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51results about How to "Grafting is firm" patented technology

Organic/inorganic hybridization solar cell based on zinc oxide (ZnO) homogeneous core-shell structure nanorod array and production method thereof

The invention discloses an organic / inorganic hybridization solar cell and a production method thereof, wherein a zinc oxide (ZnO) nanorod array ZnO-sodium (Na) which is vertically grown on an indium tin oxide (ITO) lining base is utilized as a template, a nanorod array ZnO-natural rubber (NR)-quantum dot (QD)-NA which takes a ZnO nanorod as a core and a polycrystal film which consists of ZnO quantum dots as an inorganic finishing shell layer is prepared, an organic matter N719 is utilized to modify the ZnO-NR-QD-NA, so a homogeneous core-shell structure nanorod array ZnO-NR-QD-N719-NA which is modified by the N719 is obtained, a polymer and the ZnO-NR-QD-N719-NA are compounded to produce a finished product, the open-circuit voltage of the cell reaches 0.62V, the short-circuit current of the cell is 3.79mA / cm<2>, and the conversion efficiency of the cell reaches 0.84%. Compared with a phenylacetylene (MEH-PPV) / ZnO-NA cell, the open-circuit voltage of the cell is improved by 88%, the short-circuit current is increased by 192%, and the conversion efficiency is improved by 425%.
Owner:INST OF PLASMA PHYSICS CHINESE ACAD OF SCI

Preparation method of alkylated modified graphene

The invention discloses a preparation method of alkylated modified graphene. Graphite oxide is used as a raw material, in the process of preparation of graphene with a reduction method, graphene oxide obtained through cleavage is subjected to graft modification by the aid of a modifier containing an alkyl chain in a molecular chain and then is reduced, and alkylated modified graphene is obtained. According to the preparation method of alkylated modified graphene, graphite oxide is used as the raw material, the alkyl chain is grafted during peeling, and then an alkylated modified graphene product with the high grafting rate is obtained through reduction. For example, if octadecylamine is used as the modifier, the grafting rate is deduced according to the content of N, and the content of N can be up to 1.5wt%; if a silane coupling agent KH560 is used as the modifier, the grafting rate is deduced according to the content of Si, and the content of Si can be up to 2.9wt%; if a silane coupling agent KH560 is used as the modifier, the grafting rate is deduced according to the content of Si, and the content of Si can be up to 2.8wt%.
Owner:THE SIXTH ELEMENT CHANGZHOU MATERIALS TECH

Hardening liquid and preparation method thereof

InactiveCN113308143AFully dispersedFully grafted on the surface in dispersed statePolyurea/polyurethane coatingsEpoxy resin coatingsArylPolymer science
The invention discloses a hardening liquid. The hardening liquid comprises the following components in percentage by mass: 1-70% of modified inorganic nanoparticles, 30-99% of curable resin or oligomer, 0-5% of an additive and 0-65% of a solvent, the modified inorganic nano particles comprise inorganic nano particles and surface grafting modified chain segments bonded with the inorganic nano particles; the surface grafting modified chain segment comprises at least one polymerizable group; and the surface grafting modification chain segment is bonded with the inorganic nano particles through a-SiR1R2-group and / or-R1OTiOR2-group, wherein R1R2 is at least one of alkyl, alkoxy, alkynyl, aryl, acrylic acid group, ester group, ether group and carboxyl. According to the hardening liquid, the usage amount of the dispersing agent can be reduced, even the inorganic nano particles can be stably dispersed without adding the dispersing agent, and a coating of the hardening liquid has good mechanical performance.
Owner:广东海浦倍尔新材料有限公司

Color-absorbing fiber and method for preparing color-absorbing nonwoven fabric

The invention discloses a preparation method of dye-absorption fibers. The preparation method of the dye-absorption fibers comprises the steps that a cationic cellulose ether aqueous solution with the concentration of 5g / L-100g / L is prepared, an alkali compound is added to the cationic cellulose ether aqueous solution to adjust the pH value to be 11-13, viscose is put into the cationic cellulose ether aqueous solution to be reacted for 15-60 minutes at the temperature of 80-100 DEG C, and poly quaternary ammonium salt viscose is obtained; the poly quaternary ammonium salt viscose is taken out and dried, and then the dye-absorption fibers are obtained. The invention further provides a preparation method of dye-absorption non-woven cloth. The preparation method of the dye-absorption non-woven cloth comprises the steps that the dye-absorption fibers are provided; lapping is carried out on the dye-absorption fibers; net fixation is carried out on the dye-absorption fibers after lapping, and the cloth is obtained. By means of the preparation method of the dye-absorption fibers and the preparation method of the dye-absorption non-woven cloth, dye-absorption non-woven cloth with high absorption force and tearing resistance can be prepared.
Owner:上海希丝无纺布制品有限公司

