The invention relates to a positive
electrode-
solid electrolyte integrated structure, a preparation method and a
solid-state battery, belongs to the technical field of
solid-state batteries, and aims to solve the problems that the solid-state battery is poor in cycle performance and poor in reliability due to the fact that an interface between a solid
electrolyte and an
electrode material is unstable, low in
ion transport
kinetics and relatively high in
interface impedance in an existing method. And the
energy density is low. According to the preparation method, the
aluminum element is doped by adopting an electrochemical method, the
controllability of the preparation material is realized, the carbon-coated
sodium-rich aluminum-doped
titanium sodium phosphate is prepared by adopting the electrochemical method, high-temperature
sintering preparation is avoided, the energy is saved, the product purity is high, and the preparation method is simple; the oxidation thickness is controlled by controlling
pulse current, temperature and time, so that the thickness of the solid
electrolyte is controlled, and the solid electrolyte with a certain thickness is prepared. The positive
electrode and the solid electrolyte are prepared into an integrated structure without a contact interface, so that the interface
contact resistance is greatly reduced, the cycle performance and the rate performance are excellent, and the
energy density of the battery is improved.