27 results about "Indium chloride" patented technology

The application discloses a graphene quantum dot / indium sulfide electromagnetic wave absorbing material and a preparation method thereof, and comprises the following steps: carrying out a hydrothermal reduction reaction on trinitro-pyrene and an alkaline solution to obtain graphene quantum dot powder rich in hydroxyl functional groups on the surface; and carrying out a hydrothermal reaction on a mixture of indium chloride tetrahydrate and thioacetamide and the graphene quantum dot powder to obtain a graphene quantum dot / indium sulfide heterojunction electromagnetic wave absorbing material with a sulfur vacancy concentration of 3.8% to 5.7%. The addition amount of the sulfur source is controlled by regulating the addition amount of the thioacetamide in the hydrothermal reaction process, the introduced sulfur vacancy concentration is accurately controlled, the In-O covalent bond is formed at the interface between the graphene quantum dot and the indium sulfide, the interface covalent bridging structure is formed, the interface charge transfer efficiency is accelerated, the built-in electric field in the interface is enhanced, stronger interface polarization loss is induced, and the performance of high absorption intensity and wide bandwidth of the composite wave absorbing material is realized.

The application discloses a preparation method of an In2O3-Cu-Cu2O ternary heterojunction catalyst. The method comprises the following steps: dissolving indium chloride tetrahydrate in ethylenediamine-glycol (volume ratio 1:20-1:30) binary glycol amine mixed solvent to obtain a homogeneous solution at room temperature and normal pressure; then, the solution is transferred to a hydrothermal kettle, different volumes of deionized water and Cu2O powder are added, and hydrothermal crystallization is carried out at 160-200 DEG C for 10-14 h; the obtained precipitate is subjected to centrifugal separation, water washing-alcohol washing alternately 2-3 times, vacuum drying at 60 DEG C for 5-7 h, and then calcination is carried out under N2 atmosphere at a temperature increasing rate of 3-5 DEG C / min to 600±10 DEG C for 3 h, and the target product is obtained after furnace cooling. By adjusting the addition amount of deionized water, the mass ratio of In2O3, Cu and Cu2O three phases can be continuously controlled, and the controllable preparation from "rich copper" to "rich cuprous oxide" to "stable ternary" can be realized.

The invention discloses a preparation method of a CuInS2 / FeS2 wood mildew-proof antibacterial agent, which comprises the following steps: dissolving cuprous chloride, indium chloride tetrahydrate, ferric trichloride hexahydrate and thiourea or thioacetamide in ethylene glycol, and carrying out one-step solvothermal reaction and calcination to obtain a CuInS / FeS composite antibacterial agent; the material has triple effects of photo-thermal, photocatalysis and copper ion slow release, and can inhibit mildew and decay fungi on the surface of wood under the condition of visible-near infrared illumination or no illumination. NH4VO3 and 2-methylimidazole are added into a reaction system and calcined in an ammonia-containing atmosphere, so that a V < 5 + > / V < 4 + > redox pair can be formed on the surface, near-infrared absorption is further widened, electron-hole recombination is delayed, and long-acting antibiosis under weak light is realized. The process is simple, does not contain chromium and arsenic heavy metals, and is suitable for environmental protection of wood materials.

The application discloses a preparation method of triethyl indium, and relates to the technical field of metal organic source synthesis, wherein a commonly used indium source is mainly trimethyl indium; the trimethyl indium is in a solid state at normal temperature, and is easy to cause the solid indium source to be easy to be hardened and to have excessive residues; when the solid indium source is used in a machine, the concentration output stability is worse than that of a liquid source; the liquid indium source will become an important indium source in the future; the operation method of the triethyl indium in preparation is more complicated; and the purity of the triethyl indium prepared by purification cannot reach a better ideal state. In the application, n-butyllithium and ethyl iodide are reacted under the protection of inert gas, then the reaction product is reacted with indium chloride to generate triethyl indium; the whole operation is simple, raw materials are easy to obtain, and the product has high purity; under the protection of inert gas, the interference of other solution reagents in the preparation process is reduced; therefore, high-quality triethyl indium raw materials can be purified and processed.

