The invention discloses a high-performance prestressing duct grouting agent which is prepared by the following components, by weight, 1-10% of water reduction component, 15-40% of water retention component, 1-10% of plastic-reserving component, 0.03-0.3% of tackifying component, 0-0.5% of delayed coagulation component, 0.1-1% of plasticity expansion component and 50-70% of later-stage volume expansion component. By mixing the high-performance prestressing duct grouting agent into cement according to a ratio of 10%, grout can obtain high mobility and high plasticity stability, a segregation layering phenomenon is greatly reduced, bleeding is avoided, and grouting is full. Whole-process volume stability of the prepared grout is high, micro expansion of plasticity and hardening stages can effectively compensate various contractions. Early strength and high-strength performance of the grout are prominent, durability is good, and the grout is applicable to various prestressing duct constructions. Simultaneously, bag-packaged additives are even in composition compared with additives prepared on the spot, transportation and comprehensive cost is low, and technical economical benefit is remarkable.