The invention discloses a preparation method of the MOF-
metal nanoparticle-COF
composite material. The method comprises the following steps: dispersing MOF into a solution containing a
metal ion precursor, adding a
sodium borohydride solution or performing illumination reduction, or performing
hydrogen reduction after
centrifugation to obtain the MOF-
metal nanoparticle composite material. Activating at a high temperature of 120-150 DEG C and then dispersing in 1, 3-
butanediol; the method comprises the following steps: adding 1, 4-dioxane and
mesitylene into a mixed
solvent of 1, 4-dioxane andmesitylene; then adding a small amount of
aldehyde group organic ligand and ultrasonically and uniformly mixing; subsequent addition of
acetic acid, adding a corresponding amount of amino organic ligand, and continuously stirring for a period of time to obtain an MOF-metal
nanoparticle-COF
seed crystal compound; and adding an
aldehyde group organic ligand and an amino group organic ligand, uniformly stirring and mixing, adding a corresponding amount of
acetic acid, and continuously stirring, heating and preserving heat to obtain the MOF-metal nanoparticle-COF compound.
Covalent binding of thetwo materials is achieved through a
Schiff base reaction between
aldehyde groups on the surfaces of the seed crystals and amino groups on the surfaces of the MOF materials, the
binding force is stableand firm, the preparation method is simple, the method can be used for
mass production, and traditional high-temperature and high-pressure
reaction conditions are not needed in the compounding process.