The invention relates to the technical field of
sodium ion batteries, and discloses a diaphragm and a
sodium ion battery using the diaphragm, the diaphragm comprises a porous base membrane and a functional
coating coated on at least one surface of the porous base membrane; the functional
coating is prepared from the following raw materials in parts by weight: 85-95 parts of a
ferric sodium pyrophosphate active material, 4-10 parts of a binder and 1-5 parts of a conductive agent. In the
sodium ion battery, one side of the diaphragm, which is provided with the functional
coating, is arranged towards the positive
pole piece, and the coating is in
close contact with the positive pole through hot-pressing shaping. The high-proportion
ferric sodium
pyrophosphate is loaded on the diaphragm, and the sodium removal characteristic of the
ferric sodium
pyrophosphate during first-time charging is utilized, so that extra sodium ions are provided for the negative
electrode to compensate for consumption formed by an SEI film, and the first-time coulombic efficiency and
energy density of the battery are improved; meanwhile, high-temperature shrinkage of the base membrane is inhibited by utilizing a heat-resistant framework supporting effect of the coating, internal
short circuit of the battery is prevented, and the
thermal safety of the battery is enhanced.