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186results about How to "Process operation is stable" patented technology

Method of deep desalting and recycling of industrial effluent

ActiveCN102452751AGuaranteed uptimeAvoid the problem of susceptibility to incoming water organic contaminationGeneral water supply conservationMultistage water/sewage treatmentElectricityIndustrial effluent
The invention provides a method of deep desalting and recycling of industrial effluent. The method is characterized in that industrial effluent to be treated is treated with a hardness reducing operating unit, an efficient filtering operating unit and an electro-adsorption desalting operating unit to reach a standard of recycling water. The method comprises specific steps of: a. hardness reduction, precipitation and neutralization; b. efficient filtering; and c. electro-adsorption desalting. The provided method of deep desalting and recycling of industrial effluent requires no equipment of electroosmosis or reverse osmosis membrane, or ion exchange resin, keeps stable operation of the system under a condition of water quality conductivity higher than 2500 muS / cm and does not scale; and an outlet water quality satisfies water quality requirements on recycling water replenishment. Discharge secondary industrial effluent with water quality conductivity lower than 4500 muS / cm can be treated to reach water replenishment requirements of an industrial recycling water system. The method is suitable for chemical effluent, printing and dyeing effluent, spinning effluent and oil refining effluent and has wide water quality scope of application, stable technology operation and high desalting efficiency.
Owner:CHINA PETROLEUM & CHEM CORP

Method and device for refinery sludge carbonization treatment and carbon recovery

The invention relates to a method and device for refinery sludge carbonization treatment and carbon recovery. The method comprises the following steps: pre-treatment: heating oil-containing sludge to 160-180 DEG C in an external heating manner while isolating air, and ensuring that the water content of the oil-containing sludge is controlled at 20% or below; carbonization: carbonizing the oil-containing sludge at 600-650 DEG C for 30-45 minutes, and recovering the solid residue generated by carbonization; condensation and oil-water separation: collecting gas-phase products generated by pre-treatment and carbonization, condensing in a water spray manner to obtain carbonization liquid and non-condensable gas, and performing oil-water separation on the carbonization liquid to obtain carbonization oil; utilization of combustible gas: performing combustion treatment on the non-condensable gas, enabling high temperature generated by combustion to provide heat energy for pre-treatment and carbonization, and performing purification treatment on the tail gas before discharging. The invention also provides a device for realizing the method. According to the invention, the advantages of high oil content recovery rate and stable and reliable process operation are achieved.
Owner:ZHE JIANG ECO ENVIRONMENTAL TECH CO LTD

Ozone low-temperature oxidation denitration technology and system

The invention discloses an ozone low-temperature oxidation denitration system which comprises a flue, an ozone generator and a washing tower. The ozone low-temperature oxidation denitration system is characterized in that an ozone distributor is mounted in the flue; the ozone is supplied to an ozone channel of the ozone distributor through a pipeline at an outlet of the ozone generator; the ozone is jetted into the flue by the ozone distributor; the outlet of the flue is connected with the washing tower; the mixture of the ozone and exhaust gas in the flue enters into the washing tower. Compared with the prior art, the ozone low-temperature oxidation denitration system has the beneficial effects that the investment and running cost is lower than that of SCR (Selective Catalytic Reduction) technology; NOx removal rate is high and can reach 95% or more; the technique is simple, the expandability is excellent and the technological operation is simple, stable and reliable; the adaptation of the technical condition is wide; operation at low temperature is carried out and no high-temperature window is required; the system is free from ammonia escape secondary pollution and ammonium sulfate corrosion. The invention also discloses an ozone low-temperature oxidation denitration technology.
Owner:山东普莱斯玛环保设备有限公司

Method for preparing environment-friendly plasticizer by recycling waste resources

The invention relates to a method for preparing an environment-friendly plasticizer by recycling waste resources. The method comprises the following steps of transferring alkali-reduction wastewater containing sodium terephthalate into an acid precipitation tank with a stirring device and adding sulfuric acid to further precipitate terephthalic acid (PTA) solids; carrying out plate-frame filtration on the mixed solution to obtain a crude PTA material; adding the recovered crude PTA material into an esterification reactor with an alcohol-water separation device, adding iso-octanol, heating and dehydrating, adding tetrabutyl titanate as a catalyst and carrying out esterification reaction; after water is no longer produced, stopping reaction and dealcoholizing to obtain a crude DOTP (Dioctyl Terephthalate) product; rectifying the prepared crude DOTP product in a packing-type rectifying tower to obtain a rectified product, adding the rectified product into a neutralization reaction kettle, adding sodium hydroxide lye, stirring and washing with alkali; standing, precipitating and discharging the aqueous solution in the lower layer, adding hot water, stirring and washing with water, standing, precipitating and discharging the moisture in the lower layer, carrying out temperature-raising dehydration, adding an inorganic filter aid and filtering to obtain the pure DOTP product. By the method, the recycling of the waste resources is achieved.
Owner:INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY

