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138results about How to "Rich surface functional groups" patented technology

Doped carbon dot and graphene compound as well as preparation method and application thereof

The invention belongs to the technical field of nanomaterials and particularly relates to a doped carbon dot and graphene compound as well as a preparation method and an application thereof. The preparation method comprises the steps as follows: lipoic acid, ethylenediamine, phytic acid and the like are used as mixed element precursors to be dissolved in deionized water and uniformly mixed, and doped carbon dots are obtained through a hydrothermal reaction in a reaction kettle; the carbon dots are added to a graphene oxide aqueous solution to be subjected to a hydrothermal reaction, then washing and drying are performed, and the doped carbon dot and graphene compound is obtained. The electro-catalysis effect best for oxygen reduction can be obtained by adjusting the type of mixed elements in the carbon dots and the proportion of the carbon dots to graphene. The preparation method is simple and easy to implement and low in cost; the chemical and physical properties of the obtained material are stable, a representative nitrogen and sulfur double-doped carbon dot-graphene composite can realize the four-electron transfer process for oxygen reduction, the reduction overpotential is obviously smaller than that of single-doped samples and other doped samples, and the material can be applied to electro-catalysis of oxygen reduction reactions on cathodes of fuel cells.
Owner:FUDAN UNIV

Preparation method and application of multi-site activated and modified reed-lutarioriparius biochar

The invention relates to the field of treatment to heavy metal pollution in water and soil, in particular to a preparation method of multi-site activated and modified reed-lutarioriparius biochar andapplication thereof to removal of heavy metals zinc and cadmium. The preparation method comprises the following steps: firstly washing, drying and crushing reed-lutarioriparius biomass, ultrasonicallystirring in an aqueous manganese ore powder solution thoroughly, then performing low-temperature hydrothermal carbonization to produce unactivated and unmodified biochar, then soaking the biochar ina calcium chloride-hydrogen peroxide mixed solution, activating a biochar-calcium chloride-hydrogen peroxide mixed solution by using microwave, and then modifying the dried biochar through ultravioletradiation to obtain activated and modified biochar, wherein the obtained biochar is applied to the removal of the heavy metals zinc and cadmium in the water and the soil. An application method comprises the following steps: adding the activated and modified biochar into heavy metal zinc and cadmium wastewater for an adsorption reaction; or directly adding into heavy metal zinc and cadmium contaminated soil, thoroughly mixing uniformly, and aging for a period of time to complete bioremediation of heavy metal zinc and cadmium pollution in the soil.
Owner:JIANGXI ACADEMY OF SCI

Programmed multi-target tree-shaped macromolecular assembled body medicine conveying system as well as preparation method and application thereof

The invention discloses a programmed multi-target tree-shaped macromolecular assembled body medicine conveying system as well as a preparation method and application thereof and belongs to the field of biomedical materials. The medicine conveying system taking an amphipathic tree-shaped macromolecular assembled body as a carrier is used for realizing programmed multi-target through responding a tumor micro-environment, so that main biological obstacles met in a process of transferring the medicine carrier in a body are overcome, and finally, medicines are conveyed to the destination. The obtained self-assembled body has a multi-target effect through the functionalization effect of a plurality of types of terminal groups. On one hand, tree-shaped molecules are used as the medicine carrier and have the advantages of good stability, high mechanical strength, multivalent terminal groups, hyper-branched structures, and intracellular conveying of echoviruses; on the other hand, a multi-element cooperated self-assembling policy is integrated with the advantages of all functional groups on a tree-shaped macromolecular self-assembled unit, so that the assembled body can be conveyed by the multifunctional and efficient medicine system. The system is particularly suitable for conveying anti-tumor medicines.
Owner:SICHUAN UNIV