Permeable closed amphoteric emulsion for primer and preparation method thereof

InactiveCN111234082AStrong anti-salinity performanceFine particle sizePriming paintsButyl acrylateGlycidyl methacrylate
The invention discloses a permeable closed amphoteric emulsion for a primer. The amphoteric emulsion is prepared from the following raw materials in parts by weight: 50 to 110 parts of deionized water; 10-60 parts of styrene, 5 to 20 parts of n-butyl acrylate; 5-20 parts of iso-octyl acrylate, 2-5 parts of an emulsifier, 2-5 parts of glycidyl methacrylate, 2-5 parts of dodecyl methacrylate, 2-5 parts of methyl erucate, 2-5 parts of a cationic monomer, 2-5 parts of an anionic monomer, 0.5-2.5 parts of a crosslinking monomer, 1-5 parts of a hydrophilic monomer and 0.5-2 parts of an initiator. The emulsion is zwitter-ionic amphoteric emulsion for permeable closed primer, and has excellent paint preparation stability, excellent permeation reinforcing performance and salt and alkali flooding resistance.
Owner:广东巴德富新材料有限公司

Environment-friendly and sterilization diatom ooze coating

The invention discloses environment-friendly and sterilization diatom ooze coating. The environment-friendly and sterilization diatom ooze coating comprises the following raw materials in parts by weight: 50-55 parts of natural diatom ooze, 15-20 parts of negative ion powder, 10-13 parts of sepiolite powder, 7-10 parts of a polylactic acid-chelated silver ion sterilization agent, 7-9 parts of vermiculite powder, 3.2-3.6 parts of a toughening agent, 1.2-1.5 parts of an emulsifying agent, 1.2-1.5 parts of a curing agent, 1.4-1.7 parts of a de-foaming agent, 1.3-1.6 parts of a leveling agent, 0.7-1 part of a leveling auxiliary agent, 0.8-1.2 parts of a mildew-proof agent, 1.8-2.2 parts of a dispersant, 1.2-1.5 parts of a film-forming auxiliary agent and 55-60 parts of de-ionized water. The environment-friendly and sterilization diatom ooze coating disclosed by the invention has a good sterilization performance, is environmentally friendly and durable and is good indoor coating.
Owner:TIANCHANG YINHU PAINT

Cyanuric chloride-based quaternary ammonium salt compound and preparation method thereof

The invention relates to a cyanuric chloride-based quaternary ammonium salt compound and a preparation method thereof. The preparation method comprises the following steps of 1, stirring cyanuric chloride and 3-aminopropyltriethoxysilane in an organic solvent at a temperature of 0-5 DEG C for a reaction for 3-5h, 2, heating the system obtained by the step 1 to 25-40 DEG C, carrying out stirring for 10-15min, adding triethylamine into the system, and sequentially carrying out stirring reaction for 8-12h to obtain a flavescent suspending liquid, and 3, carrying out centrifugal separation on the flavescent suspending liquid obtained by the step 2 to obtain flavescent solids, carrying out washing 3-5 times by an organic solvent and carrying out vacuum drying at a temperature of 60-90 DEG C to obtain the cyanuric chloride-based quaternary ammonium salt compound. Compared with the common quaternary ammonium salt compound, the cyanuric chloride-based quaternary ammonium salt compound has high charge density and can be stably grafted to the material surface by covalent bond effects. The preparation method does not need other assistants, utilizes cheap and easily available raw materials, has mild reaction conditions and can be operated conveniently.
Owner:SHANGHAI UNIV OF ENG SCI

