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Preparation method for flexible and bendable aluminum ion battery

ActiveCN106450309AHigh mass densityHigh volume densityGraphiteCell electrodesAluminum IonFiber
The invention discloses a preparation method for a flexible and bendable aluminum ion battery. The preparation method comprises the steps of extruding graphene oxide or a graphene oxide inorganic salt mixed solution to rotary inorganic salt solution coagulating bath in spinning equipment with certain diameter; then filtering and collecting short fibers from the coagulating bath by a filtering net, and lapping joint the short fibers into graphene oxide cloth; reducing the obtained graphene oxide cloth in a reduction temperature to obtain graphene cloth; and then assembling the obtained graphene cloth positive electrode material, a diaphragm, a negative electrode, an electrolyte and a battery shell to obtain the aluminum ion battery taking the graphene cloth as the positive electrode material. The flexible and bendable aluminum ion battery is green, environment-friendly and low in cost, and suitable for continuous and controllable large-scale industrial production; under the premise of ensuring relatively high energy density, power density and cycle life of the aluminum ion battery, the flexibility and bendable property of the battery are realized; and the flexible and bendable aluminum ion battery is applicable to the field of high-safety wearable energy storage devices.
Owner:杭州德烯科技集团有限公司

Method for synthesizing monoclinic phase mesoporous bismuth vanadate through template method

The invention relates to a method for synthesizing monoclinic phase mesoporous bismuth vanadate through a template method. The method comprises the following steps of: mixing nitric acid, ethanol and bismuth nitrate which are weighed in a mass ratio of 1:(2.8-28):(0.2-1) by ultrasonic wave, so as to obtain a bismuth nitrate solution; mixing nitric acid, ethanol and ammonium meta-vanadate which are weighed in a mass ratio of 1:(2.8-28):(0.05-0.25) by ultrasonic wave, so as to obtain an ammonium meta-vanadate solution; dropping the ammonium meta-vanadate solution slowly into the bismuth nitrate solution, so as to obtain a mixed solution; adding silicon dioxide aerogel microspheres to be used as a template, evacuating in order to fully inject the mixed solution in the template, reacting for 6 hours to 24hours at the temperature of 60 DEG C to 110 DEG C, so as to obtain solid products; and finally, heating the solid products to 160 DEG C to 400 DEG C in a tube furnace at the heating rate of 0.5 DEG C per minute to 10 DEG C per minute, roasting for 2 hours to 24 hours, naturally cooling to room temperature, and then removing the template by using a sodium hydroxide solution to obtain the monoclinic phase mesoporous bismuth vanadate with average aperture distribution (1nm to 20nm). The method provided by the invention is simple and easy to control in process and is environment-friendly; and the monoclinic phase mesoporous bismuth vanadate obtained by the method has excellent photo-catalytic performance within the range of visible light.
Owner:TONGJI UNIV

Preparation method of 3D ordered macroporous polyaniline (OM PANI)/TiO2 composite photocatalytic material and application thereof

The invention belongs to a preparation method of a 3D ordered macroporous polyaniline (OM PANI) / TiO2 composite photocatalytic material and application thereof. The preparation method comprises the following steps: A, dipping 3-10g of prepared 3D OM PANI / TiO2 material in 50ml of a hydrochloric acid containing 0.05-0.5ml of an aniline monomer, and carrying out ultrasonic oscillation for 5-20 minutes; B, putting a reaction system in the step A into ice bath, dropwise adding a monomer initiator with the concentration of 0.25-1%, and reacting for 2-5 hours; C, washing a sample by adopting ethyl alcohol and / or diethyl ether, and washing the sample with distilled water; D, drying at the low temperature of 60-80 DEG C so as to obtain the sample. The 3D OM PANI / TiO2 composite material is used for combining the favorable conducting performance of PANI as well as characteristics of the relatively low energy gap with the TiO2 catalytic performance, meanwhile improves the defects that the photoproduction electron-hole recombination rate of a single TiO2 material is high and the visible light response is poor, and achieves the effects of improving the TiO2 photocatalytic quantum efficiency and reinforcing the visible light absorption; meanwhile, the material is at hundreds of nanoscales, is difficult to reunite, is easy to settle, and is good in regeneration performance.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Non-allergenic fully-degradable medical and hygienic non-woven material capable of adjusting moisture