Modified biochar, preparation method and application thereof

InactiveCN112263994AEnhanced chelation of heavy metals (leadEnhance the ability of cadmium, copper, etc.)Other chemical processesContaminated soil reclamationCamellia oleiferaManganese oxide
The invention provides modified biochar, a preparation method and application thereof. According to the modified biochar, biomass is used as a raw material, and is subjected to carbonization pyrolysisthrough mixing modification with potassium permanganate and ferric chloride to prepare iron-manganese oxide loaded biochar, and the biochar is modified with chitosan to obtain the modified biochar, wherein the raw material is one of straw, rice straw, rice husk, peanut shell, corncob, camellia oleifera shell and cottonseed hull. According to the invention, the prepared modified biochar is large in specific surface area, developed in pore and multiple in surface oxygen-containing functional groups; the modified biochar is applied to treatment of heavy metal organic matter contaminated soil, onthe basis of promoting adsorption of heavy metal and organic matter in the contaminated soil, a good solidification and stabilization effect can be achieved on the heavy metal organic matter; and themodified biochar material can stably exist in the soil for a long time, and has long-term restoration.
Owner:NORTHEASTERN UNIV

High-capacity boron affinity separation material and preparation method and application thereof

The invention discloses a high-capacity boron affinity separation material. According to the material, surface-initiated atom transfer radical polymerization and terminal modification technologies are combined, alkene compounds containing phenylboronic acid serve as monomers to be polymerized on solid matrix surfaces, and phenylboronic acid containing alkynyl is used for polymer chain end functionalization through click chemistry, and accordingly, the separation materials containing high-density phenylboronic acid groups are obtained. The separation material is high in absorption capacity and specificity and has the advantages of being few in use material and high in recovery rate and sensitivity when being used for separating and gathering cis dihydroxylation substances. (img file= 'dest_path_image001. TIF' wi= '468' he= '224' / ).
Owner:NORTHWEST UNIV

Method for preparing biochar by using blue algae

The invention discloses a method for preparing biochar by using blue algae, which comprises the following steps: 1. preparing raw materials; 2. freeze-dry; 3. carbonization; 4. granulation. Biochar prepared by utilizing that method for preparing biochar from blue algae of the present invention is a carbon-rich solid by-product remaining after pyrolysis of biomass in an anaerobic or hypoxic state.Because of its high carbon content, well-developed pore structure and good corrosion resistance, it can retain water, nutrients, adsorb organic matter, heavy metals and other pollutants, and is an ideal soil improver and adsorbent, and can slow down greenhouse benefit, improve soil, increase crop yield and reduce environmental pollution. Biochar is an ideal adsorbent because of its well-developedpore structure and abundant surface functional groups, which can remove organic matter and heavy metals, especially heavy metals.
Owner:SUZHOU ACADEMY OF AGRI SCI

Iron oxide loaded biomass carbonized microspheres and preparation method and application thereof

The invention discloses iron oxide loaded biomass carbonized microspheres and a preparation method and application thereof. The preparation method includes following steps: adding iron salt into a boiling cetyl trimethyl ammonium bromide solution; using a sodium hydroxide solution to adjust pH; adding coconut shell which is frozen, ground and screened by a 100-mesh sieve, stirring for evaporation, and drying at constant temperature; performing hydrothermal carbonization in a zinc acetate solution to obtain the iron oxide loaded carbonized microspheres. The preparation method is simple in process and simple and convenient to operate, the carbonized microspheres are low in cost, stable in physiochemical property, good in performance of adsorbing lead and cadmium in wastewater and free of secondary pollution, and removal rate can reach higher than 92% when the carbonized microspheres are used for treating wastewater containing cadmium ions or lead ions of below 20mg / L.
Owner:CENT SOUTH UNIV

Catalyst for rapid pyrolysis and liquefaction of biomass as well as preparation method and application thereof

The invention relates to a catalyst for rapid pyrolysis and liquefaction of biomass as well as a preparation method and application of the catalyst and belongs to the technical field of biomass energy. The catalyst consists of a carrier and an active component, wherein the active component is loaded onto the carrier through an immersion method. The carrier is a side product rapid pyrolysis carbon produced from the rapid pyrolysis and liquefaction of biomass; the rapid pyrolysis carbon is deoiled, delimed, activated and oxidized to form a middle-large hole structure with holes of 20-80 nanometers; the active component is a transition metal which is immersed onto the carrier through the steps of loading and reducing; then the catalyst for the rapid pyrolysis and liquefaction of biomass is prepared. By adopting the catalyst provided by the invention, the problem of high additional value utilization of the side product rapid pyrolysis carbon is solved, the adaptability to a pyrolysis reaction environment is strong, and the directional adjustment and control for the rapid pyrolysis and liquefaction of biomass can be realized.
Owner:BEIJING FORESTRY UNIVERSITY