Modified inorganic nanoparticles and preparation method thereof

The invention discloses a modified inorganic nano particle. The modified inorganic nano particle comprises an inorganic nano particle and a surface grafting modification chain segment bonded with the inorganic nano particle, the surface grafting modified chain segment comprises at least one polymerizable group; the surface grafting modification chain segment is bonded with the inorganic nano particles through a -SiR1R2-group and / or-R1OTiOR2-group; wherein R1R2 is at least one of alkyl, alkoxy, alkynyl, aryl, acrylic acid group, ester group, ether group and carboxyl. When the modified inorganic nanoparticles are used in the hardening liquid, the use amount of a dispersing agent can be reduced, even the inorganic nanoparticles can be stably dispersed without adding the dispersing agent, so that the negative influence of the dispersing agent, especially a macromolecular dispersing agent, on the hardening effect of the inorganic nanoparticles in a coating can be effectively reduced; and meanwhile, the mechanical property of the coating can be effectively improved.
Owner:广东海浦倍尔新材料有限公司

Photocatalysis active carbon fiber and preparation method thereof

The invention relates to the field of active carbon, and specifically relates to a photocatalysis active carbon fiber and a preparation method thereof. The preparation method comprises the following steps: in a vacuum microwave environment, spraying an atomized coupling agent on active carbon fibers, then soaking active carbon fibers in a nano titanium dioxide solution to graft nano titanium dioxide onto active carbon fibers, and drying the active carbon fibers to obtain the photocatalysis active carbon fiber. According to the preparation method, nano titanium dioxide with a high visible-light catalytic activity is grafted onto the active carbon fibers, and thus the active carbon fiber has an adsorption performance and also has a visible light catalyzing performance. The preparation method is simple, the preparation cost is low, and the prepared photocatalysis active carbon fiber has an excellent performance, and has an important meaning for promoting the application and development of organic matter decomposition.
Owner:江苏盛世基业环保科技有限公司 +1

Preparation method for antibacterial and anti-pollution polymer separation membrane based on surface grafting

InactiveCN107694358ASustained antibacterial effectSustained high-efficiency antibacterial and anti-pollution effectSemi-permeable membranesMembranesAtom-transfer radical-polymerizationElectron transfer
The invention relates to a preparation method for a polymer separation membrane with high-efficiency persistent antibacterial and anti-pollution effects, and belongs to the scientific and technical fields of water treatment and membrane separation. According to the invention, through an electron transfer activation regeneration catalyst atom transfer free radical polymerization method, a quaternary ammonium salt is grafted at the surface of the polymer separation membrane, so that the anti-pollution performance of the polymer separation membrane can be effectively improved, the polymer separation membrane modified by the method has obvious inhibiting effects on reproduction of bacteria and microorganisms and good antibacterial performance, and the modified membrane has good separation performance and long-term stable antibacterial and anti-pollution effects. The method is simple in process, green and environmentally friendly, and the method can be operated under the lower content of acatalyst; and the polymer separation membrane has stronger operability in practical industrial production and potential and wide application value in the field of water treatment.
Owner:TONGJI UNIV

High-tenacity and shock-proof bactericidal diatom ooze coating

The invention discloses high-tenacity and shock-proof bactericidal diatom ooze coating, which comprises the following raw materials in parts by weight: 40 to 50 parts of nature diatomite, 14 to 16 parts of negative ion powder, 8 to 12 parts of polylactic acid chelated silver ion bactericide, 12 to 15 parts of light calcium carbonate, 9 to 12 parts of bentonite, 5 to 8 parts of talcum powder, 1.8 to 2.2 parts of dispersing agent, 1.2 to 1.5 parts of coalescing agent, 1.5 to 1.8 parts of emulsifier, 3 to 6 parts of pigment, 1.6 to 1.9 parts of wetting agent, 1.1 to 1.5 parts of smoothing agent, 1.4 to 1.7 parts of smoothing assistant, 1.6 to 1.9 parts of defoamer and 60 to 65 parts of deionized water. The high-tenacity and shock-proof bactericidal diatom ooze coating disclosed by the invention has good bactericidal performance, is environmental friendly and durable, and is good indoor coating.
Owner:TIANCHANG YINHU PAINT