The invention discloses a non-allergenic fully-degradable medical and hygienic non-woven material capable of adjusting moisture, and aims to solve the problem that the conventional degradable medical and hygienic materials are mainly made by a spunbonding method, and certain production processes are complex. The non-allergenic fully-degradable medical and hygienic non-woven material consists of the following raw materials of 60 to 80 mass percent of polylactic acid fibers and 20 to 40 mass percent of Tencel fibers and is prepared by the following steps of: preparing Tencel fiber non-woven paper by a wet laying method, wherein part of the Tencel fiber non-woven paper is fibrillated; pre-treating the polylactic acid fibers and preparing a polylactic acid fiber web; unreeling the non-woven paper on the polylactic acid fiber web once again, interweaving the fibrillated Tencel fibers with the polylactic acid fiber web by a high-pressure spraying method, and fibrillating the Tencel fibers further; and drying at proper temperature to bind the fibrillated Tencel fibers to the periphery of the polylactic acid fibers firmly. The non-allergenic fully-degradable medical and hygienic non-woven material has the characteristics of non-allergenic property and capacity of adjusting the moisture, and can be degraded fully after being discarded.
Owner:CHANGSHU GOLD SPRING CHEM FIBERS & KNITTINGS

Silicon-based triphenylamine derivative, preparation method thereof and application thereof in perovskite solar cell

The invention discloses a silicon-based triphenylamine derivative, a preparation method thereof and application thereof in a perovskite solar cell. In a chemical structural formula of the silicon-based triphenylamine, substituent groups are hydrogen, methyl, methoxyl, a methylthio group and a methylseleno group, and the substituent groups can be at any substitution site of a benzene ring. The silicon-based triphenylamine derivative material is not only simple in synthesis steps and has relatively high synthetic yield, and raw material cost is extremely low, a device preparation technology is simplified after the silicon-based triphenylamine derivative material is applied to a hole transport layer of a p-i-n type planar perovskite solar cell, and conversion efficiency of the solar cell alsocan be obviously improved, so that a good application prospect is shown; besides, it is worth mentioning that the silicon-based triphenylamine derivative disclosed by the invention has good crystallinity when m is equal to 0 and is not in an amorphous form, which is infrequent in other hole transport materials, and good crystallinity after annealing is beneficial to further improvement of hole transmission rate of the silicon-based triphenylamine derivative and increase of current of the solar cell and a fill factor.
Owner:SUZHOU UNIV +1

Preparation method of novel polyphenylene sulfone solvent-resistant nanofiltration membrane containing modified micropore spheres

The invention discloses preparation of modified micropore spheres on the basis of a ZIF-8 type metal-organic framework material and a preparation method for preparing a novel polyphenylene sulfone solvent-resistant nanofiltration membrane by applying the modified micropore spheres. The method comprises the steps that ZIF-8 nanoparticles grow inside macropore spheres and on the surfaces of the macropore spheres, and the modified micropore spheres are obtained; the modified novel micropore spheres are added to a polyphenylene sulfone membrane casting solution, and the novel polyphenylene sulfone solvent-resistant nanofiltration membrane containing the modified micropore spheres is prepared through an immersion-phase conversion method. The reparation method of the novel polyphenylene sulfone solvent-resistant nanofiltration membrane containing the modified micropore spheres has the advantages that nano-scaled porous structures of the modified micropore spheres are utilized for improving the pore structure of the polyphenylene sulfone membrane, large-size solute molecules in the organic solution are effectively intercepted, and fluid channels, facilitating solvent permeation, in the membrane are increased; when the addition ratio of the modified micropore spheres is 1.0 wt%, the membrane property is the best, and the permeation flux and interception rate can be increased simultaneously.
Owner:BEIJING FORESTRY UNIVERSITY

