue gas. The activated coke has characteristics of developed porous structure, low manufacturing cost and good adsorption effect, etc.

The invention provides a novel method for preparing battery grade lithium carbonate by using tantalum niobium tailings lithium mica. The method is characterized by comprising the following steps of: crushing lithium mica powder until granularity is 100 to 200 meshes, adding the crushed lithium mica powder and 30 to 70 percent sulfuric acid solution in a solid and liquid mass ratio of 1:(2-8) into a reaction device, reacting at the temperature of between 60 and 200 DEG C for 3 to 10 hours to obtain the sulfuric acid solution which contains Li<+>, and separating to remove fluorine-containing solution; performing filtering separation on the sulfuric acid solution which contains the Li<+>, and fully washing the filter residue with water to remove the filter residue and obtain filtrate which serves as mother liquor 1; changing the temperature of the mother liquor to be between 10 and 100 DEG C with stirring, separating solids, namely rubidium, caesium and alum, performing filtering separation, washing the filter residue, and recovering the filtrate as mother liquor 2; adding calcium hydroxide into the mother liquor 2, and controlling the pH value of the solution to between 2 and 7 to obtain solid and liquid mixed solution of neutralization reaction; performing filtering separation on the solid and liquid mixed solution, washing and filtering the filter residue, and recovering the filtrate as mother liquor 3; performing evaporation concentration on the mother liquor 3, controlling the concentration of the Li<+> in the solution to be between 40 and 65g/l, and filtering to obtain the filtrate serving as mother liquor 4; and blowing carbon dioxide into the mother liquor 4 at the temperature of between 95 and 105 DEG C under 2 atmospheres and performing lithium-sinking reaction for 40 to 100 minutes, filtering and mechanically separating to obtain lithium carbonate, washing with water, and drying to obtain the battery grade lithium carbonate product.

The invention relates to an activity enhanced ketoreductase mutant, which is derived from wild-type ketoreductase of Candida magnoliae, can transform 4-chloroacetoacetic acid ethyl ester into (S)-4-chloro-3-hydroxy butyric acid ethyl ester, and has one or more mutations of E9R, S42Q, T190L and E234M. The ketoreductase mutant provided by the invention has obvious high specific enzyme activity, which is increased by 2-20 times than wild-type ketoreductase. According to the invention, the reaction conditions are mild, the requirement for equipment is low, the production process has need for high temperature or cooling, the energy consumption is low, and as enzyme catalysis has high efficiency and specific selectivity, production of the statin drug key intermediate (S)-4-chloro-3-hydroxy butyric acid ethyl ester by the method generates no by-product, and purification can be convenient. In addition, most solvents involved in the reaction of the invention are water, thus having low discharge of three wastes, and being green and environment-friendly.

The invention discloses a method for manufacturing N-phosphonomethyliminodiacetic acid (PMIDA). The method comprises the following steps: (1) IDA disodium salt source is reacted with sulphuric acid to obtain IDA monosodium salt solution; (2) the IDA monosodium salt solution is then reacted with sulphuric acid to separate out iminodiacetic acid (IDA), and reaction mother liquor is treated by liquid alkali to obtain Na2SO4 after evaporated dehydration; moreover, the mother liquor is treated as the raw material of the step (2); (3) the IDA is mixed with phosphorous acid and formaldehyde to generate PMIDA through reaction under the condition of sulphuric acid, wherein the PMIDA is obtained through cooling crystallization and filtration after formaldehyde-containing waste water is separated through evaporation; the mother liquor is treated as the raw material of PMIDA; the formaldehyde-containing waste water separates concentrated and reclaimed concentrated formaldehyde through a pervaporation membrane separating device, and the separated concentrated formaldehyde is treated as formaldehyde raw material; and discharged water is used for reclaimed water recovery after resin treatment. The invention reclaims the byproduct of Na2SO4 and makes effective use of resources such as PMIDA, IDA, formaldehyde, sulphuric acid and water in the production waste water of PMIDA.

The invention discloses a method for making foods by ultrasonic waves. According to the technical scheme, in the food processing process, the temperature is between -5 DEG C and 95 DEG C, and the adopted ultrasonic frequency is 20-200 KHz. The novel method has the beneficial effects of no production of harmful substances during processing, short production period, few production procedures, saving of places and workers as well as water and power and reduction of three-waste emission, and is capable of keeping the nutrition, flavor and safety of foods.

The invention discloses synthesis methods of 3, 6-dichloro-2-methoxybenzoic acid and its intermediate. The invention provides the synthesis method of 2, 3, 6-trichlorobenzoic acid. The synthesis method comprises that in the presence of a catalyst, 2, 3, 6-benzotrichloride and an oxidation reagent undergo an oxidation reaction to produce 2, 3, 6-trichlorobenzoic acid. The synthesis methods have simple processes, a high conversion rate, a high yield, high product purity, a low production cost and environmental friendliness and are suitable for industrial production.