117results about How to "Not easy to sinter" patented technology

The invention discloses a high-strength lamellar Al-based metal ceramic composite material and a preparation method thereof, aiming at solving the problems of high preparation cost, complex operation, single type of reinforcement ceramic and low strength. The high-strength lamellar Al-based metal ceramic composite material, i.e., high-strength lamellar structure Al-Si-Mg/(Al2O3, SiC, TiC) composite material comprises ceramic powder and Al-Si-Mg alloy. The volume fraction of ceramic powder is 20%-40vol%; the volume fraction of Al-Si-Mg alloy is 80%-60vol%; the mass ratio of aluminum in the Al-Si-Mg alloy is 75-84wt%; the mass ratio of silicon is 10-15wt%; the mass ratio of magnesium is 6-10wt%. The preparation method of the high-strength lamellar Al-based metal ceramic composite material comprises the following steps: preparation of water-based ceramic slurry; directional solidification; freezing and drying; sintering of blanks; smelting of alloy; and non-pressure infiltration.

The invention discloses a manganese-cerium complex oxide catalyst loaded by TiO2, which takes nanometer titanium dioxide as a carrier and the manganese-cerium complex oxide loaded on the carrier as an active ingredient. The mole ratio of each ingredient is that Ti: Mn: Ce is equal to 1: (0.05 to 1): (0.05 to 1). The invention also discloses a preparation method of the catalyst, which adopts sol-gel preparation technology to promote the dispersity and strength of the two ingredients of manganese and cerium on a TiO2 carrier. Furthermore, the catalyst prepared by adopting the preparation method has the advantages of high catalytic activity and uniform particles; active substances is good in dispersity and is hard to sinter; when used in low-temperature SCR reaction, the catalyst can greatly lower the operation temperature and the operation cost of the SCR since the catalyst has a very high removal rate of NO at the temperature about 120 DEG C.

A catalyst used for industrial production of 1, 6-hexanediol and a preparation method for the catalyst and relate to a catalyst used for hydrogenated production of 1, 6-hexanediol with 1, 6 dimethylene adipate, and a preparation method for the catalyst. The catalyst basically comprises copper oxide, zinc oxide and aluminum oxide. The copper oxide takes up 25 to 60 percent of the total catalyst weight, the zinc oxide takes up 25 to 60 percent of the total catalyst weight, and the aluminum oxide takes up 10 to 30 percent. The preparation method comprises preparation of a copper nitrate and zinc nitrate mixed solution, preparation of a aluminum hydroxide suspension, deposition, filtering, washing, drying, granule making, calcination, mixing with an extender, tablet pressing and molding. Thus, the catalyst used for industrial production of 1, 6-hexanediol is produced, and make the conversion rate of the raw material of 1, 6 dimethylene adipate larger than 99 percent and the hexanediol selectivity larger than 96 percent.

The invention provides a molecular sieve coating load manganese based composite oxide integrated catalyst with easy material acquisition, low preparation cost and firm combination of active constituents and carrier of catalyst, and a preparation method thereof for the defects that the noble metal catalyst has few noble metal resources, high price and high preparation cost. The catalyst provided by the invention is a cellular catalytic combustion catalyst, which comprises a molecular sieve coating, a manganese based composite oxide and a cellular carrier. The catalyst provided by the invention is prepared by the following steps of: uniformly mixing a precursor with the manganese based composite oxide, the molecular sieve and the water to obtain a grout with manganese based composite oxide precursor; soaking the cellular carrier into the grout with manganese based composite oxide precursor; and drying and baking to obtain the molecular sieve coating load manganese based composite oxide integrated catalyst.

