181 results about "Copper(I) iodide" patented technology

Acid-soluble cupric acetate may used in conjunction with potassium iodide to generate cuprous iodide (CuI) as an acid corrosion inhibition aid. A suitable corrosion inhibitor together with the aid protects steel surfaces in an acid environment, for instance, while acid fracturing or matrix acidizing subterranean formations. Cupric acetate monohydrate may be used with an alkali metal iodide salt such as potassium iodide or sodium iodide to generate cuprous iodide in situ in aqueous acid solutions. Use of cupric acetate provides a somewhat delayed reaction rate with potassium iodide to generate the desired product, cuprous iodide, which has very low solubility in acid systems. The method includes delayed and in situ production of cuprous iodide for enhancing performance of commercially available corrosion inhibitors, commonly referred to as intensifying the effect of the corrosion inhibitor (corrosion inhibitor intensifier or simply an intensifier).

The invention relates to a zero-dimensional lead-free caesium copper iodine perovskite blue nanocrystal and a preparation method thereof, and belongs to the technical field of photoelectron material preparation. The preparation method of the nanocrystal comprises the steps that cesium iodide and cuprous iodide are dissolved in N,N-dimethylformamide or dimethyl sulfoxide to obtain a precursor solution, then the precursor solution is injected into an organic solution, a stirring reaction is performed for 3-6 minutes at a speed of 5000-9000 rpm, then centrifugation is preformed, a precipitate istaken and washed, and the nanocrystal is obtained. The nanocrystal not only has a good crystal structure, high yield, high fluorescence efficiency and a stable structure, but also contains no heavy metal lead, reduces the harm to the human body and the environment, and has wide application prospects in photovoltaic devices. The preparation method of the nanocrystal is simple and easy to implement,has low cost and can be popularized in the industrial production.

The invention discloses a conjugated microporous polymer, and a preparation method and application thereof. The preparation method of the conjugated microporous polymer comprises the following steps:under the atmosphere of argon or nitrogen, mixing a compound II, a compound III, cuprous iodide and a palladium catalyst into an diisopropylamine / organic solvent mixed solution, and uniformly carryingout stirring at room temperature; carrying out ultrasonic dispersion, carrying out freezing and deoxidizing, then carrying out heating to 50-120 DEG C, and carrying out a reaction for 24-72 hours; and carrying out cooling to room temperature, and carrying out filtering, washing and drying. An ion-loaded nano-composite catalytic material is prepared by taking the conjugated microporous polymer asa carrier to load nano-silver particles. The composite catalytic material can be used for efficient catalytic reduction of industrial pollutant p-nitrophenol, and the industrial pollutant p-nitrophenol is converted into common medicines and chemical raw material p-aminophenol. In addition, the catalyst has good solvent tolerance, stability and recyclability.

The invention discloses a luminescent material of red-phosphorescence cuprous iodide complex and a preparation method thereof. The phosphorescence complex is obtained through complexation of CuI and a ligand, with a molecular structure of (CuIL)n, wherein L is the ligand, the ligand is electrically neutral heterocyclic ligand 4-(2-benzoxazolyl) pyridine, that is, the combination of the benzoxazolyl and the pyridine. Due to introducing the benzoxazolyl group beneficial to luminescence of molecular excited state and heavy halogen iodine beneficial to intersystem crossing of the excited state into the material, and promotion of the intersystem crossing by metal-to-ligand charge transfer, the material has relatively good phosphorescence performance. The material is obtained by the directly mixing reaction of the ligand with an acetonitrile solution of CuI, has advantages of simple technology, simple equipment, easily-available raw materials, low cost and good thermal stability, and can be used as a photoluminescence red-phosphorescence material, and a phosphorescent material of a luminous layer of an electroluminescent device composed of multilayer organic materials.

The invention discloses a preparation method of gamma-copper iodide. The preparation method comprises the following steps: adding iodine into water so as to obtain an iodic aqueous solution and adding hydrazine hydrate into the iodic aqueous solution for mixed reaction to obtain an iodide ion solution, wherein the molar ratio of the iodine to the water is controlled at 1:(50-90) and the molar ratio of the hydrazine hydrate to the iodine is controlled at (4.1-4.5):1.0; and adding the iodide ion solution into a copper sulfate solution under the stirring effect, controlling the molar ratio of copper sulfate to iodine at (2.0-2.2):1.0, fully reacting, filtering and drying to obtain gamma-copper iodide. According to the preparation method, the iodine utilization rate is high, a product is less in possibility of being oxidized and decomposed, the production cost is low, and the process is simple.