The application discloses a high-fluorescence-quantum-yield Sb 3+ :Cs2NaInCl6 perovskite preparation method belongs to the technical field of inorganic luminescent material preparation. First, cesium chloride, sodium chloride, indium chloride and antimony chloride are mixed and ground, the obtained powder is placed in a vacuum drying box and is treated at 60-300 DEG C for 0.5-2h, a mixture of oleylamine and oleic acid is added, and grinding is continuously performed until the solution becomes uniform, a hydrochloric acid solution with pH=3.2 is added to the product, and after uniform grinding, DOPC is immediately added to the product, and it is observed that the blue fluorescence of the product is strengthened, thereby obtaining high-purity and high-fluorescence-efficiency Sb 3+ :Cs3TbCl6NCs inorganic perovskite. The application realizes Sb doping through mechanical grinding for the first time 3+ :Preparation of Cs2NaInCl6 NCs, and the fluorescence efficiency of the Cs2NaInCl6 NCs is obviously enhanced through post-processing, thereby being Sb 3+ :Application of Cs2NaInCl6 in photoelectricity provides a good prospect.

The embodiment of the present application relates to the technical field of functional materials, and specifically discloses a CuInS2-In2S3 nano-heterojunction catalyst and a preparation method and application thereof, the CuInS2-In2S3 nano-heterojunction catalyst is prepared by using indium chloride, octadecene, oleylamine, sulfur powder and appropriate Cu 1.94 S nanocrystals as raw materials, nucleating In2S3 particles on the Cu 1.94 S nanocrystals through heating reaction, the catalyst has stable structure and stable product performance, exhibits good carbon dioxide reduction catalytic activity, and greatly improves the CO2 reduction product selectivity of CuInS2, thereby solving the problems that the product selectivity of CuInS2 is low in the CO2 reduction, and the small current density limits the catalytic activity and application in the catalytic process in the prior art. Moreover, the preparation method provided by the embodiment of the present application has high controllability, and is simple and efficient compared with the method in the prior art, and has a wide market prospect.

The invention provides a solid electrolyte, a preparation method thereof and a lithium battery. The preparation method of the solid electrolyte comprises the following steps: providing raw materials including lithium chloride, indium chloride, yttrium chloride and lithium fluoride according to a stoichiometric ratio of Li3In1-mYmCl6-nFn, m being 0.05-0.4 and n being 0.15-0.45; grinding the lithium chloride, the indium chloride, the yttrium chloride and the lithium fluoride to prepare a precursor; and carrying out primary sintering at the temperature of 120-200 DEG C, and carrying out secondary sintering at the temperature of 240-280 DEG C. The positive ion-negative ion double-site cooperation strategy aims at breaking through the performance bottleneck of traditional doping, and the solid electrolyte has high ionic conductivity, wide voltage stability, low interface impedance and long cycle life at the same time.

The application belongs to the technical field of nanometer material preparation, and discloses a tubular ZnIn2S4 photocatalyst and a preparation method thereof. Zinc chloride, indium chloride and a hydrazine hydrate solution are mixed, and then thiourea is added to obtain a reaction precursor solution, and a hydrothermal reaction is performed to obtain the tubular ZnIn2S4 photocatalyst. The preparation method has a simple process flow, is convenient to operate, and has relatively mild reaction conditions. The method does not need complex and expensive instrument equipment, and does not need to introduce an additional template agent or a surfactant, reduces the difficulty of subsequent impurity removal, and is beneficial to maintaining the purity and structural stability of the product composition.

