The invention discloses a preparation method of hollow
oxide microspheres. The preparation method includes the following steps that 1, carbon spheres serve as templates, the surfaces of the carbon spheres adsorb water, then, the carbon spheres are dispersed in
solvent with the coordination effect with
metal alkoxide, and carbon sphere template suspension is obtained; 2,
metal alkoxide is added into the carbon sphere template suspension, the
solvent with the coordination effect with
metal alkoxide is added to enable the concentration of
metal alkoxide to be 0.05-0.5 mol / L, and stirring reaction is conducted; 3, after a solution obtained in the step 2 is subjected to high-temperature and high-pressure reaction, and through washing and separation, C /
oxide microspheres with core-shell structures are obtained; 4, after the C /
oxide microspheres obtained in the step 3 are dried and subjected to heat treatment, the hollow oxide microspheres are obtained. According to the preparation method of the hollow oxide microspheres, the
solvent with the coordination effect is adopted, the water is limited to the surfaces of the carbon spheres, the quantity of homogeneous
nucleation can be greatly reduced, the thicknesses of the shell
layers of the hollow oxide microspheres are effectively controlled, and the preparation method of the hollow oxide microspheres has good application prospects.