Peptide dentritic macromolecular drug and preparation method and application thereof

The invention discloses a peptide dentritic macromolecular drug and a preparation method and application thereof, and belongs to the field of biomedicine. The drug comprises a peptide dentritic macromolecular skeleton, and terminal-group functionalized groups. The biological activity of the drug is ensured through the terminal-group functionalized groups; and the periphery of the peptide dentritic macromolecular drug can be grafted with a lot of terminal-group functionalized groups, so that the biological effect of the terminal-group functionalized groups is effectively amplified by the amplification effect of dendritic macromolecules. The drug has an accurate molecular structure and abundant surface functional groups, is good in water solubility, and also has the biological characteristics of being similar to globulin, easy to be taken in by cells and the like; the biological effect of the peptide dentritic macromolecules is enriched; and the development of peptide drugs is promoted. The preparation method is simple in technology; and the structure of the peptide dentritic macromolecular drug is accurately controlled by controlling preparation of various raw materials.
Owner:SICHUAN UNIV

Method for preparing calcium carbonate-chitin composite powder by using crab shells as raw material and application of method

The invention discloses a method for preparing calcium carbonate-chitin composite powder by using crab shells as a raw material and application of the method. The preparation method comprises the following steps: (1) removing meat on the crab shells, drying by a drum and pulverizing; (2) removing protein and fat in powder with 1-10% of alkali liquor; (3) decolorizing the powder by using an oxidizing agent solution with mass concentration of 0.1-5%; and (4) grinding by a wet process, carrying out filter pressing, drying by the drum and polarizing to obtain the calcium carbonate-chitin composite powder. The sources of raw materials are extensive, the process is simple, operation conditions are gentle, the natural composite structure of calcium carbonate-chitin in the crab shells is kept in the prepared powder, and respective advantages of calcium carbonate and chitin are combined, particle size distribution is even, the whiteness is high, and the calcium carbonate-chitin composite powder can be used as packing of plastic and rubber, an adsorbent, a flocculating agent, an antibacterial agent, a catalyst or a tissue engineering material.
Owner:ZHEJIANG UNIV

Method for reducing bioavailability of soil with combined heavy metal pollution

The invention discloses a method for reducing the bioavailability of soil with combined heavy metal pollution. The method comprises the following steps: subjecting the soil with combined heavy metal pollution to air drying, sieving and preservation; with agricultural and forestry residues as raw materials, preparing biochar particles, and carrying out crushing, screening, air drying or stoving, and preservation; mixing the screened dried biochar particles and the soil with combined heavy metal pollution in a weight ratio of 1: 20 to 1: 100 under stirring, adding distilled water to allow the water content of the obtained mixture to reach 50 to 70% of field moisture capacity, and subjecting the mixture to standing for 5 to 7 days to allow the mixture to be fully decomposed so as to prepare achar-soil mixture with combined heavy metal pollution; and transplanting tobacco seedlings into the char-soil mixture by using a well cellar seedling transplanting method, uniformly filling the wellcellar with the mixture and allowing the growing points of the tobacco seedlings to main exposed. The method provided by the invention substantially reduces the available contents of Cd and Pb in thesoil with combined heavy metal pollution and lower absorption and enrichment of the heavy metals Cd and Pb by the roots, stems and leaves of crops; and the method has the advantages of low cost, highefficiency, simple operation and easy promotion and application.
Owner:INST OF GEOCHEM CHINESE ACADEMY OF SCI

Remediator and preparation method thereof and restoration method for heavy metal contaminated soil thereby

The invention discloses a remediator for restoration of heavy metal contaminated soil. The remediator is prepared from the following ingredients in parts by weight: 30 to 60 parts of biomass charcoal, 2 to 7 parts of calcium carbonate, 3 to 6 parts of dolomite, 4 to 6 parts of bentonite, 2 to 5 parts of wood vinegar and 0.2 to 1 part of trichoderma. The invention also discloses a restoration method for heavy metal contaminated soil, comprising the following steps of adding the remediator to the heavy metal contaminated soil after the soil is turned over; planting rape in the soil; detecting physical and chemical properties of the soil after harvesting the rape until the rape reaching the harvest period; and repeating the above procedure until the physical and chemical properties of the soil meet the requirements. Soil fertility is improved greatly and the degree of heavy metal pollution is reduced through the method of combining the prepared remediator for restoration of heavy metal contaminated soil with the rape cultivation. Meanwhile, the method is easy to operate and low in cost.
Owner:千人计划土壤治理研究院(唐山)有限公司