This invention discloses a sunflower-shaped tungsten oxide / indium zinc sulfide heterojunction. The tungsten oxide / indium zinc sulfide heterojunction consists of tungsten trioxide located within a central sphere and indium zinc sulfide distributed as nanosheets on the sphere's surface, forming a three-dimensional sunflower shape. Using glucose as a raw material, this invention first prepares uniformly sized carbon spheres via a hydrothermal method. Then, using the synthesized carbon spheres as a template and WCl6 as a precursor, hollow WO3 spheres are obtained through in-situ hydrolysis combined with high-temperature calcination. Finally, using the synthesized hollow WO3 spheres, indium chloride, indium chloride, and thioacetamide as starting materials, the three-dimensional sunflower-shaped tungsten oxide / indium zinc sulfide heterojunction is prepared using a water bath method. The WO3 / ZnIn2S4 heterojunction material of this invention has a larger specific surface area than pure WO3, which is beneficial for exposing more active sites. The three-dimensional heterojunction constructed in this invention can effectively inhibit the free diffusion of CO2 molecules, increase the local CO2 concentration on the catalyst surface, and is more conducive to the adsorption and activation of CO2 molecules.

The invention relates to a preparation method of a novel perovskite C8H32Cl7 (In1-xSbx) N4 yellow luminescent material, which comprises the following steps: sequentially dissolving indium chloride, dimethyl ammonium chloride, antimony chloride, oleylamine, oleic acid and concentrated hydrochloric acid in dimethyl sulfoxide, and fully stirring and mixing; reacting the mixed solution at a constant temperature, and leaving a generated product after the reaction is finished; and repeatedly cleaning the product with toluene, and drying to obtain the yellow luminescent material. The size of the synthesized novel perovskite yellow luminescent material can reach 2 cm, the requirement of growth on growth conditions is low, and theoretically, the material can be successfully grown according to the synthesis conditions provided by the invention.

The invention relates to the technical field of preparation of anhydrous indium chloride, in particular to a preparation method of anhydrous indium chloride, which comprises the following steps: (a) providing an indium source and a chlorine source, the indium source being indium metal or indium compound, and the chlorine source being chlorine, hydrogen chloride or organic chloride; and (b) in an anhydrous inert atmosphere, introducing the indium source and the chlorine source into a reactor, controlling the reaction temperature in a range of 100-400, and carrying out a chlorination reaction for 1-10 hours to generate the indium chloride intermediate. According to the preparation method of anhydrous indium chloride, a product with ultra-high purity and stable chlorine content can be stably obtained by effectively inhibiting a hydrolysis reaction, meanwhile, the hygroscopicity of the product is remarkably reduced, and the product is convenient to store and transport. The technological process is mild and controllable, the safety is high, toxic corrosive gas is prevented from being used, and the method has the remarkable advantages of being easy and convenient to operate and environmentally friendly.

The invention relates to the technical field of solar energy resource utilization, and discloses surface-modified indium oxide and a preparation method and application thereof.The surface modification method of indium oxide comprises the steps that indium chloride and an ammonium hydroxide ethanol solution are mixed, and turbid liquid is obtained; centrifuging the turbid liquid, taking the centrifuged solid, and drying; grinding and calcining the dried solid to obtain powder; and placing the powder in PECVD equipment, introducing gas, keeping a low-pressure atmosphere in a tubular furnace in the PECVD equipment, setting the power of a radio frequency circuit of the PECVD equipment, and carrying out heat preservation to obtain the surface modified indium oxide. By means of the method, multiple effective utilization of solar energy resources and in-situ utilization of extraterrestrial resources are achieved. The prepared surface modified indium oxide can be applied to photo-thermal catalytic carbon dioxide reduction reaction.