The invention discloses a preparation method of amide. With an aldehyde derivative and a formamide derivative as a reaction substrate, iodide as catalyst and tert-butanol hydrogen peroxide as an oxidizing agent, the amide is prepared through decarbonylation double free radical cross-coupling reaction, wherein the chemical structural formula of the aldehyde derivative is shown in the description, R1 is selected from a naphthyl, a heterlcyclic ring, an alkylene or a mono-substituted aryl; and the iodide is one selected from sodium iodide, potassium iodide, cuprous iodide, lithium iodate, an iodine elementary substance, tetrabutyl ammonium iodide, tetraheptylammonium iodide, tetramethylammonium iodide and benzyltrimethylammonium iodide. According to the invention, because the amide is prepared by using the iodide as the catalyst and using the double free radical cross-coupling method, the use of the traditional metal catalyst with expensive price and larger toxicity as well as a complicated experiment method is avoided so that the reaction is simpler, more convenient, easier, safer, greener and more economic; moreover, the preparation method of the amide disclosed by the invention has the advantages of quite moderate reaction condition, simpler post-treatment and potential industrial application value.

The invention belongs to the technical field of organic synthesis midbody, medicine, pesticide and liquid crystal materials, in particular to a preparation method of 1,4-diaryl-1,3-butadiyne. In the invention, the easily obtained beta, beta-dibromo arylethylene is served as a raw material, under the catalytic action of cuprous iodide, no ligand is added to the raw material and the 1,4-diaryl-1,3-butadiyne compound is efficiently synthesized in dimethylsulfoxide solvent in the presence of 1,8-dual nitrogen heterocyclic ring hendecene. The 1,4-diaryl-1,3-butadiyne synthesized by the invention can be served as the synthesis midbody of the medicine, the pesticide and the liquid crystal. Compared with the existing synthesis method of noble metal palladium, the method of the invention has the characteristics of easily obtained raw materials, low cost, simple operation, and mild reaction conditions, is easy to be industrialized, and has wide application prospect.

The invention discloses a method for synthesizing a 3-hydroxy-3-arylindole-2-one derivative shown as a structural formula (I), which comprises the following steps of: fully reacting raw materials such as an isatin compound shown as a structural formula (II) and arylboric acid shown as a structural formula (III) in an inert organic solvent in the presence of a copper catalyst, a nitrogen-containing bidentate ligand and an alkaline compound, and separating and purifying reaction liquid after the reaction is finished to obtain the 3-hydroxy-3-arylindole-2-one derivative, wherein the copper catalyst is one or any combination of copper trifluoromethanesulfonate, copper acetylacetonate, copper acetate, cuprous iodide, copper bromide, copper fluoride and copper chloride. The method is high in implementation value and good in social benefit and economic benefit.

An agent for virus inactivation capable of exhibiting inactivation action based on structural destruction such as degradation and decomposition against viruses, which comprises a monovalent copper compound such as cuprous oxide, cuprous sulfide, cuprous iodide, and cuprous chloride as an active ingredient, and a virus inactivation material, which contains the agent for virus inactivation on a surface of a substrate and / or inside of the substrate.

The invention discloses a method for preparing CuInS2 nanocrystalline and CuInS2 / ZnS core-shell structure nanocrystalline, which is characterized in that stearic acid indium is reacted with cuprous iodide with the same mole in a mixed solution containing oleic acid, superfluous dodecanethiol and octadecene to obtain the CuInS2 nanocrystalline, a zinc stearate solution is added to obtain the CuInS2 / ZnS core-shell structure nanocrystalline. The CuInS2 nanocrystalline and the CuInS2 / ZnS core-shell structure nanocrystalline have the characteristics of homogeneous phase, low toxicity, good monodispersity, strong repeatability, wide spectrum coverage and high fluorescent quantum yield, wherein the fluorescent quantum yield of the CuInS2 nanocrystalline can reach as high as 8.7%; and the fluorescent quantum yield of the CuInS2 / ZnS nanocrystalline can reach as high as 60%. The method of the invention has the advantages of easy available and stable raw materials, safe and convenient operation and no requirement of rigorous condition; thereby the laboratory large-scale preparation and industrial production of the CuInS2 nanocrystalline and CuInS2 / ZnS core-shell structure nanocrystalline realize the possibility.