The present invention provides a montmorillonite/ZSM-5 molecular sieve composite material and its preparing method. The montmorillonite/beta molecular sieve composite material is prepared by evenly mixing montmorillonite with ZSM-5 molecular sieve gelatin, then processing home position crystallization, and via filtering, washing and drying. The composite material have structure characteristics of the montmorillonite and the molecular sieve at the same time, the montmorillonite and the molecular sieve are alternative. The synthetic montmorillonite/ZSM-5 molecular sieve have characteristics of small crystal grain molecular sieve by controlling the synthetic course and the conditions. The preparing method is simple, the easily separating, the molecular sieve composite material has better water-heat stability. The composite material are mainly used for all kinds of catalysts and absorption agents, especially the preparing of hydrogenation catalyst.

The invention discloses a novel solid catalyst material for methane carbon dioxide reforming reaction, a corresponding widely-applicable preparation method and a simply and easily operated testing andreacting process. According to the perovskite catalyst, a substrate is a perovskite material which includes in-situ precipitated B-site doped metal nano-particles and an A site short of positive ions. The in-situ precipitated B-site high-activity metal nano-particles for catalyzing cover the surface of the substrate, the A site is any one of a rare earth element and an alkali-earth metal element,and a B-site substrate is doped transition metal with various valence states. The perovskite catalyst can provide good catalytic performances, and carbon deposit and catalyst deactivation caused by carbon deposit in reforming reaction are avoided. The in-situ precipitated-in-situ reaction preparation and testing method has the advantages of simplicity in operation, practicability, high efficiencyand novelty. The method has a good application prospect in a preparation and testing process of the catalyst.

The invention relates to a catalyst used for removing flue gas NOx at low temperature. The weight percentage of each component is: 90.0 to 99.0 percent of active carbon fiber and 0.1 to 10.0 percent of V2O5. The active carbon fiber is dipped into a mixed solution prepared by oxalic acid and ammonium metavanadate which contains V2O5 and has a concentration of 0.000088735 to 0.0088735g/ml, then is stood for 2 to 5h under the room temperature, dried for 2 to 12h under a temperature of 40 to 60 DEG C, dried for 2 to 6h under a temperature of 100 to 120 DEG C, then is calcined for 2 to 8h in an argon atmosphere at 400 to 500 DEG C and is calcined for 2 to 5h in air of 200 to 260 DEG C to obtain the catalyst. The invention is simple to be operated, has excellent poisoning capacities of H2O resistance and SO2 resistance and improves the activity of selectively catalyzing and reducing the NOx.

The invention provides a preparation method for tetragonal phase nano barium titanate. The preparation method comprises the steps as follows: i), preparing water solutions of barium chloride and oxalic acid respectively, and mixing alcoholic solution of butyl titanate and oxalic acid solution uniformly to obtain titanium oxyoxalate complex ion solution; ii), adding titanium oxyoxalate complex ion solution obtained in the step i) into a supergravity reactor as a circulating flowing phase to control the supergravity level; and meanwhile, dropping barium chloride solution to obtain white barium titanyl oxalate precipitation suspension as a precursor of barium titanate, and keeping the pH value of the whole system at 2.5-3.5 during reaction; and iii),ageing the precipitation suspension obtained in the step ii), leaching, washing and drying to obtain white barium titanyl oxalate power. The preparation method provided by the invention has the advantages that tetragonal phase nano barium titanate can be prepared; and the particle size of the prepared power can be controlled to be within the range of 30-90 nm; the average particle size is small, and the particle size is narrow in distribution; and the degree of crystallinity is high, and the crystal formation is intact.