The invention discloses a metal sulfide-based S-type heterojunction photocatalyst and a preparation method thereof, and the method comprises the following steps: respectively dissolving sodium tungstate and zinc acetate with the same substance amount in deionized water, and stirring to form a first turbid liquid; carrying out first-step hydrothermal reaction, and treating to obtain zinc tungstate nanorod powder; the method comprises the following steps: weighing indium chloride, zinc acetate and thioacetamide according to the element stoichiometric ratio of sulfur indium zinc, dissolving the indium chloride, the zinc acetate and the thioacetamide in deionized water, and stirring to form a solution; and adding zinc tungstate nanorod powder into the solution, stirring to form a second turbid liquid, carrying out a second-step hydrothermal reaction, and treating to obtain the S-type heterojunction photocatalyst. The heterojunction catalyst with an S-type energy band staggered structure is formed, compounding of carriers in a single-component catalyst is inhibited, photo-generated carriers with high oxidation-reduction capacity are kept to participate in a catalytic reaction, the forbidden band width is effectively reduced, light absorption of a system is enhanced, and therefore the heterojunction catalyst is higher in catalytic activity and higher in catalytic efficiency. The photocatalytic hydrogen production efficiency is improved.

The application relates to a bismuth ferrite-indium zinc sulfide-silver composite catalyst driven by ultrasonic and visible light, and a preparation method and application thereof, wherein the preparation method comprises the following steps: S1. hollow bismuth ferrite core preparation: taking bismuth nitrate and iron nitrate as raw materials, adding a solvent, heating to obtain a precursor powder, calcining the precursor powder to obtain a crude product, and washing and drying the crude product to obtain the hollow bismuth ferrite core; S2. shell-core type bismuth ferrite-indium zinc sulfide heterojunction preparation: taking zinc chloride, indium chloride and thioacetamide as raw materials, adding a solvent, adding the hollow bismuth ferrite after mixing, dispersing, heating and reacting to obtain the shell-core type bismuth ferrite-indium zinc sulfide heterojunction; and S3. composite catalyst preparation: dispersing the heterojunction powder into a solvent, adding silver nitrate, mixing in the dark, heating and reacting, collecting the precipitate, washing and drying the precipitate, heating and stirring the precipitate in acetone, filtering, and drying to obtain the composite catalyst. The composite catalyst can form an inner core piezoelectric field, a heterojunction interface and an outer layer Mott-Schottky potential barrier, realizes ultrasonic and visible light dual-energy driving, activates persulfate and degrades organic pollutants.

The invention relates to a synthesis method of oseltamivir phosphate, which comprises the following steps: by taking (1R, 5R, 6R)-trans-5-(1-ethyl propoxy)-7-oxobicyclo [4.1. 0] hept-3-ene-3-carboxylic acid ethyl ester as a starting raw material, reacting with acetonitrile under the catalysis of indium chloride to synthesize (3aR, 4R, 7aR)-2-methyl-4-(pent-3-alcohol oxy)-3a, 4, 7, 7a-tetrahydrocyclohexene [2, 1-d] [1, 3] oxazole-6-ethyl formate; the preparation method comprises the following steps: synthesizing (3R, 4R, 5S)-4-(acetamido)-5-[(diphenylmethylene) amino]-3-(pent-3-oxyl) cyclohexene-1-ethyl formate by using ethyl acetate as a raw material, performing ring-opening reaction with benzophenonimine under the catalysis of cuprous iodide and cesium carbonate to synthesize (3R, 4R, 5S)-4-(acetamido)-5-[(diphenylmethylene) amino]-3-(pent-3-oxyl) cyclohexene-1-ethyl formate, hydrolyzing benzophenone to synthesize oseltamivir, and reacting with phosphoric acid to synthesize oseltamivir phosphate. The method has the advantages of short synthetic route, low cost, easily available initial raw materials, simple operation, few and controllable reaction impurities, and suitableness for industrial production.

