The invention relates to a preparation method of
ricinoleic acid-based water-dispersible
isocyanate, which comprises the following steps: mixing
ricinoleic acid,
methoxypolyethylene glycol and p-toluenesulfonic acid monohydrate, heating in an
oil bath, and stirring to obtain an
intermediate product; extracting the
intermediate product to obtain a post-treated
intermediate product; and mixing the post-treated intermediate product and polyisocyanate, continuously stirring in a
nitrogen atmosphere, simultaneously heating in an
oil bath, and finally cooling to obtain the
ricinoleic acid-based water-dispersible
isocyanate. The preparation method has the following beneficial effects: bio-based ricinoleic acid (RA) and
methoxypolyethylene glycol (mPEG) are taken as raw materials, an intermediate mPEG (at) RA is synthesized through
esterification reaction, and then the intermediate mPEG (at) RA is crosslinked with polymethylene
polyphenyl isocyanate (PAPI), so that the water-dispersible
isocyanate crosslinking agent mPEG (at) RA (at) PAPI is successfully prepared, the
dispersion stability of isocyanate in a water-based
system is remarkably improved, and the water-dispersible isocyanate crosslinking agent mPEG (at) RA (at) PAPI has a good water-dispersible property. The dependence on
petrochemical raw materials is reduced, and the environment-friendly characteristic is realized.