Photocatalyst active carbon floating sphere and preparation method thereof

The invention relates to the field of active carbon, and concretely relates to a photocatalyst active carbon floating sphere and a preparation method thereof. The method comprises the following steps: spraying active carbon particles with an atomized coupling agent in vacuum microwave environment, immersing the sprayed active carbon particles in a silver-doped nanometer titanium dioxide solution to make the active carbon particles be grafted with nanometer titanium dioxide, and drying the grafted active carbon particles to obtain the photocatalyst active carbon floating sphere. The active carbon floating sphere is grafted with the silver-doped nanometer titanium dioxide, so the active carbon floating sphere has an organic matter photocatalysis function in visible lights, and also has excellent adsorption ability. The preparation method has the advantages of simplicity and low preparation cost, and the photocatalyst active carbon floating sphere prepared in the invention has excellent performances, and is of great significance to promote the application and development in the sewage field.
Owner:张爱民

Method for preparing hydrophobic silica by virtue of fumed silica

The invention provides a method for preparing hydrophobic silica by virtue of fumed silica. The method comprises the following steps: performing a reaction between fumed silica and vinyl silicone oilto prepare silicon dioxide containing vinyl; mixing silicon dioxide with a mixture of methyl silicone oil and a Karstedt catalyst; adding tetramethyldisiloxane to react to obtain modified silicon dioxide; and finally, adding alpha-olefin to react, so as to obtain hydrophobic silica. According to the method, the treatment of hydroxy on the surface of fumed silica is relatively thorough; long-chainalkyl is grafted to the surface of fumed silica, so that the grafting rate is high, obtained long-chain alkyl surface-modified silicon dioxide has good hydrophobicity and hydrophobic stability and further has good consistency with organic matters (including materials mainly containing carbon chains).
Owner:SHANDONG DONGYUE ORGANIC SILICON MATERIAL

Organic photoelectric material and preparation method thereof

The invention relates to an organic photoelectric material and a preparation method thereof. The organic photoelectric material is prepared from diisobutyronitrile, polyol, conductive carbon fibers, a hydrophilic chain extender, a photoelectric conversion material and a compatilizer. A large amount of carboxyl is enriched on the surface of the conductive carbon fiber; a chain of a polyurethane prepolymer further comprises an epoxy group, so that the polyurethane prepolymer has viscosity, after a polyurethane high-molecular compound is grafted on the conductive carbon fiber, a photoelectric conversion material is coated between the polyurethane prepolymer and the conductive carbon fiber, then the polyurethane prepolymer is subjected to chain extension, the polyurethane material is modified through the conductive carbon fiber, the conductive carbon fiber provides current carriers to conduct electricity and promote the photoelectric conversion effect, the polyurethane firmly bonds the photoelectric conversion particles together, photoelectric conversion is carried out through the photoelectric conversion material, and the effective photoelectric conversion effect is achieved.
Owner:NORTHWESTERN POLYTECHNICAL UNIV

High-performance ceramic-based epoxy modified organic silicon coating material, preparation method and application method thereof

The invention relates to a high-performance ceramic-based epoxy modified organic silicon coating material, which is characterized in that a boehmite modified epoxy resin, an epoxy modified organic silicon resin and a curing agent are selected as main components, and a ceramic-based resin is gradually formed in a resin curing and cross-linking process, so that high hardness and wear resistance of the epoxy modified organic silicon coating material are realized, and the coating material has excellent oil resistance and high-temperature resistance. According to the invention, the ceramic-based epoxy modified organic silicon coating material has the advantages of simple construction, no need of complex equipment, good film-forming property of the prepared material, and high adhesive force; and by applying the ceramic-based epoxy modified organic silicon coating material, the scratch-resistant protection and corrosion protection effects on equipment can be realized, and the coating can also be widely applied to high-temperature protection of facilities such as chimneys, hot pipelines and the like, and has relatively high economic benefits.
Owner:725TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Preparation method of fibrilia antibacterial functional material