The invention provides a solid electrolyte, a preparation method thereof and a lithium battery. The preparation method of the solid electrolyte comprises the following steps: providing raw materials including lithium chloride, indium trichloride and lithium fluoride according to the stoichiometric ratio of Li3InCl6-xFx, x being 0.1-0.5; grinding the lithium chloride, the indium trichloride and the lithium fluoride to prepare an amorphous precursor; carrying out first sintering at the temperature of 250-280 DEG C to prepare an intermediate phase; and sintering for the second time at the temperature of 280-350 DEG C. The specific crystal lattice site of Cl <-> in the Li3InCl6 crystal is selectively occupied by doping F <->, the sectional area of a lithium ion migration channel is enlarged after partial substitution, migration activation energy is reduced, and the ionic conductivity is improved. In addition, the incompletely reacted LiF is uniformly distributed on the grain boundary in a nano-particle form, an additional lithium ion transmission path is provided, water molecule permeation is effectively blocked, and the humidity stability is improved.

The application relates to the technical field of nanomaterial preparation, in particular to a method for synthesizing a zinc-sulfur double-vacancy Zn3In2S6 photocatalyst, wherein specific-volume ammonia water is mixed with deionized water to form a solvent, zinc sulfate, indium trichloride and thioacetamide precursors are added, and after uniform stirring, one-step hydrothermal reaction is carried out at 160 DEG C for 12 hours, and the product is obtained through centrifugal washing and vacuum drying. Through the coordination induction effect of ammonia water, zinc vacancies and sulfur vacancies are in-situ constructed in the Zn3In2S6 crystal lattice, the introduced defect energy level is used as an electron trap to capture photo-generated electrons, carrier recombination is inhibited, and the surface active site is increased. The application can significantly improve the hydrogen production activity under visible light, the hydrogen evolution rate is 2.25 times that of the hydrogen production activity without adding ammonia water, and the application has the advantages of simple process route, excellent catalytic performance and strong structural stability.

The application discloses a method for preparing antimony-doped cesium indium chloride lead-free perovskite nanocrystals through an improved hot injection method. First, cesium carbonate is dissolved by oleic acid to obtain a cesium oleate precursor solution. Then, in another three-necked flask, indium acetate and antimony acetate are dissolved by using 1-octadecene, oleic acid, oleylamine and tri-n-octylphosphine, and the prepared cesium oleate precursor solution is added. After vacuumizing and heating to a certain temperature, a clear solution is obtained. Then, ice-bath cooling is performed, nitrogen is introduced after the temperature is lowered to a certain temperature, isopropyl alcohol and deionized water are injected, and the temperature is raised to a specific temperature. Then, phenyl phosphinic dichloride is rapidly injected. After washing and centrifugation, the target product can be obtained. According to the application, high-quantum-yield antimony-doped cesium indium chloride lead-free perovskite nanocrystals can be prepared at a lower injection temperature and in a shorter time.

The invention is mainly applied to the field related to a photocatalysis technology, and provides an S-type heterojunction NiCo2O4-coated ZnIn2S4 catalyst with photocatalysis performance and a preparation method and application thereof. Through a nano casting strategy, polyacrylic acid (PAA), ammonia water and deionized water are uniformly mixed, isopropanol is dropwise added at a constant speed, a mixed aqueous solution of cobalt chloride and nickel chloride in a stoichiometric ratio is added in batches, and under continuous stirring, the pH value of a system is adjusted to a proper range through the ammonia water, so that cobalt ions and nickel ions are distributed and precipitated on the surface of a PAA template. And centrifuging, washing and drying, and copying the three-dimensional structure of the PAA sphere template to obtain the hollow NiCo2O4 nanosphere. And uniformly dispersing the obtained hollow NiCo2O4 nanospheres in water, adjusting the pH value, sequentially adding zinc chloride, indium chloride and thioacetamide, enabling ZnIn2S4 nanosheets to grow on the surfaces of the hollow NiCo2O4 nanospheres in situ, centrifuging, washing, and drying in vacuum to obtain the S-type heterojunction NiCo2O4-coated ZnIn2S4 catalyst with photocatalytic performance. The S-type heterojunction NiCo2O4-ZnIn2S4 catalyst provided by the invention has the characteristics of stable structure, high light utilization rate and strong dispersity, has good performance of photocatalytic reduction of CO2, and has wide application prospects in the fields of photocatalytic degradation of antibiotics and the like.