Finishing method of waterproof and moisture-permeable clothing fabric

The invention provides a finishing method of a waterproof and moisture-permeable clothing fabric. The finishing method includes the steps that silk fibroin powder, an initiator and acrylic acid are added into water in sequence to react to obtain a grafted modified silk fibroin dispersion solution, then chitosan, calcium chloride and deionized water are added and made into a thick solution, then atextile is pretreated with water glass liquid and then subjected to pad steam for two times accordingly through the thick solution to obtain a pre-finished fabric, then a foaming agent, a three-proofing finishing agent and acrylic ester emulsion are made into a finishing solution, the finishing solution is sprayed on the surface of the pre-dried fabric by ultrasonic atomization to form a coating,and thus the waterproof and moisture-permeable clothing textile fabric is obtained. According to the method, the acrylic grafted silk fibroin powder with excellent water absorption performance is fixed on fabric fibers, the requirements of moisture permeability and comfort for clothing fabrics are met, the finishing solution is sprayed on the fabric surface to form the firm coating with good micropores, moisture permeability is facilitated, and the waterproofness is good.
Owner:CHENDU NEW KELI CHEM SCI CO LTD

Leakproof humidifying composite hollow fiber membrane as well as preparation method and application thereof

The invention provides a leakproof humidifying composite hollow fiber membrane as well as a preparation method and application thereof. The leakproof humidifying composite hollow fiber membrane comprises an outer hydrophilic layer and an inner hydrophobic layer attached to the inner surface of the outer hydrophilic layer, the outer hydrophilic layer is of a spongy pore structure, the pore diameter of the outer hydrophilic layer becomes smaller from the outer surface to the inner surface, and the thickness of the inner hydrophobic layer of the leakproof humidifying composite hollow fiber membrane is smaller than that of the outer hydrophilic layer. According to the prepared leakproof humidifying composite hollow fiber membrane with the asymmetric structure of the inner hydrophobic layer and the outer hydrophilic layer, the thickness of the inner hydrophobic layer of the membrane is smaller than that of the outer hydrophilic layer, due to the fact that one side of the membrane is hydrophilic and the other side of the membrane is hydrophobic, the membrane shows asymmetric hydrophilic/hydrophobic dual performance, and the membrane is a novel membrane for humidifying treatment of a fuel cell; water molecule capture and permeation are facilitated, and meanwhile water vapor escape is facilitated.
Owner:江苏巨澜纳米科技有限公司

Preparation method for waterproof gas-permeable type textile polyurethane coating agent

InactiveCN108360264AIncrease moisture permeabilityImprove waterproof and breathable performanceFibre treatmentPrepolymerChemistry
The invention relates to a preparation method for a waterproof gas-permeable type textile polyurethane coating agent, and belongs to the technical field of coating agents. According to the technical scheme adopted by the invention, a keratin solution is prepared from feathers, and is polymerized with a polyurethane material; the coating agent is formed after the polyurethane material and keratin are polymerized, keratin is uniformly dispersed inside the material, and a continuous channel is formed in the modified coating layer, so that water vapor penetration is facilitated; the keratin solution can effectively promote the interface between the keratin and polyurethane to have a great number of seams, so that a novel moisture penetrating channel is formed, and therefore, moisture penetrating amount is remarkably improved, and waterproof gas-permeable performance of the coating agent is further improved. Keratin and polyurethane are polymerized, so that keratin loses water under a high-temperature environment, and heat resistance of a composite material is effectively improved; and meanwhile, in a preparation process, the polyurethane material is subjected to self-polymerization reaction, so that number of terminal groups of prepolymer is increased, and effective cross-linking density of the coating is improved, and therefore, a water pressure resistance value of the coating iseffectively increased, and washing distance and toughness of the coating are effectively improved.
Owner:常州五荣化工有限公司
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