The invention discloses a di-nuclear cuprous complex green luminescent material and a preparation method thereof. The green luminescent complex provided by the invention is prepared by complexing cuprous iodide and a ligand, and the molecular structure of the complex is [CuI(DPPB)]2, wherein the DPPB in the formula is an electro-neutral 1,4-di(diphenylphosphine) butane containing a ligand P, and iodide ions of a bridging ligand are connected with the centers of two metal ions to form a di-nuclear structural molecule. The complex not only has the advantages that small molecules are easy to purify and the luminous efficiency is high but also has high thermal stability. The material is prepared through a direct mixing reaction between the cuprous iodide and a dichloromethane solution of the ligand, and has the advantages of simple and convenient process, simple equipment, easily-obtainable raw materials, low cost and the like. The material can be used as a green photo-luminescent material or used as a green luminescent layer material in an electroluminescent device consisting of a plurality of layers of organic materials.

The invention discloses a zero-dimensional Cs3Cu2I5 perovskite scintillation crystal and application thereof. The zero-dimensional Cs3Cu2I5 perovskite scintillation crystal is prepared through the steps that firstly, N, N-dimethylformamide and dimethyl sulfoxide are mixed evenly to prepare a mixed solution, cesium iodide and cuprous iodide are added into the mixed solution, stirring is conducted to prepare a supersaturated precursor solution, and finally crystal growth is conducted through an inverse temperature crystallization method after the supersaturated precursor solution is filtered. When the Cs4PbI6 perovskite crystal is prepared, the inverse temperature crystallization method is adopted, operation is easy, controllability is high, repeatability is good, and large-scale industrialproduction can be achieved; meanwhile, the crystal prepared by the method is good in transparency, good in stability, high in quantum luminous efficiency and high in responsivity, and can be used fornuclear radiation detection.

The invention discloses a copper trifluoromethseleno (I) reagent for aryl halides / alkanes, and a preparation method and an application thereof, wherein cuprous iodide, red selenium powder, anhydrous potassium fluoride and trimethylsilane are stirred in acetonitrile at normal temperature for reaction, and a ligand (nitrogen ligand or phosphine ligand) is added to the solution; as a result, a trifluoromethseleno agent with stable air is obtained. The reagent is capable of effectively catalyzing aryl halides / alkanes and heterocyclic compounds (derivatives) to form aromatic hydrocarbon and heterocyclic trifluoromethseleno derivatives with selenium powder as selenium element source and trimethylsilane as trimethyl source. According to the invention, the high-purity [CuSeCF3] reagent can be directly obtained at high yield by using industrially cheap reagents such as cuprous iodide, potassium fluoride and the like, and CuSeCF3 does not need to be prepared from highly toxic and gaseous CF3SeSECF3; therefore, the cost and the operation requirements can be reduced to a large extent; and the method has an excellent industrial application prospect.

The present invention relates to a composition, textile, and mask for reducing the inhalation of pollutants. The composition includes an aqueous solution of an inorganic iodide compound, a metal phthalocyanine, and a polymeric binder. The inorganic iodide can be cuprous iodide, the metal phthalocyanine can be iron phthalocyanine, and the polymeric binder can be polyvinylpyrrolidone or polyvinyl alcohol. This pollutant-inactivating composition neutralizes pollutants such as nitrogen dioxide, sulfur dioxide, ozone, volatile organic compounds and other unpleasant airborne agents, without requiring elevated temperatures or bulky canisters containing adsorbents. Optionally, a humectant can also be incorporated into the coating solution to retain moisture in the active filter matrix, which enhances the activity of the composition to inactivate oxidizing gases and other toxic constituents of air pollution.