Compound material used for hexavalent chromium removal and preparation method thereof

The invention provides a compound material used for hexavalent chromium removal and a preparation method thereof. The compound material is prepared from charcoal and magnetic ferriferrous sulfide loaded onto a charcoal matrix; the preparation method comprises the steps that through a pyrolysis and calcination method, rice hull is used as a raw material to prepare the charcoal; the charcoal is immersed in a solution containing ferrous sulfate, L-cysteine is used as a sulfur source, ethylene glycol is used as a solvent, and through a solvothermal method, the magnetic charcoal / ferriferrous sulfide compound material is synthesized in one step; application comprises the steps that the compound material is added into hexavalent chromium wastewater with a concentration of 20 mg / L, the usage amount of the compound material is 0.2-1.0 g / L, and after oscillatory reaction is carried out for a period of time at 25 DEG C, a magnet is used for separating the compound material and the solution, so that hexavalent chromium ions in the wastewater are removed. The compound material used for hexavalent chromium removal and the preparation method thereof have the advantages that the compound materialpreparation method is simple, low in cost, environmentally friendly and high in efficiency of removing the hexavalent chromium ions in the wastewater and the like.
Owner:WENZHOU MEDICAL UNIV

Method for preparing blue emission carbon quantum dots and application thereof

The invention provides a method for preparing blue emission carbon quantum dots. According to the method, carbon quantum dots are synthesized by a microwave method, and dehydration-condensation reaction generated under the microwave effect between amino acid and ethylene glycol is utilized to form carbon quantum dots. The method is a one-step preparation method, is quick, efficient and simple. Furthermore, the invention further develops application of the blue emission carbon quantum dots in oneness detection of antibiotics, and provides a novel method for quantitatively detecting metronidazole. The aim of quantitative detection can be achieved by utilizing optical sensing between metronidazole and carbon quantum dots, and the method is quicker, simpler, more convenient and more intuitive than other methods.
Owner:HEBEI UNIV OF TECH

Modification method and application of activated carbon

The invention discloses a modification method and application of activated carbon. The modification method of the activated carbon comprises the following steps of S1, subjecting the activated carbon to drying treatment; S2, introducing a gas into an atmospheric-pressure low-temperature plasma device according to a gas flow rate of 1cc / min to 200cc / min, sending the activated carbon subjected to the drying treatment into the plasma device, making the activated carbon located at an ejection outlet of the low-temperature plasma device, controlling the movement speed of the ejection outlet of the plasma device to be 0mm / s to 30mm / s, and carrying out treatment for 0.5min to 30min, so as to subsequently obtain modified activated carbon. According to the modification method, the modification of the activated carbon through spark discharge is realized through a physical way; the specific surface area of the activated carbon is obviously increased; further, surface functional groups are also more abundant. The modification process is simple and convenient; the efficiency is high; further, no pollutants are generated.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV +1

Preparation method of tannic acid-based star-shaped polycarboxylate superplasticizer

ActiveCN111019060AMolecular branchingLow viscosityPolymer scienceGlycidyl methacrylate
The invention discloses a preparation method of a tannic acid-based star-shaped polycarboxylate superplasticizer. The preparation method comprises the following steps: adding tannic acid, sodium hydroxide and water into a reaction kettle, dropwisely adding glycidyl methacrylate, and reacting to obtain modified tannic acid; reacting the modified tannic acid, an unsaturated polyether macromonomer, an unsaturated fatty acid micromonomer, an initiator, a chain transfer agent and water at 50-80 DEG C for 3-6 hours; and adjusting the pH value of an obtained star-shaped copolymer to 6.0-7.0 by usingan alkaline substance to obtain a reddish brown solution, namely the tannic acid-based star-shaped polycarboxylate superplasticizer. The tannic acid-based star-shaped polycarboxylate superplasticizerdisclosed by the invention has the advantages of multiple molecular branched chains, low viscosity, small hydrodynamic volume, rich surface functional groups; the tannic acid molecules have a large number of hydroxyl groups, the rich polar groups have a strong hydrophilic effect with the polar surfaces of cement particles, and hydration films can be generated on the surfaces of the cement particles, so that the cement particles are fully dispersed and wetted.
Owner:GUIZHOU EDUCATION UNIV