The invention discloses a preparation method of high-activity crystal seed by hydrolysis of a titanium sulfate solution and belongs to the technical field of production of titanium dioxide by a sulfuric acid method. The preparation method comprises the following steps of (A) taking and putting a hydrolytic titanium sulfate solution into a preheating groove to be preheated to 50-65 DEG C, wherein the concentration of TiO2 in the hydrolytic titanium sulfate solution is 195-205g/L, the concentration of Ti<3+> is 1.0-3.0g/L (calculated by TiO2), the concentration ratio F between effective acid andtotal TiO2 is 1.70-1.85, the concentration ratio between Fe and TiO2 is 0.26-0.31, the solid content is less than 30mg/L, and the stability is greater than or equal to 500; (B) preheating alkaline liquid to 50-65 DEG C, and controlling the concentration of the preheated alkaline liquid to 8.0-8.5%; (C) within 1-4 minutes, adding the hydrolytic titanium sulfate solution into the alkaline liquid, and after the reaction is finished, controlling the temperature of the crystal seed titanium sulfate solution to be 40-60 DEG C; (D) diluting and controlling the concentration of TiO2 in the crystal seed titanium sulfate solution to be 30-160g/L. The crystal seed prepared by the method is high in activity, less in added amount in water crystallization and high in hydrolysis rate, and the obtained hydrated titanium dioxide is uniform in particle size distribution.

The present invention provides a fire-resistant castable material of furnace lining for aluminum hydroxide gas suspension baking furnace. The fire-resistant castable material is a mixture of sintered coke sapphire chamotte and fine-grained mullite of good crystal structure in the sintering process, binder and composite additive according to different proportions; the lining of a main furnace body for aluminum hydroxide gas suspension baking furnace is prepared after furnace building, furnace baking and sintering. Wherein, the percentage of composition of raw materials is: 27 to 33 percent of coke sapphire chamotte less than 3mm, 25 to 30 percent of coke sapphire chamotte with a particle size between 3mm and 5mm, 8 to 15 percent of coke sapphire chamotte with a particle size between 5mm and 8mm, and 15 to 25 percent of fine-grained mullite powder with a particle size less than 0.074mm. The binder uses activated alumina of rho- Al₂O₃ of 5 to 8 percent; the composite additive uses high-dispersion oxidated alpha-Al₂O₃, superfine powder and silicon oxide SiO₂; the contents of the superfine powder and the silicon oxide are respectively 2 to 5 percent; the particle size of the superfine powder is less than 5 Mu m; the content of sodium tripolyphosphate is 0.1 to 0.3 percent.

The invention relates to a preparation method of TiO2/Gamma-Al2O3 composite carrier. The weight percent of TiO2 in the chemical composition of the composite carrier is 15 percent, and the composite carrier has the precursors of titanium tetrachloride (TiCl4) and aluminum nitrate (Al(NO3)3 9H2O) as raw materials, and adopts concurrent co-precipitation method to prepare. The precipitation gets a TiO2/Gamma-Al2O3 composite carrier with a 292.6m<2>/g specific surface area after drying for 24h under a temperature of 110 DEG C in oven and roasting for 2h under the temperature of 500 DEG C in muffle furnace. The preparation method of TiO2/Gamma-Al2O3 composite carrier has the advantages of simple technology, convenient operation, and even components. Meanwhile, the composite carrier has the specific surface area which is bigger 50 to 100m<2>/g than ordinary titanium-aluminum bi-oxide, can play the role of the carrier of catalysts, and also is suitable to be used as the carrier of plasma-catalytic coordination de-NO catalyst.

The invention discloses a preparation method and application of superfine calcium hexaboride to a battery. The preparation method comprises the steps of: carrying out electrolysis in a fused-salt electrolytic cell at a temperature of 500-750 DEG C through taking a composition of porous calcium borate and a metal current collector as the cathode and taking an insoluble conductor material as the anode, wherein fused-salt electrolyte contains a haloid corresponding to a metal capable of chemically reducing the calcium borate, and the voltage applied through the electrolysis is enough to reduce the calcium borate but not enough to resolve the fused-salt electrolyte; and taking out a reduction product on the cathode from the electrolytic cell, washing by using water and acid removing impurities, drying and then obtaining CaB6 powder. The obtained superfine calcium hexaboride can be used for a cathode material of a high-specific energy alkaline cell. By means of the method, the defects of high synthesis temperature, low yield and more expensive raw material of conventional boride are overcome and continuous production can be carried out.