The invention discloses a visible light ultrasonic synergistic response barium titanate-indium zinc sulfide catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, synthesizing a barium titanate nanowire; s2, synthesis of barium titanate-indium zinc sulfide nanowires: uniformly mixing deionized water, glycerol and ethylene glycol in proportion, adjusting the pH value, adding the newly prepared barium titanate nanowires, zinc oxide and indium trichloride tetrahydrate in proportion, performing ultrasonic dispersion uniformly, then adding thioacetamide, quickly heating to 70-100 DEG C under a stirring condition, then continuously heating and reacting for 2-4 hours, and cooling to room temperature to obtain the barium titanate-indium zinc sulfide nanowires. And after the reaction is finished, filtering, washing and drying to obtain the product. According to the composite catalyst, the barium titanate nanowire with piezoelectric response serves as an inner core, an S-shaped heterojunction constructed by the ultrathin indium zinc sulfide nanosheets is loaded on the surface, the light absorption range is widened, the light absorption efficiency is improved, separation of carriers can be effectively promoted, and ultrasonic / visible light dual-energy driven efficient synthesis is achieved.

The invention relates to a preparation method and application of a ferroferric selenide-diindium triselenide heterostructure carbon-based composite nanofiber material. The preparation method comprises the following steps: firstly, mixing N, N-dimethylformamide and polystyrene nitrile, then adding a polyethylene oxide-polypropylene oxide-polyethylene oxide triblock copolymer, stirring to obtain a uniform and transparent solution, then adding ferric acetylacetonate and indium chloride, continuously stirring to obtain an electrostatic spinning precursor solution, transferring the electrostatic spinning precursor solution into an electrostatic spinning medical injector, and carrying out electrostatic spinning to obtain the nano-silver-doped graphene composite material. Spinning on an electrostatic spinning device, and receiving nanofibers obtained by spinning with tin foil. And then carrying out vacuum drying and pre-oxidation on the tin foil substrate loaded with the nanofibers, and then collecting the nanofibers by using a corundum ark for selenylation treatment to obtain the ferroferric selenide-diindium triselenide heterostructure carbon-based composite nanofiber material. The core of the invention is to construct a heterostructure with a synergistic effect. The structure can effectively buffer the volume change in the charge-discharge process and accelerate ion / electron transport kinetics.

The invention discloses an aqueous zinc ion battery electrolyte additive, an electrolyte, a preparation method of the electrolyte and a battery, and belongs to the technical field of zinc ion batteries. The additive is any one of tin tetrachloride, tin tetraiodide, indium chloride or indium iodide, and the concentration of the additive in the electrolyte is 1-20 mmol / L. The electrolyte comprises an aqueous zinc ion battery electrolyte additive, an electrolyte solvent and an electrolyte, the electrolyte solvent is an aqueous solution of isopropanol with the volume fraction of 50%; the electrolyte is one or more of zinc sulfate, zinc chloride, zinc perchlorate, zinc acetate or zinc trifluoromethanesulfonate, and the concentration of the electrolyte in the electrolyte solution is 0.5-5 mol / L. According to the zinc ion battery electrolyte additive disclosed by the invention, a metal layer can be formed on the surface of a zinc negative electrode by adding the zinc-philic compound tin tetrachloride and the like, further growth of dendritic crystals can be effectively inhibited, the flatness of the surface of the electrode is maintained, and a battery containing the electrolyte additive has good cycle stability.