The invention provides a method for synthesizing a copper indium diselenide quantum dot. The CuInSe2 quantum dot is prepared through a two-step reaction by using copper iodide or copper acetylacetonate as a copper source, indium acetate or indium 2,4-pentanedionate as an indium source and oleylamine as ligand and solvent. The CuInSe2 quantum dot has a size of 4-10nm, has a tetragonal phase structure by XRD crystal phase analysis, has excellent photoelectric performance, and is suitable for preparing quantum dot sensitized solar cells. Compared with a hot injection method, the method has the advantages of simple and easy operation, simpler process, shorter synthesizing cycle, good production controllability and repeatability and low cost, is suitable for industrial production, and has a wide application prospect in solar cells.

The invention belongs to the field of nano-materials and nano technology and particularly relates to a controllable preparation method of Cu3SbS4 nanocrystalline material, characterized by comprising following steps: 1), adding copper iodide and antimony chloride into oleyl amine according to an addition ratio of 3 mmol:1mmol:10mL for the copper iodide, the antimony chloride and the oleyl amine, introducing protective argon, controlling the temperature and stirring until full dissolution of the copper iodide and the antimony chloride to obtain a metal salt complex solution; 2), adding 7-11 ml of 1mol / L diphenyl ether solution of diphenylthiourea into the metal salt complex solution, and heating to a set temperature and reacting; 3), after reacting is complete, cooling to room temperature, adding methyl alcohol to wash Cu3SbS4 nanocrystalline obtained by reacting to obtain the Cu3SbS4 nanocrystalline material. The preparation method is simple in process and low in cost.

A virus inactivator which can exhibit an inactivation activity involving structural disruption such as denaturation or decomposition on viruses, and which comprises a univalent copper compound such as cuprous oxide, cuprous sulfide, cuprous iodide and cuprous chloride as an active ingredient; and a virus-inactivating material which comprises a base material and the virus inactivator on the surface and / or the inside of the base material.

The invention relates to a perovskite solar cell based on copper-indium-sulfur nanocrystals and a preparation method thereof. The preparation method comprises the steps of dissolving sublimated sulfurpowder in DDP, and mixing evenly to form a DDP-S precursor solution; (2) mixing cuprous iodide, indium acetate, oleylamine, and octadecene to obtain a solution A, and heating the solution A; (3) mixing the DDP-S precursor solution in the step 1) and the solution A, then cooling, and injecting normal hexane to obtain a mixed solution B; (4) washing and drying to obtain a CuInS2 nanocrystal material. The CuInS2 nanocrystal material is enabled to serve as a hole transport layer to prepare a perovskite cell, and the prepared cell is good in stability and high in photoelectric conversion efficiency.

The invention relates to a preparation method of a cuprous iodide two-dimensional material. Cuprous iodide nanosheets and vertical heterojunctions thereof enrich the varieties of the new two-dimensional material and the heterojunctions, and provide new possibility for discovering new electronic and photoelectronic device equipment. The method comprises the following steps: putting a porcelain boat with cuprous iodide powder into a constant-temperature area of a tubular furnace, taking empty Si / 300nmSiO2 or Si / 300nmSiO2 with tungsten selenide and tungsten sulfide as a growing substrate of the nanosheet, and putting into a variable-temperature area at the downstream of the furnace to obtain proper crystal growth temperature; and taking argon as carrier gas, adjusting the flow of the argon to be 10 to 225 sccm, setting the temperature of the constant-temperature area to be 360 to 470 DEG C and maintaining constant temperature for 1 to 40 minutes to obtain the cuprous iodide two-dimensional material. The preparation methods of the tungsten selenide and tungsten sulfide nanosheets comprise the same steps as above. The cuprous iodide nanosheets have the thickness being 1 to 300 nm and the size being 1 to 5 microns, have regular triangular and hexagonal shapes and have high crystallinity, and the preparation method of the heterojunctions is simple.

The invention relates to a synthesis method of disubstituted urea compounds. The synthesis method comprises the following steps: (1) in an air atmosphere, adding amide, arylamine, cuprous iodide and 1,10-phenanthroline to a solvent N-N-dimethylformamide according to a molar ratio of 1:(1.0-2.0):(0.1-0.2):(0.2-0.4) and stirring at 110-130 DEG C till the reaction raw materials disappear; (2) by the end of the reaction, adding excess saturated salt water in to the system, extracting the product with ethyl acetate, washing an organic phase with saturated salt water, drying, and removing the solvent out of the organic phase through a rotary evaporator to obtain a crude product; and (3) purifying the crude product through column chromatography on silica gel in the presence of a developing solvent to obtain a corresponding disubstituted urea compound, wherein the developing solvent is selected according to the thin layer chromatography condition and the polarity condition of the products. The synthesis method of disubstituted urea compounds has the advantages that the raw materials are simple and easily available; the catalyst is cheap, a conventional solvent is used, and air is used as an oxidizing agent; and the operation is simple, the yield is medium to excellent; therefore, the synthesis method has a good development prospect in industrial production.