The invention relates to a preparation method and application of a mixed oxide-doped nano copper-cobalt alloy catalyst. According to the catalyst, CuCo serves as an active component and mixed oxide serves as a carrier, wherein Cu accounts for 5-25% in the catalyst in percentage by mass, Co accounts for 5-25% in the catalyst in percentage by mass, Al2O3 accounts for 13-25% in the catalyst in percentage by mass, and one of SiO2, ZrO2, CeO2 or TiO2 accounts for the balance. The mixed oxide-doped nano copper-cobalt alloy catalyst is obtained by calcinating and reducing a hydroxide-doped hydrotalcite-like precursor. Since silicon, zirconium, cerium and titanium ions cannot enter a hydrotalcite-like laminate, the dispersion of copper and cobalt on the surface is improved, the dispersion degree of active components is increased, and the formation of a hotspot in a reaction process of synthesizing low-carbon alcohol is relieved. The catalyst is relatively high in low-carbon alcohol selectivity and low-temperature activity, easy to operate, and low in cost and is applicable to industrial production.

The invention provides a catalytic purification composite material and a preparation method and application thereof. Activated carbon loaded manganese sand particles are used as a basic framework of the material, and mixed metal oxides as active components are loaded on the outermost layer of the framework. The preparation method of the material comprises the following steps: pretreating manganese sand and removing impurities on the surface of the manganese sand; taking wooden activated carbon or shell activated carbon as an activated carbon precursor; roasting in an inert atmosphere; preparing a porous carbon structure which uses the manganese sand as a framework; and modifying the surface of the manganese sand-porous carbon structure by using the metal oxides to form the novel composite purification material with adsorption and electro-catalyst composite functions. When the catalytic purification composite material is used, the composite material effectively adsorbs and catches low-concentration organic matters in micro-polluted raw water at first, so that pollutants are adsorbed on the surface of the material, then the composite material with adsorption saturation is guided into an electrolytic bath for electrochemical oxidation, the pollutants on the surface of the composite material are desorbed and decomposed, and are thoroughly mineralized into carbon dioxide and water, and meanwhile, recycling of the composite material is realized.

The invention discloses a graphene-modified nickel-base composite anode material of a solid oxide fuel cell and a preparation method thereof. The modified nickel-base composite anode material is prepared by compounding metal salt, an oxide or hydroxide of metal, YSZ ((Yttria Stabilized Zirconia) and graphene oxide, and then a battery assembly is prepared by compounding the nickel-base composite anode material and an electrolyte material. Through testing the performance of the battery assembly, the performance of the battery assembly is greatly improved in comparison with a battery with an un-modified anode. The graphene oxide is added in a conventional nickel-base anode material for modifying the anode material, the reduced graphene is capable of stopping nickel particles from sintering and growing, and the surface appearance of the material is improved. The graphene-modified nickel-base composite anode material has the characteristics of uniformity in particle distribution, difficulty in sintering, high strength, small volume expansion ratio, stable structure and the like; and the cyclic oxidation-reduction resisting capability of the nickel-base anode material is improved. The application of the anode material has important significance to the promotion of the application of a nickel-base anode solid oxide fuel cell technology.

The invention relates to an acrylic acid catalyst regeneration method. An acrylic acid catalyst has a concentrated pore distribution and a moderate total pore volume, the amount of medium-sized pores of about 5-10nm accounts for above 70% of the amount of total pores, and the medium-sized pores of about 5-10nm form short and thick tunnel structures, so the catalyst has the characteristics of strong carbon deposit resistance, difficult agglomeration and long service life. The two-step calcining regeneration method for regenerating an inactivated acrylic acid catalyst comprises the following steps: heating the inactivated acrylic acid catalyst to 280-320DEG C at a speed of 1-2DEG C/h, and carrying out constant temperature calcining for 1-10h; and heating to 330-370DEG C at a speed of 1-2DEG C/h, calcining in an oxidizing gas for 1-3d, heating to 380-410DEG C, and calcining in nitrogen atmosphere for 1-3d to obtain a regenerated acrylic acid catalyst having an equivalent activity with the fresh catalyst.

