The invention relates to a technology for jointly extracting synephrine, hesperidin and PMFs (polymethoxy latednavones) from fructus aurantii immaturus. The technology comprises the following steps: a, smashing fructus aurantii immaturus, and subpackaging equal quantity of the smashed fructus aurantii immaturus in a percolation tank I and a percolation tank II respectively; adding a dilute acid solution in the percolation tank I, soaking, stirring and percolating; adding effluent liquid into the percolation tank II, soaking, stirring and percolating; mixing the leachate, performing vacuum concentration, adsorbing synephrine by a resin column, desorbing and collecting a desorption solution by using weak aqua ammonia, and performing vacuum drying to obtain dried synephrine; b, washing fructus aurantii immaturus dregs to be neutral with clear water, soaking with a dilute strong base solution, stirring, percolating, performing vacuum concentration, adding absolute methanol or absolute ethyl alcohol, performing still standing, filtering, performing vacuum concentration on the filtrate, and recycling alcohol to obtain a mother solution; c, adsorbing PMFs from the mother solution through the resin column and a chromatographic column, enabling methyl alcohol or ethyl alcohol to pass through the columns for desorbing under static pressure, collecting the stripping liquid, performing vacuum concentration, and recycling an eluent to obtain PMFs; acidizing the effluent liquid passing through resin, standing, and performing devitrification to obtain dried hesperidin.