Process for treating wastewater generated in solar silicon wafer production process

The invention discloses a process for treating wastewater generated in a solar silicon wafer production process and relates to wastewater treatment in the field of the electronic semiconductor industry. The process comprises the following steps of: pretreating wastewater in a preliminary sedimentation tank; carrying out Fenton and iron-carbon micro-electrolysis combined oxidization reaction on the wastewater in an iron-carbon micro-electrolysis reactor; after the reaction, feeding the wastewater into a coagulation-sedimentation integrated pool, feeding PAC (Poly Aluminium Chloride) and PAM (Poly Acryl Amide) to arouse the coagu-flocculation reaction of the wastewater, and after the reaction, performing sludge-water separation on the wastewater; causing the supernate to flow to a hydrolysis acidification pool, and then causing the wastewater to flow to a contact oxidation tank; causing the mixed liquid to flow to a secondary sedimentation tank for sludge-water separation, while causing the supernate to flow to a deflection sedimentation pool, and feeding PAC for purifying water so that the supernate is up to the stand and can be discharged after sedimentation; finally, performing concentration treatment on sludge. After non-degradable organic wastewater is treated by the process provided by the invention, the BOD5 (Biological Oxygen Demand) / CODcr (Chemical Oxygen Demand) ratio of the wastewater is obviously increased.
Owner:ANHUI GREEN TITAN ENVIRONMENTAL TECH

Treatment system for wastewater without sewage sludge

The invention relates to a wastewater and sludge treatment technique, which particularly provides a sludge and wastewater free treatment system. The system comprises grilles, an aerated grit chamber, a hydrolysis acidification pond, an oxidation pond and a secondary sedimentation pond which are orderly connected, and the system also comprises a disinfection pond, a slag pond, a slag concentration tower and a sludge dewatering machine. When the system is operated, the wastewater passes through wide and narrow grilles to remove large impurities and enters the aerated grit chamber for sedimentation treatment, the discharged water enters the hydrolysis acidification pond; by a sludge bed in the hydrolysis acidification pond, the wastewater and reflux slag sludge are captured and the slag sludge is decomposed; the wastewater after the sedimentation treatment passes through a fixed type biological bed in the oxidation pond for biological treatment, the discharged water enters the secondary sedimentation pond for slag sedimentation, the discharged water after the slag sedimentation enters the disinfection pond for disinfection treatment, the water after the disinfection treatment can be discharged or reutilized, and the sedimentation slag is sent to the slag pond, and is concentrated by the slag concentration tower and is sent to the sludge dewatering machine for dewatering treatment. The sludge and wastewater free treatment system has the advantages of low equipment investment, low operating cost and good effect of wastewater treatment.
Owner:李波

Glyphosate-producing wastewater treatment integration technology

The invention discloses a gyphosate-producing wastewater treatment integration technology. The technology comprises steps as follows: micro-electrolysis treatment is performed under the aeration condition, toxic and degradation-resistant organic matters in wastewater are oxidized by a Fenton regent comprising hydrogen peroxide and ferrous ions which are by-products produced by ferric carbon filler, after lime is added to effluent and pH is regulated to 8-9, a flocculating agent is added for precipitation, suspended matters and iron-phosphorus precipitates are removed, effluent after precipitation is sent to an upflow anaerobic reactor, and degradation-resistant and toxic organic matters in wastewater are further degraded, removed and transformed, the effluent enters a multi-stage contact oxidation pond and a primary aeration sedimentation tank for biochemical treatment, the treated wastewater is emitted up to standard, and the organic matter removal rate in a pretreatment combination physicochemical technology can be up to 50%. The technology is stable in operation and good in treatment effect, the treatment cost is reduced, and the treated effluent can meet the integrated wastewater discharge standard (GB-8978-1996).
Owner:四川省生态环境科学研究院 +2

Synergistic gas-liquid-solid pollutant treatment system based on power plant wastewater zero-discharge technology