The invention discloses a preparation method for 1,4-disubstituted-1,2,3-triazole derivatives, and belongs to the technical field of organic synthetic intermediates. According to the preparation method, any of the 1,4-disubstituted-1,2,3-triazole derivative is prepared by the following steps: adopting a cheap and readily available nitro compound as a raw material, performing reduction reaction on the nitro compound and a reducing agent at room temperature to obtain the compound I, performing oxidation reaction on the compound I and sodium nitrite to obtain a compound II, then performing azido reaction on the compound II and sodium azide to obtain a compound III, and finally performing reaction on the compound III and alkyne catalyzed by copper iodide, wherein the four reaction steps are continuous in operation, and intermediate products are free of separation. The preparation method has the advantages that the cost is low, the reaction efficiency is high and the operation is convenient, and can be used in industrial production; the synthesized compound contains a 1,2,3-triazole ring structure unit; the preparation method can be applied to synthesis and modification of the organic synthetic intermediates and drugs, and serve as a novel and efficient synthesis method for drug screening.

The invention discloses a blue-light-emitting double-core cuprous iodide complex luminescent material and a preparation method thereof. The blue-light-emitting complex is obtained by complexing cuprous iodide and ligand, and has a molecular structure of [CuI(DPPP)]2, wherein DPPP in the formula is electrically neutral P ligand-containing 1,5-di(diphenyl phosphine) pentane; two metal ion centers are combined by bridging ligand iodide ions to form a double-core structural molecule. The complex has the advantages that small molecules are easy to extract and high in luminous efficiency and has high thermal stability. The material is obtained by directly mixing and reacting the cuprous iodide and the dichloromethane solution of the ligand, and has the advantages of simple and convenient process, simple equipment, readily available raw materials, low cost and the like. The material can be used as a photoluminescent blue-light-emitting material, and can also be used as a blue-light material for a luminescent layer in an electroluminescent device consisting of a plurality of layers of organic materials.

The invention relates to a preparation method of a graphdiyne-like substance. The method includes: with cuprous iodide being a substrate, performing a coupling reaction to hexaalkynyl benzene under catalysis by the cuprous iodide in a solvent; removing the cuprous iodide with ammonia water through corrosion, and performing centrifugal separation and drying, and grinding the product to obtain the graphdiyne-like powder product. The method can prepare the graphdiyne-like substance at large scale, shortens the researching period of the graphdiyne in other fields, and makes the graphdiyne possibleto be applied to other fields.

The invention relates to a preparation method of an antidepressant drug Vortioxetine, which belongs to the technical field of pharmaceutical chemicals. According to the method, by taking water as a solvent, a compound 2,4-dimethylbenzenethiol shown in a formula (4), a compound 2-bromoiodobenzene shown in a formula (3) and a compound piperazine shown in a formula (2) react with copper iodide, a phase transfer reagent and alkali in an aqueous solution so as to obtain a compound shown in a formula (1). The method disclosed by the invention is easily-obtained in raw materials and simple in process; and one-pot reaction operation can be performed, and water is taken as a solvent, so that the method is green and environmental-friendly, and facilitates the industrialized production of the bulk drug.

The invention relates to a trivalent gold complex. The general chemical formula of the trivalent gold complex is MAuL, wherein M refers to 2,6-diphenyl pyridine or 2,6-bis(4-tertiary butyl phenyl) pyridine, L refers to phenylacetylene or 3,6-2-tertiary butyl-9-(4-acetenyl phenyl)-9H-carbazole. A preparation method comprises the steps that a chlorine gold (III) precursor and L are dissolved in a mixed solution formed by cuprous iodide, dichloromethane and triethylamine, stirring is carried out for 6 h to 12 h at room temperature, and after the reaction is finished, the reaction product is purified to obtain the trivalent gold complex. The trivalent gold complex achieves visible-light responses, and is a catalyst capable of fast reducing water to prepare hydrogen.