Copper-cerium co-doped magnetic composite material and preparation and application method thereof

The invention belongs to the technical field of water treatment and particularly relates to a copper-cerium co-doped magnetic composite material, a preparation method thereof and application of the material in water body arsenic removal. Iron salt, copper salt and cerium salt serve as the raw materials, sodium acetate serves as an alkaline source, ethylene glycol serves as a solvent, and the copper-cerium co-doped magnetic composite material is synthesized through the solvothermal method. Dual-metal doped magnetic composite materials with different sizes and specific surface areas are obtained by regulating the molar ratio of doped copper metal to cerium metal salt. The preparation method has the advantages of being low in cost, simple in process, excellent in arsenic adsorption, capable of achieving magnetic separation easily and the like, and plays an important role in solving arsenic pollution in water bodies.
Owner:CENT SOUTH UNIV

Sulfur-based intercalated hydrotalcite modified charcoal-based adsorption material and preparation and application thereof

The invention belongs to the technical field of wastewater treatment and soil remediation, and particularly relates to a sulfur-based intercalated hydrotalcite modified charcoal-based adsorption material and preparation and application thereof. The preparation method comprises the following steps: dipping a biomass raw material in an alkali liquor, carrying out pyrolysis carbonization to obtain an activated biochar material, carrying out hydrotalcite loading under a hydrothermal condition by taking the biochar material as a substrate, and finally replacing interlayer anions of hydrotalcite with sulfenyl anions. The adsorbent obtained by the preparation method not only has the adsorption capacity of independent biochar and hydrotalcite on heavy metals, but also can obtain a loose and porous biochar material by activating a biomass material, and then the biochar material can be further expanded through a hydrothermal reaction, and the loading capacity and the loading stability of the hydrotalcite are improved; finally, the adsorption capacity of the heavy metal anions is remarkably improved through interlayer replacement of the sulfenyl anions.
Owner:HUAZHONG UNIV OF SCI & TECH

Novel preparation method of functionalized porous magnetic microspheres

The invention provides a novel preparation method of functionalized porous magnetic microspheres. The novel preparation method comprises the following steps: firstly, preparing seed microspheres withuniform particle size through polymerization reaction; secondly, preparing porous microspheres with functional groups on the surfaces by adopting a seed polymerization method, and thirdly, modifying the porous microspheres to enable the surfaces to be charged; then preparing magnetic nanoparticles with controllable particle sizes and charges or hydrophilic and hydrophobic surfaces, mixing the surface-modified porous microspheres with the magnetic nanoparticles with charges or hydrophilic and hydrophobic surfaces, enabling the charges on the surfaces of the porous microspheres to be opposite tothose on the surfaces of the magnetic nanoparticles through pH adjustment, and through electrostatic interaction, adsorbing a layer of magnetic nanoparticles in pore channels of the porous microspheres, and then synthesizing a functionalized shell layer on the surfaces of the porous magnetic microspheres, so as to prepare functionalized porous magnetic microspheres; the functionalized porous magnetic microspheres prepared by the method have the characteristics of uniform particle size, consistent magnetic content and rich surface functional groups.
Owner:南京赛纳宝纳米科技有限公司 +1

