The invention discloses a preparation method of the MOF-
metal nanoparticle-COF 
composite material. The method comprises the following steps: dispersing MOF into a solution containing a 
metal ion precursor, adding a 
sodium borohydride solution or performing illumination reduction, or performing 
hydrogen reduction after 
centrifugation to obtain the MOF-
metal nanoparticle composite material. Activating at a high temperature of 120-150 DEG C and then dispersing in 1, 3-
butanediol; the method comprises the following steps: adding 1, 4-dioxane and 
mesitylene into a mixed 
solvent of 1, 4-dioxane andmesitylene; then adding a small amount of 
aldehyde group organic ligand and ultrasonically and uniformly mixing; subsequent addition of 
acetic acid, adding a corresponding amount of amino organic ligand, and continuously stirring for a period of time to obtain an MOF-metal 
nanoparticle-COF 
seed crystal compound; and adding an 
aldehyde group organic ligand and an amino group organic ligand, uniformly stirring and mixing, adding a corresponding amount of 
acetic acid, and continuously stirring, heating and preserving heat to obtain the MOF-metal nanoparticle-COF compound. 
Covalent binding of thetwo materials is achieved through a 
Schiff base reaction between 
aldehyde groups on the surfaces of the seed crystals and amino groups on the surfaces of the MOF materials, the 
binding force is stableand firm, the preparation method is simple, the method can be used for 
mass production, and traditional high-temperature and high-pressure 
reaction conditions are not needed in the compounding process.