The invention provides a preparation method of a fibrilia antibacterial functional material. The method comprises the following steps of soaking fibrilia in a tannic acid aqueous solution for a first reaction to obtain pre-modified fibrilia; and carrying out a second reaction on the pre-modified fibrilia, metal ions and organic amine to obtain the fibrilia antibacterial functional material. According to the invention, firstly, tannic acid is grafted on the surface of the fibrilia through hydrogen-bond interaction; after primary grafting of the tannic acid is completed, an aqueous solution of the metal ions and the organic amine is dropwise added under the ultrasonic action for further crosslinking, so that chelating bonds are formed between free phenolic hydroxyl groups of the tannic acid and the metal ions as well as between the metal ions and the organic amine, and the tannic acid is more firmly and uniformly grafted on the surface of the fibrilia; and due to the introduction of the organic amine, the distance between tannic acid and metal ion complexes is increased, uniform and firm grafting on the surface of the fibrilia is realized, and the application environment adaptability of the tannic acid grafted fibrilia is enhanced.
Owner:INST OF BAST FIBER CROPS CHINESE ACADEMY OF AGRI SCI

Starch-based polyacrylic acid magnetic adsorption material as well as preparation method and application thereof

The invention discloses a starch-based polyacrylic acid magnetic adsorption material and a preparation method and application thereof. The preparation method comprises the following steps: preparing Fe3O4 magnetic micro-nano particles through a coprecipitation method, and modifying the Fe3O4 magnetic micro-nano particles to obtain modified Fe3O4 micro-nano particles; mixing a pretreated starch base material, an acrylic monomer, tetrahydrofuran, an initiator and divinyl benzene, and conducting reacting under a vacuum condition to obtain a starch base material; and mixing the modified Fe3O4 micro-nano particles, the starch base material and polyacrylic acid for reaction to obtain the starch-based polyacrylic acid magnetic adsorption material. The preparation method is simple in process; used reagents are common drugs which can be purchased on the market, so cost is low, and operability is high; the starch raw material adopted in the preparation process is pollution-free to the environment and easy to obtain, and polymerization conditions are simple; the adopted magnetic particles are beneficial to subsequent recovery, and secondary pollution is not prone to being generated; and preparation conditions are convenient, economic benefits are produced, and production on a large scale can be realized.
Owner:XIAN UNIV OF TECH

Polypropylene fiber reinforced lipophilic modification method

ActiveCN110886087BStable and reliable lipophilicityLow costFibre typesPolymer sciencePolymer chemistry
The invention belongs to the technical field of material modification, and specifically relates to a method for reinforcing lipophilic modification of polypropylene fibers, which uses molecular self-assembly technology and chemical graft copolymerization technology to strengthen the lipophilic performance of polypropylene fibers. The method comprises the following steps: 1) performing sulfuric acid immersion treatment on raw material polypropylene fibers to obtain microporous polypropylene fibers; 2) performing gradient hydrogen peroxide solution immersion treatment on microporous polypropylene fibers to obtain hydroxyl-modified polypropylene fibers; Assembled to obtain amino-modified polypropylene fibers; 4) based on chemical graft copolymerization technology, combined with silane coupling agent, to obtain reinforced lipophilic modified polypropylene fibers. The invention improves the affinity performance and storage function of the interface to the organic phase by reserving microporous structure and grafting hydrophobic hyperbranched polymer on the surface of the polypropylene fiber, and obviously improves the lipophilic property of the polypropylene fiber.
Owner:EAST CHINA UNIV OF SCI & TECH

High polymer material for surface high-gloss injection molding

The invention relates to the field of high polymer materials, in particular to a high polymer material for surface high-gloss injection molding. The high polymer material comprises the following components in parts by weight: 50-80 parts of low-density polyethylene, 20-40 parts of polyoxyethylene, 10-15 parts of modified glass fiber, 2-8 parts of a light stabilizer, 1-10 parts of an antioxidant and 3-10 parts of a pigment. The high polymer material of the invention solves the problem that polyethylene serving as a novel environment-friendly material is relatively excellent in various properties, but relatively poor in glossiness and cannot meet the demands of people. According to the high polymer material for surface high-gloss injection molding provided by the invention, the combination of low-density polyethylene and polyoxyethylene can greatly reduce the cost of the material and enhance the market competitiveness of the material; and the modified glass fiber is added, so the glossiness of the material can be greatly improved, related use requirements are met, and the high polymer material has wide market prospects and commercial values.
Owner:广州红象科技有限公司