The invention provides a synergistic gas-liquid-solid pollutant treatment system based on a power plant wastewater zero-discharge technology and belongs to the technical field of coal-fired boiler pollutant control. The synergistic gas-liquid-solid pollutant treatment system includes a desulfurized wastewater zero-discharge treatment system, an SNCR + SCR united denitration system and a high-temperature electric dust removal system, wherein the desulfurized wastewater zero-discharge treatment system performs desulfurized wastewater pretreatment and pre-concentration, the SNCR + SCR united denitration system absorbs dissolved ammonia or urea of the treated desulfurized wastewater, uses the dissolved ammonia or urea as a reducing agent to be sprayed into an outlet of a boiler and a flue behind a coal economizer to complete denitration reaction, and the high-temperature electric dust removal system is arranged behind the coal economizer to collect and remove evaporated crystal substances of the wastewater. The synergistic gas-liquid-solid pollutant treatment system has excellent properties, is stable in process operation, achieves zero discharge of wastewater while achieving synergistic and coupled gas-liquid-solid pollutant treatment, reduces equipment investment by 10%-50% and the operation costs by 75%-90%, greatly reduces the equipment failure rate and maintains the working amount.
Owner:STATE GRID HENAN ELECTRIC POWER ELECTRIC POWER SCI RES INST +2

Coke oven flue gas multi-pollutant dry purification device and process

The invention relates to a coke oven flue gas multi-pollutant dry purification device. The device consists of an evaporator I, a desulfurizer adding apparatus, a cloth bag dust collector, and a mediumand low temperature SCR denitration reactor. The evaporator I is a heat pipe type evaporator, the desulfurizer adding apparatus is connected to a desulfurizer grinding and conveying system, and the desulfurizer grinding and conveying system consists of a desulfurizer powder bin, a Roots blower and a desulfurizer pulverizer. The cloth bag dust collector includes a filter bag chamber, the filter bag chamber includes a dust remover ash hopper, a dust remover middle box and a purified air chamber that are disposed from the bottom up in order, the dust remover middle box is internally equipped with a tubesheet, a filter bag is disposed on the tubesheet, and a pulse dust-cleaning apparatus is disposed above the filter bag. An air outlet of the cloth bag dust collector is connected to an air inlet of the medium and low temperature SCR denitration reactor, an air inlet pipeline of the medium and low temperature SCR denitration reactor is internally equipped with an ammonia injection grid anda guide plate II, and a flue gas current equalizer, a catalyst reservation layer and a catalyst layer are disposed below the guide plate II in order.
Owner:ANHUI WEIDA ENVIRONMENTAL PROTECTION TECH

Continuous esterification production method for plasticizer

The invention discloses a continuous esterification production method for a plasticizer. The method comprises the following steps of: mixing phthalic anhydride and an alcohol raw material according to the molar ratio of 1:(2.5-3.0), removing water at the temperature of between 150 and 180 DEG C, and thus obtaining a pre-esterification material; heating the alcohol raw material to obtain overheating alcohol gas; and allowing the pre-esterification material to continuously pass through at least two continuous esterification reactors which are connected in series with each other and are provided with catalyst reaction beds, continuously introducing the overheating alcohol gas into the continuous esterification reactors, and taking the plasticizer out of the bottom of the continuous esterification reactor at the tail end continuously. By the continuous esterification production method for the plasticizer, production time is greatly shortened, production efficiency is improved, a large quantity of labor power and material resources are saved, the conversion efficiency of raw materials is improved, the purity of a product is improved, energy consumption is reduced, and the raw materials are saved; and the method is environment-friendly.
Owner:WEIFANG YUANLI CHEM

Wastewater treatment system and wastewater treatment method based on photoelectric Fenton-biological enhancement

PendingCN106830563AReasonable process routeThe processing mechanism is clear and orderlyWater treatment compoundsWater aerationWater pipePrecipitation
The invention discloses a wastewater treatment system and a wastewater treatment method based on photoelectric Fenton-biological enhancement. The system comprises a preaeration tank (1), a photoelectric Fenton reactor (2), a degassing neutralizing tank (3), a coagulative precipitation tank (4), an adjustment tank (5), a microencapsulation biological fluidized bed (6) and an immobilization biological active carbon bed (7) which are connected in sequence through water pipes. The photoelectric Fenton-biological enhancement-based wastewater treatment system is reasonable in structural design, convenient to operate, high in working efficiency, low in cost and good in wastewater treatment effect and orderly, and organically combines physical and chemical treatment, biochemical treatment and guarantee treatment; the photoelectric Fenton reactor, the microencapsulation biological fluidized bed and the immobilization biological active carbon bed support and promote one another functionally, so that the removal efficiency for refractory characteristic organic pollutants is over 98 percent, the sludge yield is low, the sludge treatment cost is low, the sewage treatment effect is good, and the wastewater treatment system based on photoelectric Fenton-biological enhancement has important significance for environmental protection.
Owner:YANCHENG INST OF TECH

Method for using ozone-immobilized biological activated carbon for realizing deep treatment of industrial wastewater