Bioretention pond with simultaneous nitrogen and phosphorus removal function

The invention discloses a bioretention pond with a simultaneous nitrogen and phosphorus removal function. The bioretention pond comprises a super-high layer, a submerged layer, a covering layer, an iron-modified biochar packing layer, a gravel drainage layer and a water outlet which are all distributed in a bioretention pond body from top to bottom; the bioretention pond body is internally provided with an inspection well, the top of the inspection well is provided with a rainwater perforated strainer, the bottom of the inspection well is provided with an overflow water outlet, and the side wall of the inspection well is communicated with the water outlet; the height h of the super-high layer and the submerged layer in the bioretention pond body is the sum of the height a of the gravel drainage layer and 1 / 5 of the height b of the iron-modified biochar packing layer; the height of the submerged layer is 1 / 3 of the height of the iron-modified biochar packing layer; outflow water of theportion, at the height a+1 / 5b from the bottom, of the submerged layer is collected from the water outlet with the upturned bottom; rainwater beyond the height of the submerged layer is discharged outof the overflow water outlet of the inspection well from the rainwater perforated strainer. The bioretention pond has the advantages that the removal rates of the nitrogen and phosphorus in runoff rainwater by the bioretention pond are simultaneously increased, and the nitrogen and phosphorus removal effect is improved.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Biocharcoal-based slow release fertilizer and preparation method thereof

The invention discloses biocharcoal-based slow release fertilizer. The biocharcoal-based slow release fertilizer is prepared from biocharcoal and chemical fertilizer with the mass ratio being 20:(5 to10). The biocharcoal-based slow release fertilizer disclosed by the invention has the beneficial effects that agricultural and forest wastes such as straws with wide distribution, large yield and lowcost are adopted as biomass, has rich pore channels, is easily decomposed, is not deteriorated after being absorbed, is wear-resistant, and also has excellent adsorbing and ion-exchange properties, the fertility, the structure and microorganisms and the like of soil can be effectively improved, and the soil quality can be improved; shown from the cumulative released amount of nitrogen of the biocharcoal-based slow release fertilizer in water, the cumulative released amount of the nitrogen in 480 hours is about 80%, i.e., the cumulative released amount of nitrogen nutrients in 20 days is 80%.The invention also discloses a preparation method of the biocharcoal-based slow release fertilizer. The preparation method adopts a hydrothermal method to prepare the biocharcoal-based slow release fertilizer, the technology is manure, the operation is convenient, simple and easy, low cost, less investment and low energy consumption are achieved, and an economic and feasible technical means is provided for large-scale application of the biocharcoal-based slow release fertilizer.
Owner:HUNAN AGRICULTURAL UNIV +1

Preparation and application methods of polyaluminium chloride modified graphene oxide adsorbent

The invention discloses a method for adsorbing and removing fatty acid in wastewater by utilizing polyaluminium chloride modified graphene oxide. The method comprises the following steps: preparing graphene oxide suspension liquid by using natural graphite as a raw material and using a Hummer method; adding a certain amount of polyaluminium chloride solution into the graphene oxide suspension liquid, and evenly mixing to obtain polyaluminium chloride modified graphene oxide suspension liquid; evenly mixing the polyaluminium chloride modified graphene oxide suspension liquid with the wastewater in a certain volume ratio, and oscillating to obtain the graphene oxide suspension liquid adsorbing the fatty acid; simultaneously converting graphene oxide into floccules; filtering to obtain purified water in which the fatty acid is removed and the graphene oxide after adsorption reaction. According to the method disclosed by the invention, the graphene oxide is modified by utilizing the polyaluminium chloride, so that negative charge of the surface of the graphene oxide is changed into positive charge; through electrostatic adsorption and chemical adsorption, the adsorption volume of the graphene oxide adsorbent on the fatty acid is improved; through a flocculation effect of the polyaluminium chloride, the solid-liquid separation efficiency of the graphene oxide adsorbent is greatly improved.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Method for improving soil by applying charcoal

A method for improving soil by applying charcoal comprises a first step of adding 8-12 g of charcoal to every kilogram of dry soil, and before crop cultivation, turning over the dry soil together with a base fertilizer to 10-15 cm of a soil plough layer; a second step of guaranteeing moisture sufficiency during a crop growing period; and a third step of spraying pest and disease control pesticides quarterly. The pH of the charcoal is 10, the mass fraction of C is 51%, the mass fraction of H is 2.6%, the mass fraction of N is 1.2%, the mass fraction of O is 45%, and the mass fraction of S is 0.4%. According to the method for improving the soil by applying the charcoal, the adopted charcoal has rich micro-pore structures and physical and chemical properties, is large in specific surface area, has rich surface functional groups and is high in adsorption capacity; the soil cation exchange capacity can be improved, more nutrient ions are adsorbed, nutrient loss is avoided, and thus soil fertility and fertilizer utilization rate are improved.
Owner:郭琳