The invention discloses a preparation method of a catalyst for carbon dioxide hydrogenation methyl alcohol production. The catalyst prepared through the method can sufficiently utilize the high specific surface area and the unique duct structure of mesoporous silicon dioxide, ultrahigh dispersion of active components is achieved, and generation of high-activity loci is promoted. The method comprises the following steps that 1, a polymer is weighed to be added into deionized water, stirring is performed to achieve complete dissolution; 2, concentrated hydrochloric acid, Cu(NO3)2 and Zn(NO3)2 solid powder are added, and heating and stirring are performed; 3, a silicon source is dropped in, and a precursor system solution is obtained; 4, sealing is performed for continuous stirring for 24-28h or longer, and the reaction solution is poured into a self-pressure reaction kettle for crystallization; 5, the crystallized solution is subjected to washing and suction filtering, and obtained filter cakes are dried; 6, the dried product is calcinated; 7, the calcinated product is placed into a tube furnace to be reduced in hydrogen airflow, and the catalyst for carbon dioxide hydrogenation methyl alcohol production is obtained.

The invention belongs to the temperature control technical field, which solves the problem that the on-off between contacts is gradual in the prior art, and caused to burn during connection and separation. A temperature adjusting switch is provided, wherein a shell 1 is provided with an elastic sheet 4 and a heat sensitive bimetal strip 5 is arranged on the springy end of the elastic sheet 4. An electric heater 6 is arranged on the heat sensitive bimetal strip 5, wherein the first end and the second end of the electric heater 6 are respectively connected between a first switch control end 2 and the heat sensitive bimetal strip 5 in serial manner. The tilting end of the heat sensitive bimetal strip 5 is hinged with one end of a tilting metal strip 8 to form a hinge point 11, while a swing contact 12 on the other end of the tilting metal strip 8 is arranged in the position of a contact point 10 of a second switch control end 3. The middle part of the tilting metal strip 8 is provided with a spring 9 which is fixed on the shell 1. The line formed at two ends of the spring 9 is in the range which the heat sensitive bimetal strip 5 is heated to deform and allow the hinge point 11 to swing. The shell 1 is provided with an adjusting cam 13 which can go against the elastic sheet 4.

The invention provides a powder X-ray diffraction method for determining the magnesium aluminate spinel phase content in a catalyst. The method comprises the steps of grinding and sieving a to-be-detected biofuel hydrogenation catalyst sample to prepare a mixed sample of the to-be-detected biofuel hydrogenation catalyst sample and a corundum phase sample; simultaneously preparing a mixed standard sample of a magnesium aluminate spinel phase standard sample and a corundum phase standard sample; starting a powder X-ray diffractometer, verifying that the comprehensive stability of the diffractometer is smaller than or equal to 0.1% by using silicon powder after the diffractometer is stable to meet the determination requirements; and collecting copper target Kalpha X-ray diffraction data of the mixed standard sample and the mixed sample within a 2theta angle range of 34-40 degrees under the same working conditions of the X-ray diffractometer separately, processing programs of system software by using powder X-ray diffraction data to obtain peak intensity of a magnesium aluminate spinel phase (311) crystal surface and a corundum phase (104) crystal surface in each sample and determining the mean value, and calculating the magnesium aluminate spinel phase content in the to-be-detected biofuel hydrogenation catalyst sample by using a K-value method.

The invention provides a tundish composite working lining. The inner layer of the tundish composite working lining is a dry material layer, the outer layer of the composite working lining is a coated layer, and the dry material layer and the coated layer are closely connected and compounded into an integrated structure. The dry material layer and the coated layer are combined into the composite working lining, the advantages of the dry material layer and the coated layer are combined, and the composite working lining has the advantages of convenient construction, difficult sintering, easy tundish tilting and recarburization reduction, etc.