The application belongs to the technical field of photocathodic protection, and particularly relates to a preparation method of In2S3 / ZnIn2S4-S material for metal material photocathodic protection. The application prepares an In2S3 photoanode through hydrothermal reaction of indium chloride tetrahydrate and thiourea; then, the photoanode is used as a substrate to synthesize an In2S3 / ZnIn2S4 heterojunction through secondary hydrothermal reaction of indium chloride tetrahydrate, thiourea and zinc chloride; finally, sulfur vacancies are introduced into the heterojunction through annealing to obtain an In2S3 / ZnIn2S4-S heterojunction photoanode. The application can effectively promote separation and migration of photo-generated electron-hole pairs, significantly improve photoelectric current response and corrosion resistance of the material, greatly improve performance and stability of sulfide photoelectrochemical cathodic protection, and provide a feasible way for development of high-efficiency and stable new metal corrosion prevention materials.

The invention belongs to the technical field of catalyst preparation, and particularly relates to a CdS / ZnIn2S4 nanoflower rod catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: adding a structure-directing agent ammonium into an ethylenediamine solution of cadmium acetate and thiourea, and carrying out solvothermal reaction to obtain a CdS nanorod; the CdS nanorod, polyvinylpyrrolidone, zinc chloride, indium chloride and thioacetamide are mixed for a low-temperature solvothermal in-situ synthesis reaction, the CdS / ZnIn2S4 nanoflower rod catalyst is obtained, and the dielectric constant of a solvent of the low-temperature solvothermal in-situ synthesis reaction is 30-70. The catalyst provided by the invention is high in stability and good in catalytic performance, and has a good application prospect in the fields of catalytic reduction of CO2 and degradation of antibiotics.

The invention discloses a preparation method and application of a C-S bond bridged C3N5 / ZnIn2S4 composite photocatalyst, and belongs to the technical field of photocatalysts. The preparation method comprises the following steps: adding zinc chloride, indium chloride and thioacetamide into deionized water, uniformly stirring, adding C3N5, and carrying out ultrasonic treatment, oil bath heating, centrifugation, washing and drying to obtain the C3N5 loaded ZnIn2S4 composite photocatalyst. According to the invention, C3N5 is compounded with ZnIn2S4, so that the absorption capacity of the material to visible light can be synergistically enhanced, meanwhile, efficient separation and migration of photon-generated carriers are promoted by virtue of a composite structure, and the carrier recombination rate is remarkably reduced, so that the performance of photocatalytic preparation of hydrogen peroxide by the material is improved.

This invention discloses a method for preparing a photocatalyst for the C-C coupling conversion of methanol to ethylene glycol and its application. Zinc acetate dihydrate, indium chloride tetrahydrate, and thioacetamide, as well as zinc acetate dihydrate, cadmium acetate dihydrate, and thioacetamide, are used in a hydrothermal process to generate ZnIn2S4 nanosheets and Zn... 0.5 Cd 0.5 S nanorods were then electrostatically assembled to form a heterojunction structure. An aqueous nickel chloride solution was added during the reaction to form a nickel-modified ZnIn2S4 / Zn nanorod. 0.5 Cd 0.5 S-heterojunction solid catalyst. This invention prepares a highly active photocatalytic catalyst for the conversion of methanol to ethylene glycol through electrostatic assembly and photoreduction.

This invention relates to the field of semiconductor nanomaterials technology, specifically disclosing a semiconductor moiré superlattice material and its preparation method. This invention successfully prepared a ZnIn2S4 moiré superlattice structure for the first time using a solvothermal method and elucidated its formation mechanism. Specifically, using zinc acetate and indium chloride as precursors and thioacetamide as a solvent, the ZnIn2S4 moiré superlattice structure was synthesized in one step by controlling the reaction conditions. The prepared moiré superlattice has a rotation angle of approximately 12° and integer multiples thereof, and the preparation method exhibits good controllability and reproducibility. This invention is expected to further improve the photoelectric properties of ZnIn2S4 and develop its application potential in photocatalysis, photoelectric detection, hydroelectric power generation, and photovoltaic power generation.