The invention discloses a method for using ozone-immobilized biological activated carbon for realizing the deep treatment of industrial wastewater and relates to a deep treatment method of the industrial wastewater. The method can solve the problems that the existing industrial wastewater deep treatment processes have the common defects of greater investment, unstable process operation, unstable treatment effect and incapability of meeting environmental protection requirements, thereby causing difficult deep treatment of the industrial wastewater; and the method can also solve the problem that the adoption of the ozone-immobilized biological activated carbon technology is not applicable to the industrial wastewater deep treatment. The method comprises the following steps: 1) leading outlet water of pre-treatment to enter into a contact oxidation tower, and carrying out ozone aeration; 2) injecting the outlet water from the contact oxidation tower into an immobilized biological activated carbon tank; and 3) leading the outlet water from the immobilized biological activated carbon tank to enter into an ultrafiltration water tank for completing the method. The method can effectively carry out the deep treatment of the wastewater, reduce the cost, stabilize the process operation and stabilize the treatment effect, thereby being applicable to the deep treatment processes of petrochemical wastewater, printing and dyeing wastewater, coking wastewater and other types of wastewater and leading the water quality COD of the outlet water to be lower than 50mg/L.
Owner:HARBIN INST OF TECH

Softening process for industrial raw water

ActiveCN102134129AFast filtrationLow filtration rateWater softeningSoftened waterFiltration
The invention discloses a softening process for industrial raw water, and the process comprises the following steps of: A. industrial raw water input; B. softening reagent injection; C. precipitation and collection of a natural crystal grain which mainly comprises CaCO3; D. cyclic reinjection of the natural crystal grain which mainly comprises CaCO3; E. crystal grain growth to become a circulating fluidized-suspended bed; F. softened water output; G. sand discharge. Compared with traditional clarifier process, the invention has the advantages of both a fluidized bed and a suspended bed, so the filtration rate is high and the volume is small; and the resultant is sand which is easy for dehydration. According to the process of the invention, the crystal nucleus is generated naturally and grows circularly by itself; no artificial processing of the crystal nucleus is necessary; and the cost for the processing and the addition of an artificial crystal nucleus is saved; the particle size and the flow velocity of the suspended crystal grain in the process of the invention are self-matched without strict requirements to the particle size of the initial crystal nucleus, and are self-adjusted, so the process condition is quite wide; no accurate matching with the filtration rate of raw water is necessary; and the process operation becomes more simple and reliable.
Owner:白连福

Low-pressure ammonia synthesis process

The invention provides a low-pressure ammonia synthesis process which comprises the following steps: 1) performing deep cooling air separation on air so as to obtain nitrogen and oxygen, and performing pure oxygen self-heat conversion on the oxygen with a natural gas so as to obtain a mixed gas with CO and H2; ) performing electrolysis water separation so as to obtain hydrogen; 3) mixing the hydrogen with the nitrogen so as to obtain an ammonia synthesis raw material gas, and performing primary ammonia synthesis in a first ammonia synthesis tower filled with an iron-based catalyst, wherein the synthesis pressure is 5-7MPa; 4) feeding the mixed gas discharged from the first ammonia synthesis tower into a second ammonia synthesis tower filled with a ruthenium-based catalyst, and performing secondary ammonia synthesis, wherein the synthesis pressure is 4-6MPa. By adopting the process, the ammonia synthesis process is divided into two sections which are implemented at specific pressure in the presence of specific types of catalysts and raw material gases of specific hydrogen to nitrogen ratios, ammonia synthesis process requirements are met, stable process operation is ensured, and the net value of ammonia at the outlets of the ammonia synthesis towers and the utilization rates of nitrogen and hydrogen are increased.
Owner:绿氨(北京)技术有限公司

Process of repairing polluted soil by combined use of chemical elution and chemical reduction

The invention discloses a process of repairing polluted soil by combined use of chemical elution and chemical reduction. The process comprises the following steps: constructing a spraying site; pre-treating and stacking the polluted soil; arranging a spraying device; preparing an eluting solution in a reagent pond; implementing a spraying process taking acid, alkali and salt as the eluting solution and judging whether the pollutant concentration in a soil lixivium meets a repair target or not; and implementing a spraying process taking a reducer as the eluting solution and judging whether thepollutant concentration in the soil lixivium meets the repair target or not, wherein the spraying process taking water as the eluting solution is executed before the spraying process taking acid, alkali and salt as the eluting solution is executed. By adopting a stacking and spraying process, the process integrates the advantages of a chemical reduction stabilization technology and a chemical elution technology, and solves inevitable problems of the two technologies. The pollutants are reduced more thoroughly by adopting the reducer solution circular spraying process, and meanwhile, pollutioncaused by a lot of pollutants is reduced, use of the reducer is reduced greatly, and the environmental risk is reduced.
Owner:BEIJING GEOENVIRON ENG & TECH
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