The present application relates to the technical field of
electrode material, and particularly relates to a preparation method of seamless integrated
zinc negative
electrode material.In the present application, a three-dimensional porous structure vertical
graphene is constructed on the surface of a substrate, and the surface of the vertical
graphene is functionally treated to serve as a
zinc plating framework, so that
zinc is uniformly loaded on the surface of the substrate, and then a MOF protective layer is coated on the surface of the vertical
graphene, thereby obtaining the seamless integrated zinc negative
electrode material.In the present application, the surface
functional treatment introduces hydrophilic functional groups to the surface of the vertical graphene to enhance the interaction and uniform
electric field distribution;the introduction of the MOF protective layer does not destroy the surface morphology, and the thin and uniform MOF protective layer can also exclude large-size charged
ion complexes.