Preparation method of organic sericite for anticorrosive coating

The invention discloses a preparation method of organic sericite for an anticorrosive coating. The preparation method comprises the following steps that sericite and organic epoxy resin are mixed, themixture is added into a ball mill to be subjected to high-temperature ball milling, the temperature is controlled to range from 160 DEG C to 200 DEG C, the rotating speed is controlled to range from400 r / min to 600 r / min, and the time ranges from 3 h to 6 h; centrifuging, suction filtration and drying are performed the obtained product to obtain surface organic sericite powder; organic sericitepowder is mixed with epoxy resin, a diluent and an additive to be mechanically stirred to obtain a component A, and the component A is mixed with a component B curing agent to obtain the sericite anticorrosive coating with an organic surface. The process flow is simplified, the reaction time is shortened, and the method is environmentally friendly, high in automation degree, firm in surface grafting and suitable for industrial mass production.
Owner:NORTHEASTERN UNIV

Preparation method of chitosan oligosaccharide grafted cellulose fiber

The invention relates to a preparation method of chitosan oligosaccharide grafted cellulose fiber. The preparation method comprises following steps: A, preparation of sodium methallyl sulfonate-chitosan, wherein chitosan oligosaccharide is added into hot water to prepare a chitosan oligosaccharide aqueous solution, the chitosan oligosaccharide aqueous solution is cooled to room temperature, sodiummethallyl sulfonate is added into the chitosan oligosaccharide aqueous solution, an obtained mixture is subjected to stirring and heating, and potassium persulfate is added so as to obtain the sodiummethallyl sulfonate-chitosan oligosaccharide solution; B, cellulose fiber pretreatment, wherein cellulose fiber and soft water are introduced into a pretreatment tank, heating, stirring, water discharging, dehydration, and drying are carried out so as to obtain pretreated cellulose fiber; and C, preparation of chitosan oligosaccharide grafted cellulose fiber, wherein the cellulose fiber obtainedin step B is introduced into a reaction vessel, the sodium methallyl sulfonate-chitosan oligosaccharide solution obtained in step A is added, water is added, and stirring, heating, and centrifugal dewatering are carried out so as to obtain the chitosan oligosaccharide grafted cellulose fiber.
Owner:HMEI THREAD CO LTD OF YINBIN SICHUAN

Preparation method of cellulose antibacterial material modified based on natural active component chlorogenic acid

The invention discloses a preparation method of a cellulose antibacterial material modified based on a natural active component chlorogenic acid, which comprises the steps of dissolving cellulose in amixed aqueous solution of sodium hydroxide and urea to prepare a cellulose solution; adding anhydrous sodium sulfate into the obtained cellulose solution, stirring, and freezing until the cellulose solution is solidified; soaking the solidified mixture in water until the material floats on the water surface to obtain a cellulose material; mixing the cellulose material with a sodium hydroxide aqueous solution and epoxy chloropropane, and then cleaning the cellulose material with deionized water until the sodium hydroxide aqueous solution and the epoxy chloropropane have no residue; and takingout the cellulose material, a sodium carbonate solution and a chlorogenic acid ethanol solution, and washing the cellulose material with water until the cellulose material is not decolorized to obtainthe chlorogenic acid modified cellulose antibacterial material. The chlorogenic acid and the cellulose are covalently connected by adopting the epoxy chloropropane, so that the antibacterial agent can be more stably grafted on the surface of the cellulose, the antibacterial agent is prevented from falling off, and a good antibacterial effect is kept for a long time.
Owner:JIANGSU UNIV OF SCI & TECH

A kind of nano particle sandwich composite material and preparation method thereof

The invention relates to the technical field of nanocomposite materials, in particular to a nanoparticle sandwich composite material and a preparation method thereof, which consists of the following raw materials in parts by weight: 40-50 parts of diisocyanate; alcohol containing epoxy groups 120‑180 parts; 5‑10 parts of single-walled single-walled carbon nanotubes; 15‑35 parts of electrode materials. The present invention oxidizes single-wall carbon nanotubes to obtain oxidized single-wall carbon nanotubes with a large amount of carboxyl groups on the surface. The present invention also prepares polyurethane prepolymers containing epoxy groups, and then combines the polyurethane prepolymers with After the oxidized single-walled carbon nanotubes undergo amidation reaction, the polyurethane prepolymer surrounds the single-walled carbon nanotubes, and then the electrode material is adhered on the polyurethane prepolymer. The present invention uses the polyurethane prepolymer and the single-walled carbon nanotube Carbon nanotubes work together to increase the rate of charge and discharge, and efficient energy storage is achieved through single-walled carbon nanotubes and transition metal oxides.
Owner:XIAN TECH UNIV