The invention belongs to the technical field of coordination chemistry and particularly relates to an indium-potassium-copper three-metal coordination polymer crystal and a preparation method and application thereof. The molecular formula of the indium-potassium-copper three-metal coordination polymer crystal is [InKCu2I2C42H58N10O14]n, n is a positive integer, the crystal belongs to a monocliniccrystal system, and the space group is P21 / c. According to the crystal, the used raw materials of niacin, indium nitrate, copper iodide and potassium iodide are simple and easy to obtain, the raw materials and N,N'-dimethylformamide react under a solvent heat condition, the indium-potassium-copper three-metal coordination polymer crystal with green fluorescence performance is obtained, the preparation method is simple, and the synthesis cost is low.

The invention discloses a pyridyl phosphine ligand based cationic trinuclear cuprous iodide cluster compound green phosphor material and a preparation method thereof. The phosphor cluster compound is prepared by complexing a cuprous salt and a ligand and has a molecular structure of [(Cu3I2)(DPPY)3]PF6, wherein DPPY in the structure formula is diphenyl-2-pyridyl phosphine which is an electrically neutral phosphine ligand. The cluster compound has such advantages of a micromolecular compound as easiness in purification and high luminous efficiency and further has a high heat stability. The material is prepared by enabling an acetonitrile solution of CuI to be subjected to mixing reaction with a dichloromethane solution of DPPY and a dichloromethane solution of Cu(CH3CN)4PF6 step by step; the preparation method is simple and convenient in process and simple in equipment, adopts easily available raw materials and is low in cost. The material can be used as a photoluminescent green-light material and can also be used as a luminescent-layer phosphor material in an electroluminescent device comprising multiple layers of organic materials.

The invention discloses benzoxazole pyridine-based orange phosphorescent CuIN2P-type copper complex luminous material and a preparation method thereof. The phosphorescent complex of the invention is obtained by coordination reaction of copper iodide and a ligand and has a molecular structural formula: CuI(2-PBO)(o-Tol3P), wherein 2-PBO and o-Tol3P are respectively electrically-neutral ligands 2-(2-benzoxazole)pyridine and tris(o-methylphenyl)phosphine. The complex has small-molecular purification easiness and high luminous efficiency and is also easy to dissolve with an organic solvent. This material is obtained by directly mixing and reacting copper iodide and a ligand solution and has the advantages such as process simplicity, equipment simplicity, easy access of materials and low cost. This material may be used as a photoluminescent orange luminous material and may also be used a luminous layer phosphorescent material in an electroluminescent device composed of multilayer organic material.

The invention discloses a method of preparing a dilactone type pinoresinol precursor under the existence of cuprous iodide and a molecular sieve through directly promoting a one-step reaction between vanillin and maleate by utilizing metal samarium. The vanillin and the maleate are mixed and dissolved, under stirring, into tetrahydrofuran dehydrated and dried in advance, and then the metal samarium powder, the cuprous iodide powder and the molecular sieve are added into the mixture in order. A reaction system is performed under a condition of absolutely no water. The mixture is stirred at room temperature until the reaction is finished. The obtained reaction mixed solution is subjected to solvent recovery, and a residue is subjected to after-treatment and chromatographic column separation to obtain a high-purity product of the dilactone type pinoresinol precursor.

The invention discloses a synthetic method of 2-substituted benzoxazole. The synthetic method comprises the following steps: adding reaction substrates namely benzene halide, benzoxazole and 1-3-dimesitylimidazol-2-subunit and an organic solvent into a reaction device, uniformly mixing, adding a mixture of 0.1-1wt% of a catalyst cobalt acetate and cuprous iodide, adding cesium carbonate to adjust reaction liquid to be alkaline, heating to 140-160 DEG C, and reacting for 6-10 hours to generate 2-substituted benzoxazole. According to the synthetic method of 2-substituted benzoxazole disclosed by the invention, the yield of obtained 2-substituted benzoxazole is more than 92%; the method is mild in reaction condition, environmentally friendly, high in yield and easy in industrial production.