Preparation method and application of magnetic activated carbon

The invention provides a preparation method and application of magnetic activated carbon, and the preparation method comprises the following steps: step 1, washing, drying and cutting cotton textile waste into pieces to obtain a waste sample; 2, dissolving ferrous chloride in ethyl alcohol to obtain an ethyl alcohol-ferrous chloride solution; 3, placing the waste sample in an ethanol-ferrous chloride solution for sealed impregnation, then moving out the waste sample, and drying the waste sample to obtain an impregnated sample; 4, placing the impregnated sample in nitrogen for pyrolysis, cooling the pyrolyzed product to room temperature, and taking out the pyrolyzed product to obtain a pyrolysis sample; and 5, placing the pyrolysis sample in a hydrochloric acid solution, heating and boilingthe solution, moving out the pyrolysis sample, cleaning the pyrolysis sample, and drying the pyrolysis sample to obtain the magnetic activated carbon. The magnetic activated carbon is used for adsorbing and removing hexavalent chromium in an aqueous solution. According to the preparation method disclosed by the invention, the utilization efficiency of the activating agent is improved, and meanwhile, the magnetic activated carbon with stable magnetism can be prepared through one-step pyrolysis, synchronous carbonization and activation and magnetization, so that the preparation cost is reduced,and the preparation process is simplified.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Method and device for cooperative treatment of sludge and livestock and poultry manure

The invention belongs to the technical field of harmless treatment of sludge and livestock and poultry manure, and relates to a method and a device for cooperative treatment of sludge and livestock and poultry manure. The method for cooperative treatment of sludge and livestock and poultry manure comprises the following steps of: uniformly mixing sludge and biogas residues, adding high-temperature red-hot biochar for thermal conditioning, performing mechanical filter-pressing dehydration, mixing a filter-pressing solid phase with livestock and poultry manure subjected to aerobic composting and self-heating drying, sequentially performing pyrolysis carbonization and pyrolysis activation, using one part of the high-temperature red-hot biochar generated by pyrolysis activation for thermal conditioning, and cooling the other part of the high-temperature red-hot biochar to obtain high-quality biochar. According to the method and the device provided by the invention, the dehydration difficulty of the sludge and the livestock and poultry manure can be improved, resources are fully utilized, and the quality of the biochar obtained by pyrolysis is relatively high.
Owner:INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI

Soil chlorinated hydrocarbon remediation method based on modified zero-valent iron

The invention provides a soil chlorinated hydrocarbon remediation method based on modified zero-valent iron, comprising mixing activated carbon fibers and zero-valent iron, performing ball milling toobtain activated carbon fiber-modified zero-valent iron, adding the activated carbon fiber-modified zero-valent iron into chlorinated hydrocarbons contaminated soil, and allowing to react. Compared with existing mediation processes with zero-valent iron, the soil chlorinated hydrocarbon remediation method based on modified zero-valent iron has the advantages that the addition of active carbon fibers brings no reduction in the reaction activity of zero-valent iron to reduce trichloroethylene and other chlorinated hydrocarbons; natural hydrophobicity and good adsorption of the active carbon fibers enables the zero-valent iron to evidently increase the release rate of chlorinated hydrocarbons from soil, so that the problem is solved that hysteretic separation of chlorinated hydrocarbons causeproneness to remediation rebound; in addition, the activated carbon fiber-modified zero-valent iron helps greatly increase the selectivity of zero-valent iron on target contaminates to be removed, namely under equal conditions, upon the removal of equal chlorinated hydrocarbons, the consumption of the zero-valent iron is evidently reduced, and therefore, chemicals cost can be reduced and the quantity of zero-valent iron waste is reduced correspondingly.
Owner:TONGJI UNIV

Aluminizer adhesive layer resin containing graphene oxide and preparation method thereof