A kind of quaternary ammonium salt compound based on cyanuric chloride and preparation method thereof

The invention relates to a cyanuric chloride-based quaternary ammonium salt compound and a preparation method thereof. The preparation method comprises the following steps of 1, stirring cyanuric chloride and 3-aminopropyltriethoxysilane in an organic solvent at a temperature of 0-5 DEG C for a reaction for 3-5h, 2, heating the system obtained by the step 1 to 25-40 DEG C, carrying out stirring for 10-15min, adding triethylamine into the system, and sequentially carrying out stirring reaction for 8-12h to obtain a flavescent suspending liquid, and 3, carrying out centrifugal separation on the flavescent suspending liquid obtained by the step 2 to obtain flavescent solids, carrying out washing 3-5 times by an organic solvent and carrying out vacuum drying at a temperature of 60-90 DEG C to obtain the cyanuric chloride-based quaternary ammonium salt compound. Compared with the common quaternary ammonium salt compound, the cyanuric chloride-based quaternary ammonium salt compound has high charge density and can be stably grafted to the material surface by covalent bond effects. The preparation method does not need other assistants, utilizes cheap and easily available raw materials, has mild reaction conditions and can be operated conveniently.
Owner:SHANGHAI UNIV OF ENG SCI

A paper-based gypsum board with high strength and low absorption

The invention discloses a paper gypsum board with high strength and low absorbability, and relates to the technical field of gypsum material. The paper gypsum board is prepared by compositing of an intermediate base layer and surface protective paper at the outer side. The intermediate base layer is a gypsum board layer. The prepared light-weight high-strength gypsum board has excellent strength and low water absorption.
Owner:湖南腾飞普天声学建材科技有限公司

A kind of preparation method of modified graphene and slurry containing the modified graphene

The invention provides a modified graphene and a preparation method containing the modified graphene slurry as follows: take flake graphite powder, modifier, distilled water and boric acid solution and place them in a stainless steel high-pressure bottle, and put them in a stainless steel high-pressure bottle Fill with liquid gas, shake well and let stand. Connect the stainless steel high-pressure bottle to the solid gas preparation machine to prepare solid gas. The solid gas is placed in an ultraviolet cleaning machine for high-energy ultraviolet irradiation, and a few layers or even a single layer of modified graphene is peeled off. After the solid gas completely disappears, the ultraviolet irradiation is continued for a period of time to prepare the modified graphene. The modified graphene continues to be exposed under the ultraviolet lamp, and the modified graphene is stored in a vacuum in the intermediate. Excellent, with surface functional characteristics, and at the same time bonded and grafted with nano-titanium and silicon to form a new titanium-silicon-modified graphene ternary composite material.
Owner:CHANGSHA TIANYUAN EMPIRE MATERIALS TECH CO LTD

PH-sensitive antioxidant nano-carrier and preparation method and application thereof

The invention relates to a preparation method of a pH-sensitive antioxidant nano-carrier. The preparation method comprises the following steps: (1) dissolving chitosan in distilled water to obtain a chitosan solution; (2) completely dissolving N-acetyl-L-histidine in dimethyl sulfoxide, and then adding N, N'-diimidazole; evaporating the solution to dryness after stirring, adding the chitosan solution and performing stirring, and performing freeze-drying after dialysis to obtain N-acetyl-L-histidine grafted chitosan; (3) taking coupling agents EDC and NHS, and adding N-acetylcysteine after uniform stirring to obtain carboxyl-activated N-acetylcysteine; and (4) mixing the N-acetyl-L-histidine grafted chitosan with the carboxyl-activated N-acetylcysteine, and then adding the mixture into a TEMED / HCI buffer solution; and reacting for 6-10h under magnetic stirring, performing dialysis by using a dialysis bag, and then carrying out freeze-drying treatment to obtain the pH-sensitive antioxidant nano-carrier. The antioxidant nano-carrier prepared by the invention can promote the survival of stem cells, and efficiently delivers and releases drugs in an acidic microenvironment in a targeted manner.
Owner:ZHUJIANG HOSPITAL SOUTHERN MEDICAL UNIV
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