The invention belongs to the technical field of high polymer materials and relates to aluminizer adhesive layer resin containing graphene oxide and a preparation method thereof. The aluminizer adhesive layer resin containing the graphene oxide comprises 25-40 parts of acrylic resin, 5-15 parts of other resin, 8-20 parts of silica powder, 1-10 parts of graphene oxide, 0.5-1.0 part of addition agent and 40-70 parts of solvent. The invention further discloses the preparation method of the aluminizer adhesive layer resin. According to the aluminizer adhesive layer resin, the graphene oxide (GO) is creatively introduced into the aluminizer adhesive layer resin, and a series of adhesive layer resin of different material feeding ratios is obtained through a physical blending mode. The graphene oxide is a novel carbon material of great performances, the graphene oxide is high in specific surface area and has sufficient surface functional groups, and currently the graphene oxide is widely applied to the preparation of polymer composite materials. In addition, it is easier for the GO to disperse in modified materials on account of a single layer flake structure of the GO, and the advantages of the aluminizer adhesive layer resin can provide new ideas for improving the thermoprint performance of the aluminizer adhesive layer resin.
Owner:江苏卫星新材料股份有限公司

Compound immobilized enzyme carrier material and preparation method and application thereof

The invention discloses a compound immobilized enzyme carrier material and a preparation method and application thereof. The carrier material is prepared as follows: after alkynyl groups are introduced into a reaction of UiO-66-NH2 and 3-propargyl bromide, a click chemistry reaction occurs with poly(tert-butylmethacrylate) of which the end group is nitrine, and then hydrolyzing to obtain nano-particles with the grain diameter of 280 to 320 nm. Through electrostatic incorporation between carboxyl and amino, pectinase is fixed onto the carrier material, so that the active sites capable of being combined with pectinase are also greatly increased while the stability of the pectinase is improved, the adsorbing capacity of the pectinase is high and reaches 89.7% at most; the immobilized pectinase has higher pH, temperature and storage stability and preferable reusability, the relative enzyme activity after eight times of reusability is still 81%, and the carrier material has huge application prospect in the field of immobilized enzymes.
Owner:SHAANXI NORMAL UNIV

Lithium ion battery positive electrode material and preparation method thereof

The invention relates to a lithium ion battery positive electrode material and a preparation method thereof, the positive electrode material is a Ti3C2 MXene coated lithium manganese iron phosphate material, and the Ti3C2 MXene is uniformly coated on the surfaces of lithium manganese iron phosphate nanoparticles to form a conductive network. The preparation method comprises the following steps: adding a phosphorus source and a lithium source into a deionized water / PEG solution to form a suspension A, adding a manganese source, an iron source, an antioxidant and Ti3C2 MXene into the deionized water to form a suspension B, dropwise adding the suspension B into the suspension A under a continuous stirring condition to form a mixed solution, transferring the mixed solution into a hydrothermal reaction kettle, preserving heat, and drying to obtain the Ti3C2 MXene / phosphorus dioxide composite material. And after the reaction is completed, centrifugally separating out a product, washing, drying and sintering. According to the invention, Ti3C2 MXene is used for carrying out surface coating on the lithium manganese iron phosphate material, so that the ion and electron transmission capability and the structural stability of the lithium manganese iron phosphate material are effectively improved, and the lithium manganese iron phosphate material is very suitable for being used as a high-energy and high-power-density lithium ion battery positive electrode material.
Owner:HUBEI WANRUN NEW ENERGY TECH DEV

Dual-emission-ratio fluorescent carbon dots as well as preparation method and application thereof

The invention discloses a dual-emission-ratio fluorescent carbon dot as well as a preparation method and application thereof. According to the preparation method of the dual-emission-ratio fluorescent carbon dots, sodium alginate and glutathione are subjected to hydrothermal carbonization or solvothermal carbonization to prepare the dual-emission-ratio fluorescent carbon dots. The method is simple and easy to operate, low in cost and good in repeatability. The excitation wavelength of the prepared carbon dots is 420 nm, and the dual emission wavelengths are 480 nm and 650 nm respectively. In addition, the dual-emission-ratio fluorescent carbon dots are high in light stability, good in water solubility, low in cytotoxicity, good in biocompatibility, capable of being used for specific detection of Fe 3+, good in selectivity and high in sensitivity; so that the fluorescent carbon dot can be used for sensitive detection of Fe 3+ in environmental water such as tap water.
Owner:GUANGDONG INST OF MICROBIOLOGY GUANGDONG DETECTION CENT OF MICROBIOLOGY
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